Number-Concentration structure factors and their long wavelength limit in multicomponent fluid mixtures

Abstract

Structure factors, similar to the number-concentration structure factors of a binary alloy, are introduced for multicomponent mixtures. Expressions for the long wavelength limit of these (and hence of the related, more conventional) structure factors are derived in terms of the various thermodynamic quantities and their variation with concentrations for some special cases is discussed.     

Extraordinary solitons in non-centrally symmetric photorefractive crystals

The directions of the phase normals for which extraordinary bright screened solitons can be formed are described analytically. Formulas are derived for the directions in which extraordinary solitons can exist in lithium niobate for arbitrary orientations of the external electric field. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 76, No. 3, pp. 403–410, May–June, 2009.     

Resonance states of atomic anions

We study destabilization of an atom in its ground state with decrease of its nuclear charge. By analytic continuation from bound to resonance states, we obtain complex energies of unstable atomic anions with nuclear charge that is less than the minimum “critical” charge necessary to bind N electrons. We use an extrapolating scheme with a simple model potential for the electron, which is loosely bound outside the atomic core. Results for O^2? and S^2? are in good agreement with earlier estimates. Alternatively, we use the Hylleraas basis variational technique with three complex nonlinear parameters to find accurately the energy of two‐electron atoms as the nuclear charge decreases. Results are used to check the less accurate one‐electron model. © 2001 John Wiley & Sons, Inc. Int J Quant Chem 82: 255–261, 2001     

Screened indicators in anhydrous acetic acid medium: Chromatic evaluation of their transitions

Three efficient indicators consisting of Malachite Green and a screening dye for use in anhydrous acetic acid media have been designed by use of complementary tristimulus data. The transition quality can be evaluated by plotting the relative greyness of the indicator against free perchloric acid concentration. Several bases have been successfully determined titrimetrically with use of these indicators.     

Critical parameters and spherical confinement of H atom in screened Coulomb potential

Critical parameters in three screened potentials, namely, Hulthén, Yukawa, and exponential cosine screened Coulomb potential are reported. Accurate estimates of these parameters are given for each of these potentials, for all states having . Comparison with literature results is made, wherever possible. Present values compare excellently with reference values; for higher n, ?, our results are slightly better. Some of these are presented for first time. Further, we investigate the spherical confinement of H atom embedded in a dense plasma modeled by an exponential cosine screened potential. Accurate energies along with their variation with respect to box size and screening parameter are calculated and compared with reference results in literature. Sample dipole polarizabilities are also provided in this case. The generalized pseudospectral method is used for accurate determination of eigenvalues and eigenfunctions for all calculations. © 2016 Wiley Periodicals, Inc.     

球形对称势的能谱计算

球形对称势的能谱计算,在物理学中有着极为重要的意义,对一般的球 形 对称势,扩展了移动1/K展开解法,对任意数量的n和l,准确地给出了截断到1/K 3 项的三级微扰论的结果;并以计算了Morse势、Screened Coulomb势的S态能谱。结果 表明,对于势变化趋势的缓慢情形,这种近似求解结果可靠,收敛良好。     

用改进的屏蔽氢离子模型计算离子的能量

:用改进的屏蔽氢离子模型[1]计算了离子的电离势和次壳层能量。大量计算数据表明,改进模型计算的结果在低Z低离化时与实验相符;在高Z高离化时与MCDF的结果相符,从而弥补了R.M.More屏蔽氢离子模型、Slater单电子模型、WBEPM模型的不足。     

Properties of hydrogen molecular ion with static screened coulomb and exponential cosine screened coulomb potentials

We have investigated the properties of hydrogen molecular ion (H) interacting with screened Coulomb potentials. Two types of potentials have been considered, namely, static screened Coulomb potential and exponential cosine‐screened Coulomb potential. Simulating the localized motion of the nuclei by using high powers of the internuclear coordinate in the generalized Hylleraas‐type wave function we have been able to obtain reasonably accurate binding energies for 1¹S(J = 0, ν = 0) and 2¹S(J = 0, ν = 1) states for various values of the screening parameter within the frame work of Ritz variational method. Borromean bindings are found to exist in the ion for a wide range of the screening parameter. Furthermore, expectation values for various operators and cusp condition have been calculated. Results for the unscreened case are in nice agreement with some of the accurate results available in the literature. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2010     

改进的屏蔽氢离子模型中量子修正Δ_nl的推算

此文用等电子系列实验抛物线关系推算出了改进的屏蔽氢离子模型中量子修正Δnl的值,从而提高了屏蔽氢离子模型计算离子能量的精度     

Polarizabilities and Hyperpolarizabilities for Lithium Atoms in Debye Plasmas

The effects of plasma environments on energies, oscillator strengths, polarizabilities and hyperpolarizabilities for lithium atom have been calculated by combining the l-dependent model potential of free lithium atom and linear variation method based on B-spline basis functions. The influence of plasma on lithium atom is represented by the Debye screened potential, which describes effectively the averaged effect of the plasma environment on atomic spectra. The results are in agreement with other reported ones.