二维Ising反铁磁-反铁磁超晶格的磁性

本文用有效场理论讨论二维反铁磁一反铁磁超晶格(AFAFs)在无外场时的临界温度与超晶格结构的依赖关系,并讨论了超晶格中每一层的磁化强度、磁化率与温度和超晶格结构的依赖关系,得到了由于超晶格结构导致的磁化率的异常峰的存在.并从超晶格的对称性出发讨论了反铁磁-反铁磁超晶格和铁磁-铁磁超晶格之间的异同.     

Mn替代对Dy2AlFe16-xMnx化合物的结构和磁性的影响

通过X射线衍射及磁测量手段研究了Dy2AlFe16-xMnx化合物的结构和磁性.研究结果表明Dy2AlFe16-xMnx化合物具有六角相的Th2Ni17型结构.对x=1,2的样品采用X射线热膨胀测定法在104-647K的温度范围内测量了其热膨胀性质,发现这些化合物在低温下存在热膨胀反常现象,在居里点附近出现负膨胀性质.对自发磁致伸缩的研究结果表明Dy2AlFe16-xMnx化合物中存在着较强的各向异性的自发磁致伸缩,随着Mn含量的增加,其低温下的自发体磁致伸缩减弱.磁测量结果表明Mn的替代导致Dy2AlFe16-xMnx化合物的居里温度及自发磁化强度急剧下降.     

N,N'-双(2-氨基丙基)草酰胺合铜(II)的铜(II)-锰(II)配合物的合成和磁性

合成和表征了两种新的异双核配合物[Cu(oxap)Mn(L)~2](ClO~4)~2, oxap表示N,N'-双(2-氨基丙基)草酰胺根阴离子, L表示1,10-邻菲咯啉(phen)和5-硝基-1,10-邻菲咯啉(NO~2-phen)。测定了配合物的变温磁化率(4.2-300K), 并用最小二乘法和从自旋Hamiltonian算符, ^^H=-2J^^S~1.^^S~2-D^^S~Z~1导出的磁方程拟合。求得交换积分为J=-74.72cm^-^1(phen)和J=-76.39cm^-^1(No~2-phen), 表明两个Cu(II)-Mn(II)双核配合物中有中等强度的反铁磁超交换作用。     

不对称四核环状Co3^IIM^II簇合物的磁化学

本文用一种新的方法对三个核环状化合物Co3Fe(mp)4(Hmp)(PBu3^n)3(1) Co4(mp)4(Hmp)(PMe2Ph)3(2)(H2mp=2-巯基苯酚)和Co4(mp)4(PBu3^n)3Cl(MeOH)(3)进行了1。5-300K温度范围的磁性质研究, 即在各向同性海森堡模型的基础上, 用全矩阵对角化方法求自旋态能量本征值, 从而得到化合物的磁化率, 然后用阻尼最小二乘法拟合变温磁化率, 得到磁交换常数。因避免了使用Kambe理论, 无须对化合物进行模型简化处理, 所以得到更多、更准确的磁交换信息。拟合结果显示三个化合物都呈较弱的磁偶合作用。对化合物1得到J1=-3.14cm^-^1, J2=-3.04cm^-^1, J3=2.92cm^-^1和J4=4.08cm^-^1, 对2得到J1=-3.07cm^-^1, J2=-3.19cm^-^1,J3=-0.33cm^-^1和J4=-1.91cm^-^1; 对3得到J1=-4.818cm^-^1,J2=-4.244cm^-^1, J3=-1.164cm^-^1和J4=-2.634cm^-^1, 其中J1和J2代表通过双重μ2-S桥, J3和J4分别代表通过单重和双重μ2-O桥进行的磁交换作用常数。     

Theoretical analysis of the anisotropy of the magnetization of the Ho^3＋ ion in holmium iron garnet single crystals

The spontaneous magnetization of the Ho^3＋ ion in holmium iron garnet （HoIG） single crystals in the temperature range of 4.2-294K along the directions [111], [110], and [100] are calculated, taking into account the effects of six magnetically inequivalent sites occupied by the Ho^3＋ ions based on the quantum theory. The calculated results show that the magnetization of the Ho^3＋ ion in HoIG is obviously anisotropic. The theoretical results ave in agreement with those of experiments. A primary interpretation of the anisotropy of magnetization of the Ho^3＋ ion in HoIG is put forward.     

场冷和零场冷过程中磁化强度的模型化与数值模拟

通过采用蒙特卡罗模拟方法和磁通运动的热激活模型（ＴＡＦＭ） ,本文计算了在场冷（ＦＣ）和零场冷（ＺＦＣ） 过程中的磁场位形及磁化强度．基于简单的ＫｉｍＡｎｄｅｒｓｏｎ 模型的Ｕ（ｊ） 依赖关系,主要的实验结果都可以较好的被模拟．计算表明,在零场冷中,磁场位形非常接近Ｂｅａｎ 临界态模型,而在场冷中则相反,表现的是磁通冻结的图象．零场冷和场冷中的磁化强度都很强的依赖于钉扎势和临界电流密度,而只微弱的依赖于温度变化的速度     

MAGNETOMECHANICAL BEHAVIORS OF GIANT MAGNETOSTRICTIVE MATERIALS

The Laves phase alloy Tb-Dy-Fe, commercially known as Terfenol-D, exhibits the giant room-temperature magnetostriction at moderate field strength of a few kOe due to its combination of high magnetostriction and low magnetocrystalline anisotropic energy. Thus, this pseudobinary rare earth iron compound has found quite a number of applications such as in magnetomechanical transducers, actuators and adaptive vibration control systems. The simultaneous measurements of magnetostriction and magnetization at various fixed compressive pre-stresses applied in the axial direction for Tb0.3Dy0.7Fe1.95 samples are presented. The results show that the magnetostriction increases with increasing compressive stress until it reaches 1742 ×10^6 under 25 MPa, so does the coercive magnetic field. And the hysteresis loop area for magnetization and magnetostriction also increases with the increment of applied compressive stresses. But the maximum magnetic susceptibility χ（dM/dH） is obtained under zero stress field and the strain derivative dλ/dH increases to the highest amplitude of 0.039×10^-6 A^-1m at a stress level of 5 MPa. In the strain versus magnetization intensity curve, the initial fiat stage mainly consisting of a 180° domain wall motion becomes shorter with increasing stress. It means more initial domains are driven to the transversal direction under the compressive stress before magnetization, which is consistent with the improvement of the magnetostriction.     

非牛顿磁性纳米流体旋转流动

研究非牛顿磁性纳米磁体定常旋转流动。考虑到磁化强度的特殊贡献,应用修正的非牛顿磁性流体运动方程,磁场作用是纯扩散,不受流体运动速度场的影响。给出了多种流动的解析解。应用计算机符号运算技术,软件Maple16,可以得岀非牛顿上随体Maxwell磁性纳米流体和Oldroyd B磁性纳米流体非定常流动方程的各级近似解的常微分方程,获得解析和数值解。在研究中对纳米流体的物质常数作纳米修正。