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61.
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63.
Manju Rajeswaran Thomas N. Blanton David R. Whitcomb Nicholas Zumbulyadis Brian J. Antalek Scott T. Misture 《Journal of solid state chemistry》2006,179(4):1053-1059
In continuation of our interest in solid-state structures of silver complexes of photographic importance, the structure for silver benzotriazole (AgBZT), has now been obtained. The preferred method for solving crystal structures is via single-crystal X-ray diffraction (XRD). However, for some materials, growing single crystals of appropriate size and quality is often difficult or even impossible. AgBZT is an example of such a silver complex with poor solubility. The usual routes to preparing single crystals using recrystallization from a cooperating solvent resulted in polycrystalline powder samples. We propose a crystal structure for AgBZT, solved from synchrotron X-ray powder diffraction data, using a direct-space Monte Carlo simulated annealing approach. AgBZT crystals are monoclinic, (P21/c), with unit cell dimensions, a=14.8052(3) Å, b=3.7498(4) Å, c=12.3495(12) Å, and β=114.200(6)°. The AgBZT complex is constructed from all three of the Benzotriazole (BZT) nitrogens bonding to a separate silver atom. As a consequence of this bonding mode, the structure is a highly cross-linked, coordination polymer. 相似文献
64.
A. Deptuła T. Olczak W. Łada B. Sartowska A.G. Chmielewski C. Alvani P.L. Carconi A. Di Bartolomeo F. Pierdominici S. Casadio 《Journal of Sol-Gel Science and Technology》2003,26(1-3):207-212
Microspheres of Li2TiO3 were fabricated by a classical, inorganic sol-gel process from commercially available TiCl4. Elaborated process consists of the following main steps: (1) dissolving of TiCl4 in concentrated aqueous HCl and addition of LiOH; (2) formation of sol emulsion in 2-ethylhexanol-1 containing the surfactant SPAN-80 (EH); (3) gelation of emulsion drops by extraction of water with partially dehydrated EH; (4) impregnation of gel to Li:Ti molar ratio MR = 2; (5) thermal treatment at 1200°C in order to receive chloride free product. This temperature can be significantly lowered (to 750°C) by dechlorination starting solution TiCl4 by chemical treatment of the with nitric acid to form of nitrate-stabilized titania sols. Tritium release from sol-gel made Li2TiO3 microspheres were found very close to that observed for other traditional materials, however for the first sample process starts slightly earlier. 相似文献
65.
Michal Demetrian 《International Journal of Theoretical Physics》2007,46(3):652-663
The vacuum decay in a de Sitter universe is studied for the class of effective inflaton potentials that curvature at the top
is less than as well as greater than a critical value determined previously. By comparing the actions of the Hawking - Moss
instanton and the Coleman - de Luccia instanton(s) the mode of vacuum decay is determined in this critical situation. 相似文献
66.
用Von Neumann熵研究了附加克尔介质的压缩真空场与二能级原子依赖强度耦合相互作用量子体系的量子纠缠特性.讨论了初始压缩真空场的压缩度以及克尔非线性作用的强度对该量子体系纠缠特性的影响.结果表明,克尔介质的非线性作用的强弱可以改变体系量子纠缠的周期性;在初始压缩度较大(r=5)时,克尔介质的非线性作用可导致原子与场持续地处于最大纠缠态,无消纠缠态或持续地处于消纠缠态.
关键词:
压缩真空态
克尔介质
依赖强度耦合J-C模型
Von Neumann熵
量子纠缠 相似文献
67.
Elastic rod models provide a means to interpret single molecule DNA experiments as well as predict DNA behavior under physiological conditions. Here we use an elastic rod model to predict the stability boundary (critical torque vs. applied tension) for single molecule DNA experiments in which the molecule is subjected to applied tension and twist. We discuss the shortcomings of the usual isotropic rod model. We then derive a consistent non-linear material law from the general representation for a hemitropic (chiral) rod. Finally, we present results of a standard bifurcation analysis predicting the stability boundary. We find results from the non-linear hemitropic rod to match the data closely. 相似文献
68.
界面应力的正确评价是分析薄膜涂层材料力学特性的难题之一。利用镜像点法和Dirichlet等值性原理,本文推导了等厚双层薄膜涂层材料受表面集中力作用的平面问题理论解。该显式理论解是以固定在各镜像点上的局部坐标系下的Goursat应力函数的形式给出的。对应于高阶镜像点的应力函数,可通过递推的方法,从对应于低阶镜像点的应力函数求得,而且也易于计算机编程。随着镜像点阶数的增大,它与界面的距离也越来越大,因而相对应的应力函数对界面应力的影响越来越小。最后的算例表明,只需考虑前面有限个镜像点,便可获得足够精度的解。该理论解可作为格林函数,以求解复杂问题的理论解,也可用作边界元法的基本解,提高数值计算的精度和效率。 相似文献
69.
H. Sato A. Bensalah N. Solovieva A. Beitlerova A. Vedda M. Martini M. Nikl T. Fukuda 《Radiation measurements》2004,38(4-6):463-466
Two-inch sized KMgF3,BaLiF3 and LiCaAlF6 (LiCAF) single crystals were grown by the Czochralski method under a CF4 atmosphere. X-ray irradiation was used to carry out a comparative study of induced optical absorption phenomena and colour centre creation in the ultra-violet and visible spectral regions. The integral of the induced absorption spectra is significantly lower in LiCAF with respect to the other studied materials. It is found that the amplitude of the F-absorption band is suppressed more than a factor of 3 by Mg-doping. For Mg-doped crystals, the optimum doping concentration is about 0.2 mol% of Mg2+. 相似文献
70.
Formulas for calculating the spectral characteristics of waveguide arrays, which are incorporated into waveguide spectrum analyzers based on planar waveguides, channel waveguides, and fiber optical waveguides, are derived taking into account the contribution of both the waveguide dispersion and the material dispersion to the dispersion factor. These formulas are used to study the dependence of the dispersion factor on the waveguide-system parameters for specific models of waveguide arrays. It is shown that consideration of contributions of the waveguide dispersion and material dispersion can affect profoundly the spectral characteristics of waveguide arrays. 相似文献