全文获取类型
收费全文 | 272篇 |
免费 | 7篇 |
国内免费 | 3篇 |
专业分类
化学 | 141篇 |
晶体学 | 1篇 |
力学 | 6篇 |
数学 | 39篇 |
物理学 | 95篇 |
出版年
2024年 | 2篇 |
2023年 | 14篇 |
2022年 | 8篇 |
2021年 | 6篇 |
2020年 | 17篇 |
2019年 | 9篇 |
2018年 | 16篇 |
2017年 | 11篇 |
2016年 | 11篇 |
2015年 | 4篇 |
2014年 | 13篇 |
2013年 | 29篇 |
2012年 | 21篇 |
2011年 | 19篇 |
2010年 | 11篇 |
2009年 | 12篇 |
2008年 | 6篇 |
2007年 | 8篇 |
2006年 | 8篇 |
2005年 | 8篇 |
2004年 | 1篇 |
2003年 | 3篇 |
2002年 | 5篇 |
2001年 | 6篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 2篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有282条查询结果,搜索用时 31 毫秒
101.
Molecular dynamics simulations of the Li-ion diffusion in the amorphous solid electrolyte interphase
《中国化学快报》2023,34(11):108242
The solid electrolyte interphase (SEI), a passivation film covering the electrode surface, is crucial to the lifetime and efficiency of the lithium-ion (Li-ion) battery. Understanding the Li-ion diffusion mechanism within possible components in the mosaic-structured SEI is an essential step to improve the Li-ion conductivity and thus the battery performance. Here, we investigate the Li-ion diffusion mechanism within three amorphous SEI components (i.e., the inorganic inner layer, organic outer layer, and their mixture with 1:1 molar ratio) via ab initio molecular dynamic (AIMD) simulations. Our simulations show that the Li-ion diffusion coefficient in the inorganic layer is two orders of magnitude faster than that in the organic layer. Therefore, the inorganic layer makes a major contribution to the Li-ion diffusion. Furthermore, we find that the Li-ion diffusivity in the organic layer decreases slightly with the increase of the carbon chain from the methyl to ethyl owing to the steric hindrance induced by large groups. Overall, our current work unravels the Li-ion diffusion mechanism, and provides an atomic-scale insight for the understanding of the Li-ion transport in the SEI components. 相似文献
102.
Mamdouh A. Sofan Ahmed El-Mekabaty Ali M. Hasel Samy B. Said 《Journal of heterocyclic chemistry》2021,58(8):1645-1655
Dependence on the biological activity of 2-aminothiazole, the synthesis and chemical reactions of ethyl 3-oxo-3-(thiazol-2-ylamino)propanoate ( 1 ) with some different reagents were described for cytotoxic and antioxidant evaluation. The new derivatives 2–19 could be synthesized and characterized by correct analytical and spectral data. In addition to the thiazole ring, these compounds contain 2H-1,2,3-triazole ( 3 ), 1H-pyrazole ( 5 , 12 ), 1,3-dithiane ( 7 ), benzothiazole ( 10 ), thiazolidine ( 13 ), thiazolidinone ( 14 , 15 ), 2H-chromene ( 17 ), pyridine ( 19 ) moieties. The preparation of compounds 2–19 was performed through the formation of the isolable 2-(2-phenylhydrazineylidene) 2 , 2-dimethylaminomethylidene 4 , 2-phenylcarbamothioyl 9 , 2-(methylthio)(phenylamino) methylidene 11 and non-isolable potassium bis(thiolate) 6 , potassium thiolate 8 intermediates from precursor 1 . The activity of these derivatives 1–19 against human lung fibroblast (WI38) and human prostate cancer (PC3) were examined in vitro using the MTT assay. The assessment of their antioxidant activities was carried out by following the ABTS method to evaluate their pharmaceutical importance. 相似文献
103.
《Arabian Journal of Chemistry》2022,15(8):103986
Novel mononuclear complexes 2–8 derived from hybrid Urea Schiff base HL were synthesized using various metal Ni2+, Fe3+, Cu2+, Co2+, Mn2+, Zn2+, and Cr3+. The results revealed the ligand HL reacts with metal ions as monobasic or neutral monodentate chelator it via the nitrogen of azomethine and deprotonated/protonated phenolic oxygen atom adopting octahedral geometry. The elemental analysis of the complexes showed the bonding of the ligand with the metal ions in a ratio of 1: 1 in all-metal complexes. XRD analysis of the ligand and its complexes indicate a monoclinic, tetragonal, orthorhombic corresponding to urea Shiff base (1) and zinc complex (7), nickel complex (2), and cobalt complexes (5), respectively. The bioactivity of synthesized compounds was tested and screened against three cancer cell lines PC3 (prostate), SK-OV-3 (ovarian), and HeLa (cervical). The results revealed a weak activity for the ligand, whereas nickel and iron complexes present moderate activities against three cancer cells. The best results were mentioned with copper and proved the best results against three cancer cells PC3, SKOV3, and HeLa displaying an excellent activity with IC50 values of 0.71 ± 0.06, 0.12 ± 0.06, and 0.79 ± 0.23 μg/mL respectively. Moreover, the urea Schiff base complexes showed good safety in vivo toxicity test. The present study demonstrates that all urea Schiff base complexes is inactive against saint tissue and five metal complexes investigated herein can be effective and promising chemotherapeutic drugs for ovarian cancer cell SKOV3, emphasizing the copper-urea Schiff base complex. 相似文献
104.
A.?M.?M.?Ali P.?A.?RamazanovaEmail author Kh.?S.?Khibiev A.?S.?A.?Salim A.?V.?Tarakanova A.?V.?Anisimov 《Moscow University Chemistry Bulletin》2017,72(6):282-288
Novel 2-mercaptobenzotellurazole derivatives with different functional groups were obtained using its mercapto group. 相似文献
105.
Abstract A convenient synthesis of a series of pyrazole, pyridine, pyridinethione, pyridazine, pyrazolo[3,4-b]pyridine, imidazo[1,2-a]pyrimidine, and pyrazolo[5,1-c][1 2 4]triazine derivatives incorporating a pyrimidine moiety, via the reactions of the versatile, readily accessible 3-oxo-N-(pyrimid-2-yl)butanamide with the appropriate reagents, is described. 相似文献
106.
Najat Ahmed Al-Odaini Mohamad Ismail Yaziz Salmijah Surif Narayanan Kannan 《International journal of environmental analytical chemistry》2013,93(14):1457-1469
This study investigated for the first time the occurrence of selected synthetic hormones including 17α-ethinylestradiol, levonorgestrel, norethindrone and cyproterone acetate in Malaysian tropical waters. Samples were collected from the effluents of five sewage treatment plants (STPs) and at seven stations along the Langat River in Selangor, Malaysia, and its main tributaries. Samples were extracted by solid phase extraction (SPE) and analyzed by liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS). In Langat river samples, only levonorgestrel and cyproterone acetate were found at 50% and 3.3% frequency. The concentrations detected for levonorgestrel ranged from less than the method detection limit (<MDL) to 213?ng?L?1 and from?<?MDL to 76?ng?L?1 for cyproterone acetate. For the STP effluent samples, levonorgestrel was <MDL in all samples and the concentrations detected were in the range?<?MDL – 262?ng?L?1 for cyproterone acetate,?<?MDL ?11336?ng?L?1 for norethindrone and?<?MDL – 1898?ng?L?1 for 17α-ethinylestradiol. 相似文献
107.
《Arabian Journal of Chemistry》2014,7(6):964-971
Palm date fruits have been used for nutritional and medicinal purposes in Middle Eastern countries. They are used in folk medicine for treatment of liver diseases and highly recommended to be consumed by pregnant women before and after delivery. Therefore, the present work aimed to determine the total phenolic content and total flavonoids in three syrups obtained from palm dates extracted with aqueous ethanol (80%) and to evaluate in vitro their antioxidative properties. The new findings showed that the three tested syrups contained significantly different amounts of both total phenolic content and total flavonoids. Syrups can be arranged according to the increase of total phenolic contents and total flavonoids as follows: Yemeni-Rotab > Saudi-Tamr > Iraqi-Tamr. The results of antioxidant activities of palm dates syrups obtained by using different in vitro methods were varied depending on the method used. According to the TBARS method, H2O2 scavenging ability and DPPH methods, all syrups showed to have high to very high antioxidant activities. On the other hand, syrups showed low to intermediate antioxidant activities when other methods were used, such as the scavenging ability of OH and NO and the ability to chelate Fe2+ ions. Generally, the values of antioxidant activities of Rotab-syrup have been shown to be always the highest. 相似文献
108.
Thin films of manganese (III) chloride 5,10,15,20-tetraphenyl-21H,23H-porphine (MnTPPCl) with different film thickness were deposited by an evaporation technique. Some optical constants were calculated for these films at a thickness of 110, 220 and 330 nm and annealing temperature of 373 and 437 K. IR spectrum demonstrating that the thermal evaporation method is a good one to acquire undissociated and stoichiometric MnTPPCl films. Our perceptions demonstrate that the mechanism of the optical absorption obeys with the indirect transition. It was found that the energy gap, Eg, affected by the film thickness and annealing. Dispersion of the refractive index is described using single oscillator model. Dispersion parameters are calculated as a function of the film thickness and annealing temperature. In addition, the third-order nonlinear susceptibility, χ(3), and the nonlinear refractive index, n2, were calculated. 相似文献
109.
Ahmed S. N. Al-Kamali 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1812-1824
The alkylation of 4-cyano-5,6-dimethylpyridazin-3(2H)-thione 3 with some halo compounds gave the S-alkylated products 4a–c , which upon treatment with ethanolic sodium ethoxide afforded the cyclized thienopyridazines 5a–c as products. Pyridazothienotriazines 6a–c were prepared by the treatment of compounds 5a–c with nitrous acid, while their reaction with triethyl orthoformate and with carbon disulfide gave the corresponding pyrimidothienopyridazines 7a–c , and 8a–c , respectively. S-alkylated products 9a–o were obtained by the reaction of 8a–c with some halo compounds. 相似文献
110.
Abeer Obeid Omar Al-Shuja’a Salem Aqeel Sama Al-Aghbari Ali El-Shekeil 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(2):116-123
Three aromatic oligoazomethines containing seven benzene rings each were synthesized. The terminal rings were substituted with different organic groups; namely, OH, H, and NO2. Synthesis was carried out according to the literature by condensing the para-substituted benzaldehydes with benzidine to give the three rings compound, which is then condensed with terephthaldehyde to give the respective seven benzene rings oligomer. The oligomers were used to investigate the effects of molecular structure on the electronic structure, as well as electronic and electrical properties. DC electrical conductivity variation of oligoazomethines is studied in the temperature range 300–500 K after annealing for 24 h at 100°C and after doping with 25 and 50 wt% Multi Wall Nanotubes (MWNTs). An attempt is made to relate DC electrical conductivity and electronic properties to chain length, substituted groups and coplanarity. The different groups attached to the ends showed a small effect on conductivity of the different oligomers in the following order: electron donating > neutral > electron withdrawing groups. Oligoazomethines-MWNTs gave a value of (10?4 Scm?1) as the highest electrical conductivity at higher temperatures. DC electrical conductivity was interpreted using the band energy model. The narrow-gap activation energies noted suggest its application in formulation of photovoltaic panels. 相似文献