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101.
D. Basanta H. Hatzikirou A. Deutsch 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,63(3):393-397
Tumour cells have to acquire a number of capabilities if a neoplasm is to become a cancer. One of these key capabilities is
increased motility which is needed for invasion of other tissues and metastasis. This paper presents a qualitative mathematical
model based on game theory and computer simulations using cellular automata. With this model we study the circumstances under
which mutations that confer increased motility to cells can spread through a tumour made of rapidly proliferating cells. The
analysis suggests therapies that could help prevent the progression towards malignancy and invasiveness of benign tumours. 相似文献
102.
An improved transmission line model to study the thermal effects in semiconductor laser diodes is reported in this paper.
The temperature effects in the laser characteristics are obtained by incorporating temperature dependent gain and carrier
density equations for the laser cavity. These primary factors are introduced in the regular transmission line laser model
to estimate the static and dynamic characteristics of an 1.3μm InGaAsP double heterostructure laser diode. The results show
good agreement with the experimental observation and solution of rate equations referred in the literature. The key feature
of this model is that it provides the laser spectra at various temperatures. Based on the model, time dependent evolution
of optical spectrum, temperature dependent optical output and frequency chirp are evaluated. Further the distribution of photon
and electron density within the cavity is also determined. 相似文献
103.
The system TiO2–photo sensitive dye of a dye-sensitized TiO2 solar cell is numerically simulated. The steady-state numerical model used is based on the continuity and transport equations
for all charge species involved in the system, in connection to Poisson’s equation. The dependence of both electron diffusion
coefficient and light absorbance upon TiO2 porosity is taken into consideration. The resulting electron density after illumination is also set as a function of the
illuminating beam characteristics and material properties. Furthermore, an effective dielectric constant dependent upon the
porosity of TiO2 is used in the model. Results for different values of pore size and thickness of the TiO2 electrode are found in accordance with results reported in the literature.
Paper presented at the 11th EuroConference on the Science and Technology of Ionics, Batz-sur-Mer, Sept. 9–15, 2007.
An erratum to this article can be found at 相似文献
104.
Mitochondrial Outer Membrane (MOM) Permeabilization (MOMP) is a critical event in the mitochondrial types of apoptosis. MOMP is controled by the proteins of the Bcl-2 family and its two proapoptotic members Bak and Bax are the key effectors of MOMP. Voltage-dependent anion channel 2 (VDAC2) is an integral membrane protein that plays an important role in the regulation of Bak and Bax apoptotic function, but underlying mechanisms are not fully understood. In the present article, the mechanisms of MOMP regulation mediated by VDAC2 were explored using structure-based modeling. We show that Bak, prior to an apoptotic stimulus, possesses two low-energy conformations of high shape – and polar complementarity in respect to VDAC2, resulting in two high-affinity modes of Bak binding to VDAC2, one with Bak fully residing in the cytosol and the other with Bak α9 helix inserted into the membrane. Even higher binding affinity of VDAC2 for tBid (truncated Bid/p15) was established, suggesting the tBid-mediated displacement of Bak from the VDAC2/Bak complex resulting in the formation of the VDAC2/tBid complex. The structural analysis of the interaction of this complex with Bax revealed a very high binding affinity of this complex for Bax, suggesting the recruitment of Bax to the MOM by this complex under apoptotic conditions. Besides, we revealed one more low-energy structure of Bax of high binding affinity towards the VDAC2/tBid complex and with helix α9 inserted into the membrane. 相似文献
105.
Recent and earlier models of electrical field flow fractionation (ELFFF) have assumed that the electric field within the fluid domain is governed by Laplace's equation. This assumption results in a linear potential and a spatially constant field across the channel and is generally true for very dilute systems and relatively high effective potentials. Experimental studies show, however, that the effective potential within the channel may be less than 1% of the applied potential; this is apparently due to double layer formation and charge buildup at the poles. In such cases, local analyte concentrations can, nonetheless, be orders of magnitude higher than the bulk mean and the local potential small, both of which can lead to a nonlinear spatial distribution of the field strength. In such cases Poisson's equation must be used rather than Laplace's equation. Steady-state ELFFF simulations were performed using a Poisson's equation-based model. The domain in which Laplace's equation is valid was identified and the effects of concentration and effective field strength on device performance were explored. 相似文献
106.
107.
A. Mohamadalizadeh J. Towfighi R. Karimzadeh 《Journal of Analytical and Applied Pyrolysis》2008,82(1):134-139
At the start-up period, the most important mechanism in the coke production with a clean reactor surface is the catalytic mechanism. The study of this mechanism can be very useful for the better comprehension of the coke production process. In this paper, a model was designed for such a production through the utilization of a catalytic mechanism and a kinetic model, capable of interpreting the catalytic coke production on the reactor surface. For the determination of the model reliability, the experimental data related to the naphtha feed, existing in literature, were used. In addition, the constant parameters of the model, the velocity and the activation energy constants, associated to the kinetic model, were calculated. The results of the developed model were in satisfactory agreement with the experimental data. Eventually, the catalytic coke amount in comparison with the total coke production on the reactor surface and its significance were under investigation. 相似文献
108.
《印度化学会志》2023,100(1):100854
The sorption enhanced reformer concept breaks the thermodynamic limits of steam methane reforming and water-gas shift reactions with selective CO2 removal to produce more H2. In this paper, we propose a dynamic kinetic model for sorption-enhanced steam reformers (SERs) integrated with biomass gasifiers. An analysis of operating conditions was conducted to examine high purity hydrogen production. The kinetic model was validated with published literature results at different reactor pressures (5-20 bar), steam/carbon ratios (2-5), and reactor temperatures (673K–1023K). This study shows that biomass gasifiers can be integrated with SER reactors to produce high purity H2. 相似文献
109.
Dr. Tiancheng Pu Wenhao Zhang Prof. Minghui Zhu 《Angewandte Chemie (International ed. in English)》2023,62(4):e202212278
Strong metal–support interactions (SMSI) represent a classic yet fast-growing area in catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of metal nanoparticles (NPs) with the support material that significantly impacts the catalytic performance through regulation of the interfacial interactions. Engineering SMSI provides a promising approach to steer catalytic performance in various chemical processes, which serves as an effective tool to tackle energy and environmental challenges. Our Minireview covers characterization, theory, catalytic activity, dependence on the catalytic structure and inducing environment of SMSI phenomena. By providing an overview and outlook on the cutting-edge techniques in this multidisciplinary research field, we not only want to provide insights into the further exploitation of SMSI in catalysis, but we also hope to inspire rational designs and characterization in the broad field of material science and physical chemistry. 相似文献
110.
Natural organic matter (NOM) has been considered a major contributor to the fouling of microfiltration (MF) and ultrafiltration (UF) membranes employed in water treatment. However, the fouling potential of NOM has often been assessed in terms of its size or chemical composition. The colloid’s chemical properties have often been ignored. In this study, a chemical attachment-based (CAB) model established previously was used in conjunction with a variety of analytical techniques to investigate the existence of three major components of an aquatic NOM and their role in the fouling of a polyvinylidene fluoride MF membrane. The results suggest that colloidal NOM relevant to membrane fouling has a broader size distribution and variations in chemical properties than proposed previously. For the model aquatic NOM used in this research, fouling was primarily contributed by both non-humic and humic colloidal fractions. The non-humic colloids were larger in size and probably adhered to the membrane regardless of the solution chemistry, while humic colloids had variable size and stickiness depending on solution chemistry. The fouling caused by organic colloids was mostly hydraulically irreversible, as a consequence of favorable surface interactions. The CAB model provided a useful way to understand the role of organic colloids in membrane fouling. 相似文献