This paper examines the primer vector which governs optimal solutions for orbital transfer when the central force field has a more general form than the usual inverse-square-force law. Along a null-thrust are that connects two successive impulses, the two sets of state and adjoint equations are decoupled. This allows the reduction of the problem to the integration of a linear first-order differential equation, and hence the solution of the optimal coasting are in the most general central force field can be obtained by simple quadratures. Immediate applications of the results can be seen in solving problems of escape in the equatorial plane of an oblate planet, satellite swing by, or station keeping around Lagrangian points in the three-body problem.This work has been sponsored by the Air Force Office of Scientific Research, under Grant No. AF-AFOSR-71-2129. 相似文献
The biocatalytic, regioselective hydroxylation of 2-hydroxybiphenyl to the corresponding catechol was accomplished utilizing the monooxygenase 2-hydroxybiphenyl 3-monooxygenase (HbpA). The necessary natural 1,4-dihydronicotinamde adenine dinucleotide (NADH) co-factor for this biocatalytic process was replaced by a biomimetic co-factor, N-benzyl-1,4-dihydronicotinamide, 1b. The interaction between the flavin (FAD) containing HbpA enzyme and the corresponding biomimetic NADH compound, N-benzyl-1,4-dihdronicotinamide, 1b, for hydride transfer, was shown to readily occur. The in situ recycling of the reduced NADH biomimic 1b from 1a was accomplished with [Cp*Rh(bpy)H](Cl); however, productive coupling of this regeneration reaction to the enzymatic hydroxylation reaction was not totally successful, due to a deactivation process concerning the HbpA enzyme peripheral groups; i.e., -SH or -NH2 possibly reacting with the precatalyst, [Cp*Rh(bpy)(H2O)](Cl)2, and thus inhibiting the co-factor regeneration process. The deactivation mechanism was studied, and a promising strategy of derivatizing these peripheral -SH or -NH2 groups with a polymer containing epoxide was successful in circumventing the undesired interaction between HbpA and the precatalyst. This latter strategy allowed tandem co-factor regeneration using 1a or 2a, [Cp*Rh(bpy)(H2O)](Cl)2, and formate ion, in conjunction with the polymer bound, FAD containing HbpA enzyme to provide the catechol product. 相似文献
An unusual heterodiene, an indolothiono quinone, undergoes cycloaddition with a glycal to form an indole-N-glycoside. A novel dimer of the indolothionoquinone is assigned its structure on the basis of a match between its predicted and observed IR spectrum. 相似文献
We have carried out the study on the isomeric ratios in (γ,p) photonuclear reactions with isotopes
4092
Zr and
74183
W in the giant dipole resonance (GDR) region. The targets were irradiated with bremsstrahlungs produced by electron accelerator
Microtron MT-25 of the Flerov Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, Dubna, Russia. Spectra
of the irradiated samples were measured with a spectroscopic system consisting of 8192-channel analyzer CANBERRA and high-energy
resolution semiconductor detector CANBERRA. The results were discussed and compared with those of other authors.
The text was submitted by the authors in English. 相似文献
We present a microstructure study of different amorphous states of SiO2, which are constructed by compress–decompress procedure. The local microstructure is analyzed through the coordination number, bond-angle statistic and the characteristic of void. The simulation reveals that the number of SiO4, SiO5 and SiO6 units varies in different silica states, but their topology is identical. The densest model (highest density) is obtained upon compress pressure around 20 GPa. The change in void space for different silica states is also calculated and discussed here. 相似文献
This work presents the experimental study of the isomeric ratio of 137mCe–137gCe produced in 138Ce(γ, n) 137m,gCe photonuclear reaction, in neutron capture reaction 136Ce(n, γ) 137m,gCe and in the two simultaneous reactions 138Ce(γ, n) 137m,gCe and 136Ce(n, γ) 137m,gCe in the mixed photon—neutron field by the activation method. The investigated samples were irradiated at the bremsstrahlung photon flux, in the epithermal and thermal-epithermal neutron beam and in the mixed photon-neutron field constructed at the electron accelerator Microtron MT-25 of the Flerov Laboratory of Nuclear Reaction, Joint Institute for Nuclear Research, Dubna, Russia. The results were analyzed, discussed and compared with those of other authors to examine the role of the channel effect in nuclear reaction and provide the nuclear data for theoretical model interpretation of nuclear reactions.
The pressure evolution of the vibrational spectrum of polyethylene was investigated up to 50 GPa along different isotherms by Fourier-transform infrared and Raman spectroscopy and at 0 K by density-functional theory calculations. The infrared data allow for the detection of the orthorhombic Pnam to monoclinic P2(1)∕m phase transition which is characterized by a strong hysteresis both on compression and decompression experiments. However, an upper and lower boundary for the transition pressure are identified. An even more pronounced hysteresis is observed for the higher-pressure transition to the monoclinic A2/m phase. The hysteresis does not allow in this case the determination of a well defined P-T transition line. The ambient structural properties of polyethylene are fully recovered after compression/decompression cycles indicating that the polymer is structurally and chemically stable up to 50 GPa. A phase diagram of polyethylene up to 50 GPa and 650 K is proposed. Analysis of the pressure evolution of the Davydov splittings and of the anomalous intensification with pressure of the IR active wagging mode provides insight about the nature of the intermolecular interactions in crystalline polyethylene. 相似文献
We study the asymptotic behavior of Lipschitz continuous solutions of nonlinear degenerate parabolic equations in the periodic setting. Our results apply to a large class of Hamilton–Jacobi–Bellman equations. Defining Σ as the set where the diffusion vanishes, i.e., where the equation is totally degenerate, we obtain the convergence when the equation is uniformly parabolic outside Σ and, on Σ, the Hamiltonian is either strictly convex or satisfies an assumption similar of the one introduced by Barles–Souganidis (2000) for first-order Hamilton–Jacobi equations. This latter assumption allows to deal with equations with nonconvex Hamiltonians. We can also release the uniform parabolic requirement outside Σ. As a consequence, we prove the convergence of some everywhere degenerate second-order equations. 相似文献
Using elementary differential calculus we get a version of the Morse-Palais lemma. Since we do not use powerful tools in functional analysis such as the implicit theorem or flows and deformations in Banach spaces, our result does not require the -smoothness of functions nor the completeness of spaces. Therefore it is stronger than the classical one but its proof is very simple.