Immobilisierte Leucin-Aminopeptidase. Anwendungen in der Proteinchemie

Ohne Zusammenfassung     

Teachers' funds of knowledge and the teaching and learning of mathematics in multi-ethnic primary schools: Two teachers' views of linking home and school

In this paper we explore two teachers' views on the role(s) of parents, the local community and children's home lives in the learning of mathematics in primary school. We use Moll and Greenberg's concept of ‘funds of knowledge’ and apply it to the case studies of two teachers working in the UK context. Issues of teachers' professional experience, ethnicity, class and gender emerge as significant in examining similarities and differences in the teachers' beliefs, understandings and practices in the area of linking home and school. We end with a discussion of some implications for teacher education and professional development.     

Large transient magnetic fields for rare-earth ions recoiling in gadolinium and g-factors of high-spin states in 156, 158, 160Gd

We have determined the transient magnetic field for Coulomb-excited rare-earth nuclei recoiling with velocities in the range between 0.7ν₀ and 6ν₀ into ferromagnetic gadolinium cooled to a temperature T = 80 K. Measured and calculated g-factors in ¹⁶⁹Tm have been used as calibration standards. The transient field is found at first to increase with increasing recoil velocity, and then to level off, approaching a nearly constant value of 5.5 kT at ν = 6ν₀. At the higher velocities (3ν₀ < ν < 6ν₀) the transient fields for ¹⁶⁹Tm recoils in gadolinium are a factor of 1.42 ± 0.12 larger than those in iron, whereas the densities of polarized electrons are the same in both ferromagnets. This result demonstrates that an explanation of the transient field must take into account the atomic structure of the host (and probably also that of the recoil). The transient field is too large to be described only in a statistical picture in which inner-shell (ns) vancancies are filled by capture of polarized (4f) electrons. Possible mechanisms may involve either polarization transfer from the outer shells by spin-flip interactions, or direct vacancy polarization by diabatic molecular orbitals.The transient field calibration has been corroborated making use of known g-factors of low-spin states in ^{156, 158, 160}Gd populated by Coulomb excitation of thick Gd single crystals. For the high-spin states in these nuclei, the g-factors are found to decrease slightly, with the ratio $\text{g(10}{}^{\mathrm{+}}\text{)}\text{g(2}{}^{\mathrm{+}}$) reduced to 0.89±0.12, 0.83±0.11, and 0.93±0.13, respectively. Similar decreases have been observed previously for other N = 90?96 nuclei.     

Matrix reactions of alkaline earth metal atoms with ozone : Infrared spectra of the metal ozonide and metal oxide molecules

The 15°K deposition of alkaline earth metal atoms and ozone molecules at high dilution in argon yielded intense bands near 800 cm⁻¹ and in the region, 450–650 cm⁻¹. The bands near 800 cm⁻¹ showed the appropriate oxygen isotopic shifts for assignment to ν₃ of the ozonide ion; the use of scrambled isotopic ozones indicated that the metal cation is symmetrically bound to the ozonide anion which contains three oxygen atoms with two equivalent oxygens. For the case of Ca and Ba atoms and ozone, infrared absorptions appeared between 450–650 cm⁻¹ which showed appropriate oxygen isotopic shifts for vibrational assignment to several metal oxide species. In the calcium experiments, bands at 635.7 and 575.5 cm⁻¹ which showed diatomic oxygen-18 isotopic shifts were tentatively identified as (CaO)₂ species; a pair of bands at 593.0 and 592.2 cm⁻¹ were tentatively assigned to CaO₂. For the barium reactions, bands at 634.7, 571.3, and 460.0 showed appropriate oxygen-18 frequency shifts for assignment to BaO, BaO₂, and (BaO)₂, respectively. The BaO assignment was confirmed by the N₂O-nitrogen matrix reaction which yielded a nitrogen matrix counterpart for BaO at 612.4 cm⁻¹.     

Equation of state of the alpha and epsilon phases of iron

An empirical equation of state that is thermodynamically consistent is found for the alpha (body-centered-cubic) and epsilon (hexagonal-close-packed) phases of iron. It is fit to all available types of experimental data-calorimetic, thermal expansion, acoustic, static compression, and shock data. All thermodynamic identities are satisfied, since expressions for all observables are derived from a thermodynamic potential. No specific theoretical assumptions are made, but the Helmholtz potential is formulated in terms of a number of adjustable functions of single variables by applying some general considerations of lattice vibrations, conduction electrons, and ferromagnetic exchange interaction. The effective Gruneisen parameter depends on temperature as well as volume. Ultrasonic and shock data for the alpha phase are found to be consistent with X-ray determinations of compression based on the sodium chloride standard. The Slater and Dugdale-MacDonald relations are tested against the fit at low pressure and are found to be in error. At high pressure not enough different types of data exist to establish a unique fit without theoretical assumptions.     

One-dimensional BeH2 polymers: infrared spectra and theoretical calculations

Laser-ablated beryllium atoms react with H2 upon co-condensation in excess hydrogen and neon to form BeH2 and (BeH2)2, which are identified through isotopic substitution and DFT calculations. Unreacted Be atoms isolated in solid neon or hydrogen are excited to the 1P0 state and react further with H2 to enhance the BeH2 and (BeH2)2 concentrations and produce (BeH2)n polymers. The series of strong infrared-active parallel Be-H-Be bridge-bond stretching modes observed for (BeH2)n polymers suggests one-dimensional structures, and this conclusion is supported by DFT calculations. The computed polymerization energy per BeH2 unit is about 33 kcal/mol.