A three‐dimensional cadmium coordination polymer based on 1,4‐bis(1,2,4‐triazol‐1‐yl)but‐2‐ene and benzene‐1,3,5‐tricarboxylic acid

The Cd^II three‐dimensional coordination poly[[[μ₄‐1,4‐bis(1,2,4‐triazol‐1‐yl)but‐2‐ene]bis(μ₃‐5‐carboxybenzene‐1,3‐dicarboxylato)dicadmium(II)] dihydrate], {[Cd₂(C₉H₄O₆)₂(C₈H₁₀N₆)]·2H₂O}_n , (I), has been synthesized by the hydrothermal reaction of Cd(NO₃)₂·4H₂O, benzene‐1,3,5‐tricarboxylic acid (1,3,5‐H₃BTC) and 1,4‐bis(1,2,4‐triazol‐1‐yl)but‐2‐ene (1,4‐btbe). The IR spectrum suggests the presence of protonated carboxylic acid, deprotonated carboxylate and triazolyl groups. The purity of the bulk sample was confirmed by elemental analysis and X‐ray powder diffraction. Single‐crystal X‐ray diffraction analysis reveals that the Cd^II ions adopt a five‐coordinated distorted trigonal–bipyramidal geometry, coordinated by three O atoms from three different 1,3,5‐HBTC²⁻ ligands and two N atoms from two different 1,4‐btbe ligands; the latter are situated on centres of inversion. The Cd^II centres are bridged by 1,3,5‐HBTC²⁻ and 1,4‐btbe ligands into an overall three‐dimensional framework. When the Cd^II centres and the tetradentate 1,4‐btbe ligands are regarded as nodes, the three‐dimensional topology can be simplified as a binodal 4,6‐connected network. Thermogravimetric analysis confirms the presence of lattice water in (I). Photoluminescence studies imply that the emission of (I) may be ascribed to intraligand fluorescence.     

区域低碳协同发展评价:京津冀、长三角和珠三角城市群的比较分析

京津冀、长三角和珠三角城市群是中国经济高度发达、最具发展潜力的区域,在低碳发展方面起到引领作用.从经济、资源、环境和绩效的角度构建区域低碳协同发展评价指标体系,采用结合逼近理想解的TOPSIS方法、灰色关联理论和距离协同模型,利用2005~2014年三大城市群50个城市数据实证分析了三大城市群的低碳协同发展程度.结果表明,三大城市群低碳协同发展度整体上呈现上升趋势,其低碳协同程度从高到底依次为长三角、珠三角和京津冀城市群.     

不同类型专利对经济增长影响的实证研究

文章考察三种不同类型专利对经济增长的影响,结合广东省1985-2014年最新数据,通过Matlab、Excel软件对数据进行图像模拟,并根据函数理论、计量经济学理论,创造性地构建一种多元非线性计量模型。进一步地,运用所得模型进行实证分析,结果显示发明专利在经济增长中产生的影响远大于实用新型专利和外观设计专利,论证了原创性创新在现阶段广东省经济转型升级中的核心作用。     

Three‐dimensional printed magnetophoretic system for the continuous flow separation of avian influenza H5N1 viruses

As a result of the low concentration of avian influenza viruses in samples for routine screening, the separation and concentration of these viruses are vital for their sensitive detection. We present a novel three‐dimensional printed magnetophoretic system for the continuous flow separation of the viruses using aptamer‐modified magnetic nanoparticles, a magnetophoretic chip, a magnetic field, and a fluidic controller. The magnetic field was designed based on finite element magnetic simulation and developed using neodymium magnets with a maximum intensity of 0.65 T and a gradient of 32 T/m for dragging the nanoparticle–virus complexes. The magnetophoretic chip was designed by SOLIDWORKS and fabricated by a three‐dimensional printer with a magnetophoretic channel for the continuous flow separation of the viruses using phosphate‐buffered saline as carrier flow. The fluidic controller was developed using a microcontroller and peristaltic pumps to inject the carrier flow and the viruses. The trajectory of the virus–nanoparticle complexes was simulated using COMSOL for optimization of the carrier flow and the magnetic field, respectively. The results showed that the H5N1 viruses could be captured, separated, and concentrated using the proposed magnetophoretic system with the separation efficiency up to 88% in a continuous flow separation time of 2 min for a sample volume of 200 μL.     

Divided-difference equation and three-term recurrence relations of some systems of bivariate q-orthogonal polynomials

Partial divided-difference equations and three-term recurrence relations satisfied by the bivariate Askey–Wilson and the bivariate q-Racah polynomials are computed in this work. By using limiting processes, partial divided (or q)-difference equations and three-term recurrence relations are also provided for each of the following families of orthogonal polynomials: the bivariate continuous dual q-Hahn, the bivariate Al-Salam-Chihara, the bivariate continuous q-Hahn, the bivariate q-Hahn, the bivariate dual q-Hahn, the bivariate q-Krawtchouk, the bivariate q-Meixner, and the bivariate q-Charlier polynomials.     

惯性系统三轴综合测试转台总体设计若干问题的探讨

本文从框架形式、总体布局、轴承的种类和布置方式等方面，讨论了惯性系统三轴综合测试转台总体设计中的若干问题，从设计、制造和使用等方面阐述了各种总体布局形式的优缺点，并提出了自己的相应看法，最后讨论了目前惯导测试设备研究领域需要研究的关键技术。     

三轴运动模拟转台的结构对称性与动力学计算

本文给出了三轴运动模拟转台动力学相互作用的计算公式，并讨论了它的结构对称性问题。     

三轴模拟台的交叉耦合及其控制方法的研究

本文主要从三轴转台的模型出发，研究了采用状态反馈的最优控制及状态观测器来提高控制系统的自适应能力，以解决三轴台特有的不确定非线性耦合问题和变结构解耦控制。     

用三维光弹法确定轴表面横向半椭圆裂纹应力强度因子及其修正系数

用三维光弹法测定了轴表面横向半椭圆裂纹的应力强度因子，并分析计算了应力强度因子修正系数，结果表明，应力强度因子的分布型式对加载条件和裂纹几何不敏感；修正系数对裂纹深度呈现对称分布趋势，仅取决于裂纹几何参数。     

等达因图象的自动采集与识别

文中提出了一种机机械扫描系统．小功率激光器、图象板、相移元件、微机和程序软件组成的等达因图象自动采集与处理系统，用灰度值比较的思想实现了等达因图象的跟踪采集。提出了四幅图象相移法实现等达因图象的自动识别。系统能快速、实时、精确和全自动地实现等达因图象的记录和分析。给出与物体内各点应力状态一一对应的位相图。并用来研究了其他实验方法困难的局部三维效应问题。