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Synthesis,Characterization of 9, 9'-Bianthracene and Fabrication of 9, 9'-Bianthracene Field-Effect Transistors 下载免费PDF全文
We synthesize and purify 9, 9'-bianthracene with the purity up to 96.4%. The electronic and crystallographic structures of 9, 9'-bianthracene are studied. The results of a joint experimental investigation based on a combination of x-ray diffraction (XRD) spectra, hydrogen nuclear magnetic (HNMR) spectra, infrared absorption (FT-IR) spectra, and mass spectra (MS) of 9, 9'-bianthracene are obtained. The uniform compact film is observed by an atomic-force microscope (AFM). Organic field effect transistors (OFETs) with an active layer based on the synthesized 9, 9'-bianthracene are fabricated for the first time. Its field-effect mobility is as large as 0.067 cm^2 /(V·s) and the on/off ratio is above 5 ×10^4. The result demonstrates that the oligomerization of a small semiconductor molecule is an effective method to develop high-mobility organic semiconductors. 相似文献
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为研究自然风荷载对斜拉桥拉索风雨激振的影响,将数值模拟的非稳态风荷载作用到拉索振动微分方程中,对拉索振动响应进行了详细分析。首先,针对水线初始位置,使用最小二乘法拟合得到水线初始位置方程;接着,采用四阶Runge-Kutta法求解拉索振动响应。通过比较在非稳态风和稳态平均风作用下的拉索响应,发现在非稳态风荷载下拉索最大振幅的变化趋势并没有发生较大改变,皆是随着风速的增大先增大后减小;但拉索的整个振动过程发生了变化,伴随着节拍改变,其最大振幅也出现在不同振动周期内。此外,从风速-振幅曲线知,对频率为1 Hz,2 Hz和3 Hz的拉索,在一定风速范围内,考虑非稳态风荷载的拉索振幅反而更大,而且此时的风速范围也更大。 相似文献