纳米氧化镍浓度对磁性准固态染料敏化太阳能电池的影响

以琼脂糖为聚合物基质,N-甲基-2-吡咯烷酮(NMP)为溶剂,磁性纳米氧化镍颗粒作为添加剂用于制备染料敏化太阳能电池(DSSC)的磁性聚合物电解质。通过SEM与离子电导率测试研究不同纳米氧化镍掺杂浓度对磁性聚合物电解质的影响,并对相应的染料敏化太阳能电池进行光电性能测试与电化学交流组抗谱(EIS)测试,结果表明:1.0wt%的纳米氧化镍掺杂浓度为最优掺杂浓度,在此浓度下聚合物电解质的表面形貌较为平整,同时电解质具备最高离子电导率(2.43×10-3S.cm-1);染料敏化太阳能电池的光电效率与电子寿命均随着纳米氧化镍掺杂浓度的增加而先增加后降低,并都在纳米氧化镍掺杂浓度为1.0wt%达到最大,此时电池的光电效率为1.63%、开路电压为0.57 V、短路电流密度为5.8 mA.cm-2、填充因子为0.53。     

Energy Transfer and Avalanche Upconversion of NdxY1-xVO4 Nanocrystals

We explore Nd3＋ concentration and excitation power dependences of the avalanche upconversion of NdxY1-xVO4 （x=0-1） nanocrystals with uniform size and shape. The avalanche threshold power caused by the near-resonant energy transfer between 4F5/2→4I13/2 and 4F5/2→2G9/2 significantly decreases as the Nd3＋ concentration increases. The off-resonant energy transfer between 4F5/2→4I13/2 and 4F5/2→4G11/2 in the strong excitation regime leads to apparent broadening on the blue-side of the upconversion spectrum of NdVO4 nanocrystals.     

Saturable Absorption Enchantment of Au Nanorods Based on Energy Transfer between Longitudinal and Transverse Energy Levels

Four kinds of Au nanorods(NRs)with different aspect ratios are designed to adjust the relationship between resonance energy level of longitudinal(L)and transverse(T)modes.During the femto-second Z-scan experiments,huge saturable absorption phenomena are observed while the energy level T is located between one to two times of the energylevel L.This means that the energy may transfer between longitudinal and transverse energylevels in the same and/or different Au NRs.It effectively depresses the production of revised saturated absorption and increases the saturable absorption efficiency.This method is significant for the preparation of high-efficiency saturable absorption devices.     

辐射对称金字塔型剪纸的力学行为

通过在弹性薄板上引入切口,构建了多边形辐射对称金字塔型剪纸结构.利用伽辽金法求解的悬臂梁形变公式和悬臂梁组合的方法,创建了用于解释形变过程的"梁模型",得到n个模块的正N边形金字塔结构的弹性系数与结构参数的关系公式,并求出弹性系数线性阈值的表达式,解释了该结构产生平面外扭曲的原因.利用推导的"梁模型"公式,并通过有限元仿真和实验的方法,系统研究了辐射对称金字塔型剪纸结构的力学响应特征,验证模型的准确性,并用于已有报道的石墨烯剪纸结构的力学特征分析.这项工作系统解释了竖直拉伸的金字塔型剪纸结构的力学响应.     

远紫外高光谱成像光谱仪的辐射定标技术

利用紫外恒星对远紫外高光谱成像光谱仪进行在轨定标是实现高精度定量遥感的重要步骤。然而,在上述过程中,在轨定标系数无法直接用于目标反演。因此,转换在轨定标系数对提升仪器在轨定标精度具有重要意义。推导了定标系数的转换过程,给出了新的定标系数方程,并利用研制的仪器开展了相关验证实验。结果表明,利用修正后的定标系数进行目标反演,可将反演精度提升40%。