Generation of Superstable,Monodisperse Microbubbles Using a pH‐Driven Assembly of Surface‐Active Particles

Bubbling to the surface : Microscale gas bubbles can be generated in a microfluidic device by simultaneously injecting CO₂ and a dispersion of particles whose hydrophobicity increases as the pH value decreases. The CO₂ dissolves rapidly out of the bubbles, which shrink, and render the dispersion increasingly acidic. This drives the particles to the bubble surface where they form a type of “armor” against further dissolution (see picture).

     

Spatial distribution of sonoluminescence and sonochemiluminescence generated by cavitation bubbles in 1.2 MHz focused ultrasound field

An intensified charge coupled device (ICCD) camera was used to observe the spatial distribution of sonoluminescence (SL) and sonochemiluminescence (SCL) generated by cavitation bubbles in a 1.2 MHz focused ultrasound (FU) field in order to investigate the mechanisms of acoustic cavitation under different sonication conditions for FU therapeutic applications.It was found that SL emissions were located in the post-focal region. When the intensity of SL and SCL increased as the power rose, the growth of SCL was much higher than that of SL. In the post-focal region, the SCL emissions moved along specific paths and formed branch-like streamers. At the beginning of the ultrasound irradiation, cavitation bubbles generated SCL in both the pre-focal and the post-focal region. When the electrical power or the sonication time increased, the SCL in the post-focal region increased and became higher than that in the pre-focal region. The intensity of SCL in the focal region is usually the weakest because of “oversaturation”.The spatial distribution of SCL near a tissue boundary differed from that obtained in free fields. It organized into special structures under different acoustic amplitudes. When the electrical power was relatively low, the SCL emission was conical shape which suggested a standing wave formation at the tissue-fluid boundary. When the electrical power exceeded a certain threshold, only a bright spot could be captured in the focus. The cavitation bubbles which centralized in the focus concentrated energy and hindered the formation of standing waves. With rising electrical power at high levels, besides a bright spot in the focus, there were some irregular light spots in pre-focal region, which indicated some cavitation bubbles or small bubble clusters achieved the threshold of SCL and induced the reaction with the luminol solution.     

氦离子注入4H-SiC晶体的纳米硬度研究

4H-SiC晶体经能量为100 keV,剂量为3×10¹⁶ cm^-2的氦离子高温（500 K）注入后,再在773—1273 K温度范围内进行了退火处理,最后使用纳米压痕仪测量了样品注入面的硬度.测试结果表明,在500—1273 K温度范围内样品的硬度随退火温度升高呈现先增大后减小再增大的趋势,其中773 K退火样品的硬度增大明显.分析认为,退火样品的硬度变化是由退火过程中缺陷复合与氦泡生长导致样品内部的Si—C键密度、键长和键角改变引起的. 关键词： SiC 注入 氦泡 纳米压痕     

基于粒子成像测速技术的水中气泡界面的光学性质研究

基于粒子成像测速的流体可视化技术，根据菲涅耳公式计算了入射到水中气泡界面的光强，得出点光源连续两次反射或折射的光强具有等比数列的规律，光线在气泡界面反射、折射4次就变成完全偏振光且光线几乎消失.当入射角避开35°左右时，即便有一定宽度的线光源入射到气泡界面，第2次折射出气泡的光强与线光源的宽度无关，类似一条光线入射所产生的光强，给出了面光源在界面所产生的光强的二重积分表达式.线光源所产生的界面光强理论值、面光源产生的光强数值解与实验值都较为符合. 关键词： 水中气泡 界面 光强 粒子成像测速     

Applications of Defocusing DPIV to Bubbly Flow Measurement

Defocusing digital particle image velocimetry (DDPIV) was used to investigate a bubbly flow in the wake of a hydrofoil. DDPIV is a three component volumetric velocimetry technique that operates at full video rate. Complex, three‐dimensional, and time‐dependent flows can be measured. To measure the bubble sizes, an extension to DDPIV was made to infer bubble sizes from their intensities. Both bubble size distributions and bubble velocity fields were simultaneously measured. Results indicate that DDPIV can reliably measure bubble sizes in the range of 100 microns, as well as resolving their aggregate motion.     

两种气泡混合的声空化

将非线性声波方程和改进的Rayleigh-Plesset方程联立可以描述空化环境中的声场及相应的气泡动力学特征. 用时域有限差分方法模拟了圆柱形容器内两种气泡相互混合时的空化情况. 在烧杯内的稳态背景声场形成过程中, 瓶壁耗散吸收扮演了重要的角色. 在稳态背景声场的基础上, 分析了混合气泡与声场的相互作用、气泡之间的相互作用、混合情况下的频谱特性. 结果表明: 两种气泡平衡半径都不太大时, 气泡与声场的相互作用不强, 声场及气泡的行为也比较规律; 相反, 当其中一种气泡平衡半径相对比较大时, 声场与气泡具有较强的非线性相互作用, 声场及气泡的行为表现出复杂的特性.     

Environment-friendly surface cleaning using micro-nano bubbles

Cleaning a surface using a solution containing a large number of micro to nano scale bubbles has significant advantage regarding environmental protection. This review first briefly introduces the cleaning mechanism of micro-nano bubbles (MNBs), including physical and chemical effects. Then the applications of MNBs in cleaning of metal parts, precision parts, cultural relics or food are introduced. After that, coupled cleaning method of ultrasound and bubbles is introduced. Finally, the characterization methods for the cleaning effect are introduced, which mainly focuses on the changes of physico-chemical properties (mass or cleaning area, infiltration, colony number and light scattering intensity) of the cleaned parts or that (like conductivity) of the solvent. It is believed that MNBs technology will be applied in a broader range of surface cleaning applications.     

Effective medium method of slightly compressible elastic media permeated with air-filled bubbles

An effective medium method is developed for the slightly compressible elastic media permeated with air-filled bubbles, according to the nonlinear oscillation of the bubble, which happens when compressional wave travels through the porous media. The effective Lame coefficients of the porous medium and the nonlinear elastic wave equation are deduced, based on the fact that the micro-unit of the effective medium should have the same stress and strain as the micro-unit of the porous media. The linearized properties obtained by this method are in good agreement with the results of Gaunaurd’s classic theory [Gaunaurd G.C. and überall H., J. Acoust. Soc. Am., 1978, 63: 1699–1711]. Furthermore, the nonlinear coefficient, which is an important property of the porous media, can also be acquired by this method. __________ Translated from Acta Acustica, 2006 (in Chinese) (in press)     

Variations of Free Volume of the Air Abundant in the Water by the Millimeter Waves of Low Intensity

We have found that low power millimeter electromagnetic radiation causes an increase in the volume pertinent to the free air abundant in water. This change is caused by the transition of some part of the dissolved air into a bubble state under decreasing dissolubility of the gas due to its thermal heating by the waves. The increase in the free air may occur only under those conditions when there is no convection in the liquid, i.e. in the case of irradiating by means of low-intense waves.     

Theory of non-equilibrium force measurements involving deformable drops and bubbles

Over the past decade, direct force measurements using the Atomic Force Microscope (AFM) have been extended to study non-equilibrium interactions. Perhaps the more scientifically interesting and technically challenging of such studies involved deformable drops and bubbles in relative motion. The scientific interest stems from the rich complexity that arises from the combination of separation dependent surface forces such as Van der Waals, electrical double layer and steric interactions with velocity dependent forces from hydrodynamic interactions. Moreover the effects of these forces also depend on the deformations of the surfaces of the drops and bubbles that alter local conditions on the nanometer scale, with deformations that can extend over micrometers. Because of incompressibility, effects of such deformations are strongly influenced by small changes of the sizes of the drops and bubbles that may be in the millimeter range. Our focus is on interactions between emulsion drops and bubbles at around 100 μm size range. At the typical velocities in dynamic force measurements with the AFM which span the range of Brownian velocities of such emulsions, the ratio of hydrodynamic force to surface tension force, as characterized by the capillary number, is ~ 10^{− 6} or smaller, which poses challenges to modeling using direct numerical simulations. However, the qualitative and quantitative features of the dynamic forces between interacting drops and bubbles are sensitive to the detailed space and time-dependent deformations. It is this dynamic coupling between forces and deformations that requires a detailed quantitative theoretical framework to help interpret experimental measurements. Theories that do not treat forces and deformations in a consistent way simply will not have much predictive power. The technical challenges of undertaking force measurements are substantial. These range from generating drop and bubble of the appropriate size range to controlling the physicochemical environment to finding the optimal and quantifiable way to place and secure the drops and bubbles in the AFM to make reproducible measurements. It is perhaps no surprise that it is only recently that direct measurements of non-equilibrium forces between two drops or two bubbles colliding in a controlled manner have been possible. This review covers the development of a consistent theory to describe non-equilibrium force measurements involving deformable drops and bubbles. Predictions of this model are also tested on dynamic film drainage experiments involving deformable drops and bubbles that use very different techniques to the AFM to demonstrate that it is capable of providing accurate quantitative predictions of both dynamic forces and dynamic deformations. In the low capillary number regime of interest, we observe that the dynamic behavior of all experimental results reviewed here are consistent with the tangentially immobile hydrodynamic boundary condition at liquid–liquid or liquid–gas interfaces. The most likely explanation for this observation is the presence of trace amounts of surface-active species that are responsible for arresting interfacial flow.