4,4′-二羟基二苯砜二钾盐与4,4′-二氯二苯砜的溶液缩聚

对4,4′-二羟基二苯砜二钾盐与4,4′-二氯二苯砜的溶液缩聚,进行了较系统的研究:选择了环丁砜为聚合介质,二甲苯作带水剂;研究了缩聚温度,时间及固含量的影响;讨论了单体配比及碱用量对双酚S配比变化对聚合物分子量的影响,在成盐时添加K_2CO_3可减少产物分子量的波动范围。讨论了影响聚芳砜在加工温度下的热稳定性的因素,并建议了控制后处理过程的方法,最后列出了全对位聚芳砜的主要性能。     

薄层色谱法分离分析N,N-双(2,2,6,6-四甲基-4-哌啶)己二胺产物

研究了用薄层色谱法分离分析N,N 双(2,2,6,6 四甲基 4 哌啶)己二胺(简称哌啶胺)。该方法使用环己烷∶氨水∶甲醇∶乙醇∶异丙醇=2∶3∶4∶7∶8(V/V)为流动相(展开剂)、硅胶G为固定相、碘为显色剂,对哌啶胺的产物进行分离、分析,测定结果最小的ΔRf>0.06。该方法较高效液相色谱法方便、简单,且费用低,试样不用作任何处理,分析结果可用来指导哌啶胺的合成研究和工业化生产。     

多进小波展开的Gibbs函数的渐近性质

本文研究了一类多进小波展开的Gibbs函数的渐近性质，特别地，包括了多进Daubechies型小波．     

Determination of Tungsten Layer Profiles in Bilayer Structures Using X-Ray Reflectivity Method

An effectual method is presented to determine the profiles of a tungsten （W） layer, such as the density, the thickness and the roughness in the multilayer structures, using the x-ray reflectivity technique. To avoid oxidation effects of tungsten, a B4 C capping layer is deposited onto to the W layer. To observe the profiles of the tungsten layer with different thicknesses, three groups of W/B4 C bilayers with different thicknesses are prepared by using ultra high vacuum dc magnetron sputtering and measured by an x-ray diffractometer. A type of genetic algorithm called the differential evolution is used to simulate the measurement data so as to obtain the parameters of bilayers. According to the simulation, it is shown that the W layer density varies from 95.26% to 97.51% compared to the bulk. In our experiment, the deposition rate is 0.044 nm/s, and the thickness is varied in the range of 9.8-19.4 nm.     

Controlled Growth of Zn-Polar ZnO Films on Al-Terminated α-Al2O3(0001) Surface by Using Wurtzite MgO Buffer

The controlled growth of Zn-polar ZnO fihns on Al-terminated α-Al203 （0001） substrates is investigated by the radio-frequency plasma-assisted molecular beam epitaxy method. Prior to the growth, α-Al2O3 （0001） surface is modified by an ultrathin MgO layer, which serves as a uniform template for epitaxy of Zn-polar ZnO films. The microstructures of ZnO/MgO/Al2O3 interface are investigated by in-situ reflection high-energy electron diffraction observations and ex-situ high-resolution transmission electron microscopy characterization. It is found that under Mg-rich condition, the achievement of the wurtzite MgO ultrathin layer plays a key role in the subsequent growth of Zn-polar ZnO. An interracial atomic model is proposed to explain the mechanism of polarity selection of both MgO and ZnO films.     

非相关双束可调谐染料激光器实验研究

本文报道了研制成功的闪光灯泵浦矩形非相关双束可调谐染料激光器,它可同时在两种染料中获得双束激光输出,具有频差大、脉冲同步、无模式竞争等特点。文中给出了装置结构和典型实验结果,并做了简单讨论。 关键词：     

电容器组大功率可控硅恒流充电电源

一、本电源性能简介在受控热核反应和激光工程中,都广泛采用电容储能技术.一般采用调压器升压的高压电源作电容器组充电电源.我们研制成功了5kV,20kV两种规格的三台大功率可控硅恒流充电电源.采用闭环控制方式,使输入到高压变压器初级的电压随着电容器组所充电压成比例地升高,从而维持充电电流平均值恒定不变(充电电流仍为脉动直流,不是恒定直流).在高压侧仅有阻值很小的限流电阻.如果在充电中电容器短路放电,则输入到变压器初级的电压也很快下降,便于保护电源.另外,控制线路中设置了过流截止保护和快速晶体管过电流保护.此外,充电电流在额…     

介孔分子筛表面功能膜的制备及对水体中铅汞镉的去除作用

表面改性;功能膜材料;重金属;吸附;介孔分子筛表面功能膜的制备及对水体中铅汞镉的去除作用     

三聚氰胺聚磷酸盐阻燃剂的合成与表征

采用硅钨酸为催化剂,在甲醇反应介质中由三聚氰胺与聚磷酸反应制得三聚氰胺聚磷酸盐,用元素分析、IR、XRD、TG与DSC等对其进行了分析和表征,并对其阻燃性能进行了评价。从热分析可知,当温度升至684．8℃时,其热损失残余量为43．52％;在653．5℃时有1明显吸热峰,吸热量为629．5J/g涂覆含三聚氰胺磷酸盐的防火涂料的5层板在模拟实际火灾发生情况下,耐火极限为16min,涂料发泡倍数为50-60倍。     

两根之积在解题中的特殊功用

一般来讲,解析几何问题中涉及弦长多是韦达定理两根之和与两根之积联用;若问题只与弦的中点有关,只用两根之和即可.那么是否单独使用两根之积的情形就没有呢？事实并非如此.通过下面例题,读者即可领略韦达定理两根之积在解几问题中的特殊功用.例1过点A（-3,1）向圆x2＋y2=5引切线,求二切线的夹角.