Internal standardization for the determination of cadmium,cobalt, chromium and manganese in saline produced water from petroleum industry by inductively coupled plasma optical emission spectrometry after cloud point extraction

In the present paper a procedure is proposed for the determination of traces of Cd, Co, Mn and Cr in petroleum industry produced water by inductively coupled plasma optical emission spectrometry. The procedure is based on cloud point extraction of these metals, as their dithizonate complexes, into the surfactant-rich phase of octylphenoxypolyethoxyethanol surfactant (Triton X-114). Extractions were carried out in solutions with salinities between 10‰ and 70‰. Since residual salinity in the surfactant-rich phase caused differences in its transport to the plasma, yttrium was used as an internal standard to correct for this effect. The simultaneous metal extraction procedure was optimized by response surface methodology using a Doehlert design and desirability function. Enhancement factors of 21, 21, 9 and 19, along with limits of quantification of 0.093, 0.20, 0.73 and 1.2 μg L^− 1, and precision expressed as relative standard deviation (n = 8, 20.0 μg L^− 1) of 5.8, 1.2, 1.7 and 5.7% were obtained for Cd, Co, Mn and Cr, respectively. The accuracy was evaluated by spike recovery tests on the high salinity water samples with salinity of 40 and 63‰.     

变系数计量经济学联立模型的局部线性工具向量估计及其性质

联立方程计量经济学模型在经济政策制定、经济结构分析和经济预测方面起着重要作用。本文首次提出了我国宏观经济的一类变系数联立模型,并建立了函数系数的局部线性工具向量估计,同时在时间点列固定设计、经济变量随机设计条件下,研究了估计量的大样本性质。与我国宏观经济经典线性联立模型相比,变系数联立模型拟合效果更优。另外它也有助于克服我国宏观经济数据不多而造成的非参数方法应用困难的现实情况。     

湖南省各市州经济发展水平评价

本文利用主成分分析法分析了湖南各市州的经济发展水平和经济综合实力,对湖南省14个市州的经济发展情况做出综合评价,得出了各市州在湖南省的经济地位.最后用系统聚类分析法进行了验证,结果表明用多元统计分析法来评价地区经济发展水平是可行的.     

Infinite propagation speed of the Camassa-Holm equation

We use the inverse scattering transform to show that a solution of the Camassa-Holm equation is identically zero whenever it vanishes on two horizontal half-lines in the x-t space. In particular, a solution that has compact support at two different times vanishes everywhere, proving that the Camassa-Holm equation has infinite propagation speed.     

磁致伸缩系数的测量

为了避免非平衡电桥法测量磁致伸缩系数出现的漂移现象，本文提出了一种用光学干涉法间接测量磁致伸缩系数的实验方法。     

萃取色谱法富集原子吸收法测定环境水中超痕量金属元素──两种萃取剂的比较

本文研究并比较了分别以８－羟基喹啉和巯基苯骈噻唑为萃取剂，以活性硅胶为载体的柱式萃取色谱法对环境水中Ｚｎ、Ｃｕ、Ｐｂ、Ｃｄ、Ｆｅ、Ｃｏ、Ｎｉ和Ｍｎ的最佳富集和洗脱条件。实验证明，后者明显优于前者。以巯基苯骈噻唑为萃取剂的色谱柱对金属元素的吸附具有快速、完全、寿命长和重现性好等特点。在ｐＨ＝７～８之间回收率可达９８％以上，富集倍数为２００倍。     

负电子亲和势GaAs光电阴极中的三光子激发和发射的理论研究

将三阶微扰理论应用于单晶GaAs半导体,结合与实际相接近的能带结构,得到了GaAs中三光子吸收系数的解析式表达式,在考虑了激发电子的逃逸过程的情况下,进而推导了负电子亲和势GaAs光电阴极中三光子光电发射的发射系数的解析表达式.两表达式得到的理论数值分别与用ns量级脉宽、2.06μm波长的激光测得的GaAs中三光子吸收系数和GaAs(Cs,O)光电阴极中三光子发射系数的实验值相比较,吻合较好.     

Relations among eigenvalues of Sturm-Liouville problems with different types of leading coefficient functions

For any Sturm-Liouville problem with a separable boundary condition and whose leading coefficient function changes sign (exactly once), we first give a geometric characterization of its eigenvalues λn using the eigenvalues of some corresponding problems with a definite leading coefficient function. Consequences of this characterization include simple proofs of the existence of the λn's, their Prüfer angle characterization, and a way for determining their indices from the zeros of their eigenfunctions. Then, interlacing relations among the λn's and the eigenvalues of the corresponding problems are obtained. Using these relations, a simple proof of asymptotic formulas for the λn's is given.     

三角帆蚌对水体Cr,Pb和Cd的净化与吸收

三角帆蚌（Hyriopsis cumingii Lea）对水体Cr,Pb,Cd污染有明显的净化能力，持续处理12d，能使水体Cr,Pb,Cd含量分别下降83％，77．6％和72％。蚌体的斧足、鳃、外磁膜、体表粘液、肝脏、肠道和生殖腺等组织对3种污染物的吸收和富集作用不尽相同，其中分别以体表粘液、鳃和肝脏最为显著。3种污染物进入蚌体的速度很快，其组织吸收量一般在第3天即可达到较高水平。进入蚌体的污染物，可在组织转移和重新分布。研究结果为生物治理Cr,Pb,Cd等重金属污染积累了资料。