学贵有疑--质疑、反思

文[1]“巧解”摘录:题已知二次函数f(x)=ax2 bx c(a,b,c∈R)的图像经过点(-1,0),且x≤f(x)≤12(x2 1)对一切实数x都成立,求f(x).原解设A(x),B(f(x)),C(x2 12)为数轴上的3点,则ABBC=λ.由于当x∈R时,总有x≤f(x)≤12(x2 1)恒成立,∴λ≥0.由定比分点公式得f(x)=x λ(x2 12)1 λ.     

荧光素二聚体荧光探针测定卡那霉素的研究

基于卡那霉素对荧光素二聚体具有良好的荧光增强作用,以现场形成的荧光素二聚体作为荧光探针,建立了卡那霉素定量分析的新方法。在碱性条件下（pH=9.0）,当溴化十六烷基三甲基铵（CTAB）浓度为0.4-1.0 mmol/L时,荧光素（FL）在CTAB作用下形成弱荧光现场二聚体,导致荧光猝灭。加入卡那霉素,体系荧光明显增强,且荧光强度与卡那霉素浓度呈良好的线性关系。在优化条件下,卡那霉素的测定线性范围为2.5×10^-3 - 0.1 g/L,检出限（3σ/K）为1.4×10^-4g/L。用于实际样品分析,测定回收率为101%-116%,RSD为1.9%-2.6%。     

Investigation of Exotic Structure of the Largely Deformed Nucleus ^23A1 in the Relativistic-Mean-Field Model

A candidate for proton halo nucleus ^23A1 is investigated based on the constrained calculations in the framework of the de[ormed relativistic mean tield (RMF) model with the NL075 parameter set. It is shown by the constrained calculations that the ground state of ^23A1 has a large deformation that corresponds to the prolate shape. With that large deformation, the non-constrained RMF calculation predicts that there appears an inversion between the 2s1/2 [211] and ld5/2 [202] shells. The valence proton of ^23A] is weakly bound and occupies 2s1/2 [211] and ld5/2 [202] with the weights of 56% and 29%, respectively. The calculated RMS radius for matter is in agreement with the experimental one. It is also predicted that the difference between the proton RMS radius and the neutron one is very large, This suggests that there exists a proton hMo in ^23Al.     

制作高密度衍射光栅的光电式刻划控制的研究

高精度的光电式刻划控制系统是制作高密度母光栅的关键技术,以光栅干涉仪为控制核心,设计了光电式的光栅刻划控制系统,并对可能产生的加工误差进行了初步的分析;采用该控制系统的光栅刻划实践表明,所设计的光电式刻划控制系统已完全达到了高密度衍射光栅的亚微米栅距分度要求。     

140A MeV~(40,48)Ca和~(58,64)Ni炮弹碎裂反应产物的统计擦碎模型计算

用统计擦碎模型计算了140AMeV40,48Ca+9Be和58,64Ni+9Be弹核碎裂反应产物的截面.通过对碎片截面计算结果和实验测量结果的比较发现,采用自由空间的核子-核子反应截面计算时,对非中心反应产物的截面拟合很好,而对中心反应产物的截面有较大高估,而采用饱和密度相关的核子-核子反应截面计算时,对非周边反应产物的截面拟合较好,而对周边反应产物的截面有一定程度的低估.在统计擦碎模型中,对核子-核子反应截面进行细致的介质密度关联,可能会改进计算值与实验值的符合程度.     

A revisit to the neutron skin thickness of neutron-rich nuclei in the statistical abrasion ablation model

The cross sections of the fragments produced in the projectile fragmentation reactions of the even calcium isotopes from A=36 to A=52 are calculated using the statistical abrasion ablation model.The neutron skin thickness are studied by investigating the fragments isotopic cross section distributions.The neutron-skin thicknesses of the calcium isotopes have a good linear correlation to the peak positions of their fragment isotopic cross section distributions.The correlation between the neutron skin thickness and the neutron density distributions of 48 Ca is investigated by introducing a parameter to adjust the diffuseness parameter in the fermi-type density distribution.     

Isoscaling in Statistical Sequential Decay Model

A sequential decay model is used to study isoscaling, i.e. the factorization of the isotope ratios from sources of different isospins and sizes over a broad range of excitation energies, into fugacity terms of proton and neutron number, R21（N, Z） = Y2（ N, Z）/Y1（ N, Z） = Cexp（αN -βZ）. It is found that the isoscaling parameters α and β have a strong dependence on the isospin difference of equilibrated source and excitation energy, no significant influence of the source size on α andβ has been observed. It is found that α and β decrease with the excitation energy and are linear functions of 1/T and △（Z/A）2 or△（N/A）2 of the sources. Symmetry energy coefticient Gsym is constrained from the relationship of a and source △（Z/A）2, /3 and source △（N/A）2.     

基于离子液体的炭材料制备、改性及应用

离子液体因其熔点低、液态温域宽、蒸气压低、热稳定性高、电导率高、电化学窗口宽、结构可设计及对许多化合物的亲和性等系列性能而引起人们广泛关注。离子液体在炭材料制备、改性领域展示出了良好的前景及巨大的应用潜力,可直接作为碳源,经过高温炭化实现杂原子掺杂制备多孔炭材料;离子液体也可充当反应介质和致孔剂,将生物质转化为多孔炭材料;此外,由于离子液体与炭材料相容性较好,可以用于多孔炭材料改性制备炭复合材料。基于离子液体的炭材料在电催化、超级电容器、吸附分离及生物医学等领域具有潜在的应用价值。本文总结了基于离子液体炭材料的制备、改性及应用最新研究进展,并着重介绍了其在能源和环境相关领域的应用。     

有机试剂结构与性质的研究XII有机试剂的pKa与改进的Swain－Lupton参数

有机试剂的ｐＫ０ａ是其重要的物化参数，它是有机试剂酸碱性的度量，决定其配合物的稳定性．根据Ｓｗａｉｎ－Ｌｕｐｔｏｎ的工作，每个取代基的效应可用两个参数：场／诱导效应参数与共振效应参数来描述．本文应用Ｈａｎｓｃｈ改进的参数值研究了ｐＫａ与取代基常数的相关性，建立了下式．ｐＫａ＝ｐＫ０ａ＋ｒ１Ｆ＋ｒ２Ｒ     

超声波辅助Ru-B非晶态合金常压催化肉桂醛加氢制备肉桂醇

采用KBH₄化学还原法制备了超细Ru-B非晶态合金催化剂。Ru-B催化剂在肉桂醇液相常压加氢中显示出较高的肉桂醇选择性。在加氢过程中使用超声辐射能大大提高反应速率而肉桂醇的选择性几乎保持不变。加氢速率随着超声频率或超声时间的增加而增加。通过XRD、XPS、TEM、BET和ICP等各种表征手段，简要研究了超声辐射对Ru-B催化剂结构和电子特征的影响。同时，还讨论了超声对肉桂醛选择性加氢制肉桂醇催化性能的促进作用。