Combined effect of modified zeolite 13X and β-nucleating agent on improving β-crystal content and toughening polypropylene random copolymer

Although addition of β-NUCLEATING agent directly into homo-polypropylene(PPH) is a useful method to improve β-CRYSTAL content and toughen PPH, polypropylene random copolymer(PPR) makes this method powerless due to its random structure and low crystallinity. In this study, the-nucleated PPR with high β-CRYSTAL content was prepared by a novel high effective β-NUCLEATING system which consists of-nucleation agent(TMB-5) and modified zeolite 13X(M13X). It was found that M13X and TMB-5 had a synergistic influence on improving β-CRYSTAL content and toughening PPR. The content of β-CRYSTAL in PPR/M13X/TMB-5 was significantly larger than the sum of that in PPR/M13X and PPR/TMB-5. Besides,fracture behavior, phase morphology and relaxation of matrix chain segments were also investigated. The results showed that M13X and TMB-5 improved the mobility of amorphous chain segments at low temperature and contributed to much energy dissipation. This work provides a powerful method to modify PPR.     

石墨炉原子吸收光谱法测定铅和铜中记忆效应的消除

对石墨炉原子吸收光谱法测定Pb和Cu中 ,不同构形的石墨管存在的记忆效应问题进行了探索研究,并对石墨管采取改进措施,取得了良好的效果,有效地消除了记忆效应。     

非自治Lotka—Volterra竞争系统

讨论了一般ｎ个种群的非自治Ｌｏｔｋａ－Ｖｏｌｔｅｒｒａ竞争系统，给出了系统的正解灭绝的一个充分条件。文献「１，２」中的主要结果被很好地推广。     

Taylor公式在判断级数敛散性时的应用

在一些证明级数敛散性的问题中，Taylor公式的应用有时能起到关键作用．通过实例说明如何运用这一思想，讨论级数的敛散性问题．     

Dual-parameter Correlation Analysis of the Fluorescence Data of 1-Methyl-2-formyl-5-substituted Pyrrole(4-nitrophenyl)hydrazones

effect、pohrencct．l－methyl－2－formvl－5－Y－substitutedpyrrole（4－nltrophenyl）Ndrazones．Correlationresultsmrthefluorescencespectraldataofsubstitutedstyrenesanda－Onthebasisof＊themagnitudesofevaluatedlpm。／p、。”］valuesofEq．l，Inwhichp”a“（orPn。。／an，。）andPa（orP。』／a。。）rePresentthePolarandsPin－delocallzatloneffect，wehaverecentlyproposedthattherearefourcategoriesofpossiblecircumstancesforcorrelationanalysisofradlcalreactlvltlesandspectralpropeTtlesl．IBothpolarandsp…     

THE STABILITY OF THE θ-METHODS FOR DELAYDIFFERENTIAL EQUATIONS

1.Introduction1.1.Thethree0-methodsWedealwiththenumericalsolutionoftheinitialvalueproblem:Heref,no!TdenotegivenfunctionswithT(t)5t,whereasu(t)isunknown(fort>to)'Withtheso--calledone--leg0--method,linear0--methodandnew0--method,onecancomputeapproximat...     

Synthesis and Properties of D-Thymidylyl (3'→5')L-Thymidine (D/L-TpT)

Inrecentyearsmuchefforthasbeenspenttodevelopoligonucleotideanalogsashighlyselectivepharmaceuticalagentstoblockexpressionofdisease-associatedproteins'-'.andtheseefT'ortshaveresultedilltheapprovaloffomiversensodium(vitravene',"),thefirstantisensedrug,byFDAinAugust1998fortreatmentofAIDSpatientswithcytomegalovirus(CMV)-inducedretinitis6.However,thegreatpotentialofantisenseoligonucleotidesasantiviralandanticanceragentsiscompromisedbytheirnucleasesusceptibilityandlowcellmembranepermeability.L-D…     

First Total Synthesis of 5_α-Hydroxy-isopterocarpolone

Sesquiterpenic compounds of the Eudesmane family have attracted considerable attention due to their intriguing biological properties1,2, particularly significant antifeedant activity, cell growth inhibitory and plant growth regulating activities.In 1996, J. Hu and co-workers3 had isolated eudesmane sesquiterpene 5?-hydroxy-isopterocarpolone 1 from the aerial parts of chinese folk medicine Artemisia eriopoda and elucidated its structure by spectropic methods. Herein, we reported the first tota…     

穷时滞泛函微分方程周期解的存在性

本文利用 Mawhin 度的方法在较容易判别和较简单的假设下,得到ω周期方程 存在周期解.