Efficient Compound-Cavity Eye-Safe KTP OPO at 1.57 μm Pumped by an Electro-Optic Q-Switched Nd：YAG Laser

An efficient high-energy eye-safe optical parametric oscillator （OPO） based on a type-Ⅱ non-critically phasematched KTP crystal is demonstrated. The KTP OPO is pumped by a quasi-cw diode side-pumped electrooptic Q-switched Nd：YAG laser in a compound-cavity configuration. The maximum output energy of the signal wavelength at 1.57 μm b 66.5 m J, corresponding to an electrical-to-optical conversion efficiency of 4.47% and an optical-to-optical conversion efficiency of 12.1%. The pulse width （FWHM） is about 3.6 ns with a peak power of 18.5 MW. The output energy is insensitive to repetition rate and demonstrates good stability.     

相空间中离散完整系统的Noether对称性和Mei对称性

研究相空间中离散完整系统的Noether对称性、Mei对称性及其导致的守恒量.利用差分离散变分方法,给出相空间中离散完整系统的差分离散变分原理,建立系统的离散正则方程和能量演化方程;给出系统Noether对称性和Mei对称性的判定条件,得到系统离散形式的Noether守恒量和Mei守恒量及其存在的条件.举例说明结果的应用. 关键词： 相空间 离散完整系统 对称性 守恒量     

高稳定LD端面泵浦腔内倍频Nd∶YVO4/LBO连续红光激光器

设计出一种能够较好地补偿激光晶体热效应的激光谐振腔,实现了高稳定LD单端泵浦LBO腔内倍频Nd∶YVO4连续红光激光器.当晶体吸收的泵浦功率为24.56 W时,671 nm激光功率达到1.203 W,光-光转换效率4.9%,激光模式为TEM00模.在输出功率为1.08 W时,激光器1 h功率不稳定度为0.52%.     

A Bidirectional, Diode-Pumped, Passively Mode-Locked Nd：YVO4 Ring Laser with a Low-Temperature-Grown Semiconductor Saturable Absorber Mirror

We report the operation of a bidirectional picosecond pulsed ring Nd：YVO4 laser based on a low-temperaturegrown semiconductor saturable absorber mirror. Except for the laser crystal, the six-mirror ring laser cavity has no intra-cavity elements such as focusing lens or mirror. The bidirectional mode locked pluses are obtained at the repetition rate of 117.5 MHz, pulse duration of 81 ps, power of 2 × 200 mW.     

Simultaneous Magneto-Optical Trapping of Fermionic ^40K and Bosonic ^87Rb Atoms

We report on simultaneous magneto-optical trapping of fermionic ^40K and bosonic 87Rb atoms. This trap is the first step towards quantum degenerate fermi gas ^40K. Laser lights for the two-species magneto-optical trap （MOT） are generated from diode lasers and tapered amplifier. The enriched ^40K dispenser is utilized in the experimental setup. We obtain up to 10^7 -10^8 ^40K and 10^8 -10^9 ^87Rb atoms respectively in the steady-state single-species MOT.     

An All-Solid-State Tunable Dual-Wavelength Ti：Sapphire Laser with Quasi-Continuous-Wave Outputs

A high power dual-wavelength Ti：sapphire laser system with wide turning range and high efficiency is described, which consists of two prism-dispersed resonators pumped by an a11-solid-state frequency-doubled Nd：YAG laser. Tunable dual-wavelength outputs, with one wavelength range from 750nm to 795nm and the other from 80Ohm to 850nm, have been demonstrated. With a pump power of 23 W at 532nm, a repetition rate of 6.5kHz and a pulse width of 67.6ns, the maximum dual-wavelength output power of 5.6 W at 785.3nm and 812.1 run, with a pulse width of 17.2ns and a line width of 2nm, has been achieved, leading to an optical-to-optical conversion efficiency of 24.4%.     

四甲基吡啶卟啉与核酸相互作用的稳态和时间分辨光谱

采用稳态吸收和荧光光谱、圆二色谱和皮秒时间分辨荧光光谱手段, 研究了5,10,15,20-四[4-(N-甲基吡啶)]卟啉(TMPyP4)与腺嘌呤(A)、鸟嘌呤(G)、胸腺嘧啶(T)和胞嘧啶(C)等4种碱基, 以及相应的核苷、核苷酸和单链DNA的结合能力和光谱学性质. 研究结果发现, 嘌呤与TMPyP4的结合能力比嘧啶的强. 对于某一碱基系列, 结合能力强弱顺序依次为: 碱基~核苷<核苷酸<单链DNA. 时间分辨荧光谱研究发现, 除鸟嘌呤外, 核酸和TMPyP4复合物的荧光动力学均含有快(1~2 ns)和慢(约10 ns)两个衰减过程, 它们分别是由激基复合体和环境极性对激发态TMPyP4分子的影响所致. 单链DNA能诱导TMPyP4产生诱导圆二色信号, 而单分子(碱基、核苷、核苷酸)则无此功能.     

Solvothermal Synthesis and Crystal Structure of a Layered Thioantimonate(Ⅲ) [C_4H_9NH_3]_2Sb_4S_7

An inorganic-organic hybrid thioantimonate(Ⅲ) [CH3(CH2)3NH3]2Sb4S7 1 with layered structure was synthesized by solvothermal method. 1 crystallizes in the triclinic system,space group P1 with a=7.0124(11),b=11.919(2),c=14.879(3),α=108.791(3),β=102.441(3),γ=92.846(2)o,V=1140.1(3)3,Mr=859.71,Z=2,Dc=2.504 g/cm3,μ =5.324 mm-1,F(000)=804,S=1.013,the final R=0.0297 and wR=0.0618 for 3534 observed reflections with I > 2σ(I). 1 consists of [C4H9NH3]+ cations and two-dimensional [Sb4S7]n2n- anion which is composed of three SbS3 trigonal pyramids and one SbS4 unit joined by sharing common corners. The anionic layers are stacked perpendicularly to the c axis of the unit cell forming two-dimensional channels between the layers. The [C4H9NH3]+ cations interdigitate in a bilayer and reside in the 2D channels leading to a sandwich-like arrangement of the anion and cations.     

工业废水中微量铜（Ⅱ）和氰化物的流动注射光度分析

采用ＦＩＡ技术，以光度比色法为基础，建立了工业废水中微量Ｃｕ＾２＋和ＣＮ＾－的顺序自动分析方法和装置。其对二种离子的测定频率为６０样／ｈ，相对标准偏差＜１．０％，工作曲线的ｒ值≥０．９９９，各项分析技术指标均优于手工法操作。     

季铵盐类相转移催化剂的介绍与其在异相亲核取代反应中的应用——介绍一个国外本科生实验并讨论其相关问题

介绍了一个国外大学化学专业本科生有机化学实验"相转移催化剂的应用"，介绍了实验设计与流程，分析了实验结果，并讨论其相关的问题。该实验涉及到整套的现代有机合成流程，如薄层层析色谱（TLC）技术与硅胶柱色谱分离技术，并通过半微量反应的设计，减少对环境有害物质的使用，体现了"绿色化学"的设计理念，值得国内本科生有机化学实验借鉴与学习。