间羧基氯磺酚的合成及其光度法测定钢中铌

报道了间羧基氯磺酚(SCPmK)的合成及其与铌的显色反应,在1．8-3．0mol·L-1的盐酸介质中,铌与SCPmK形成1∶1的深蓝色配合物,最大吸收波长在640nm处,其摩尔吸光系数为1． 08×10５L·mol-1·cm-1(乙醇溶液),铌含量在0-60μg／50ml符合比耳定律,运用此法可直接测定钢中微量铌。     

Synthesis, crystal structure and magnetic properties of the binuclear copper (II) complex of a new bis (1, 4, 7,10-tetraazacyclodoclecane) ligand

A new binucleating macrocyclic ligand 2,6-bis (1,4,7,10-te-traazacyclododecan-10-ylmethyl)methoxy-benzene (L) and its binuclear copper (II) complex, [ Cu2LBr2 ] (ClO4 )2 · 3H2O (1), was prepared and the structure was determined by X-ray crystallography. Complex 1 crystallizes in monoclinic crystal system, P21/n space group with a = 0.8206(3), b = 2.0892(8), c = 2.3053(7) nm, β=95.83(2)°, V = 3.932 nm3, Mr = 1017.57, Z = 4, Dc= 1.692 g/cm3, and R = 0. 0489, Rw= 0.0552 for 6571 observed reflections with I≥2σ (I). Both of the copper(II) centers are coordinated by four amine nitrogen donors of cyclen subunits and a bromide an-ion, and each copper (II) ion is in a square-pyramidal coordination environment. Variable temperature magnetic susceptibility studies indicate that there exists weak intramolecular an-tiferro-magnetic coupling ( - 2J = 2.06 cm-1) between the two copper(n) centers.     

Studies on the interfacial charge transfer processes of nanocrystalline CdSe thin film electrodes by intensity modulated photocurrent spectroscopy

Interfacial charge transfer kinetics of the nanocrystalline CdSe thin film electrodes have been studied in sodium polysulfide solutions by intensity modulated photocurrent spectroscopy (IMPS). The interfacial direct and indirect charge transfer and recombination processes were analyzed in terms of the parameters: normalized steady state photocurrents and surface state lifetimes obtained by measuring the IMPS responses under different applied potentials and different solution concentrations. IMPS responses of polycrystalline CdSe thin film electrodes were also presented for comparison.     

Structure model and synthesis of NdCl3-FeCl3-graphite intercalation compounds

The distribution of the elements and microstructure of NdCI₃-FeCI₃-graphite intercalation compounds (GlCs) were shown by scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS). The results show that Nd element intercalates into graphite, forming NdCI₃-FeCI₃-GICs, and the distribution of Nd and Fe is nearly even. On the basis of the data, a structure model for RECI₃-GICs was founded, and the characteristic layer distance and the index of interval energy were calculated. The calculated results agree with experimental ones, and the relative errors are ±2%. Thus it can be seen that the (111) face is optimal direction for intercalation reaction of TbCI₃—LuCI₃, and the (001) face is that for LaCI₃—GdCI₃, because of the lowest interval energy.     

近红外光谱主成分-所有可能回归法定量分析烤烟、小麦样品中的组分含量

利用主成分-所有可能回归法,建立了烤烟、小麦样品不同组份的近红外光谱定量分析模型。结果表明,烤烟样品的总糖、还原糖以及小麦样品的蛋白质含量的预测模型均有好的定量分析结果,且其预测结果与PLS法预测结果相当。     

核子-核子短程关联对x>1区域原子核结构函数的影响

利用Jastrow关联波函数,重新讨论了核子-核子短程关联对原子核结构函数的作用,发现在选用正确的单粒子能量和包括核子间短程对关联效应在内的核内核子动量密度分布以后,并不能解释原子核结构函数在x>1区域的实验数据.     

基于透明陶瓷材料的激光研究进展

陶瓷激光器是一种以透明陶瓷材料作为增益介质的激光器。与单晶相比,透明陶瓷具有制备周期短和烧结温度低等优势,在激活离子高掺杂浓度下能保证良好的光学均匀性,且容易制备成各种大尺寸复合结构。近年在高功率和超短超强激光输出方面得到广泛应用,产生了一系列研究成果。回顾了陶瓷激光器的发展历程,总结了透明陶瓷在高功率、超短超强脉冲激光输出和特殊波长激光输出等方面的最新进展,并阐述了基于陶瓷制备优势的新型激光材料的发展趋势。     

矿产资源开发预警系统研究

简要介绍了预警和地理信息系统(Geographic Information Systems,GIS)的基本概念、研究现状和领域,并针对矿山开发过程中所出现资源浪费和生态环境破坏等问题,确定了基于资源条件和生态环境影响的矿产资源开发预警指标体系,并建立预警系统.论文通过对浙江省富阳大山顶矿区的实地调查和研究区域的生态环境要求,分析和评价了该矿山的资源状况和区位条件及矿产资源开发对生态环境所造成的影响,以此计算警度,然后确定预警等级和开采类型,并利用GIS的信息管理和空间分析功能,结合矿山所在区域的地理坐标、海拔高度、植被覆盖等基础信息,创建矿山预警专题地图,实现了预警的定性、定量、可视、定位及数据共享和动态监测,为矿山的信息化管理提供科学依据.     

面条的物理

当一根干的意大利面条弯曲得超过一定极限时，通常并不断成两半，而是断成从3段到10段不等的几段，这一现象在过去曾使物理学家们（包括诺贝尔奖获得者费曼）困惑不解，为了弄明白这一现象，法国Paris 6大学的Basile Audoly和Sebastian使用Kirchhoff方程模拟了细的弹性棒被弯曲时的情况，按照他们的研究结果，在细棒刚一断裂时，会沿着棒体产生弹性波，     

基于径向基函数网络的虚拟物流企业伙伴选择方法研究

在对虚拟物流企业系统研究的基础上 ,针对虚拟物流企业伙伴选择问题的特点 ,给出了一个面对虚拟物流企业伙伴选择问题的较为全面的选择过程框架 .并提出了一个基于径向基函数网络算法的虚拟物流企业伙伴选择模型 ,实例仿真说明了该算法和模型的有效性 .