非本征型法布里-珀罗干涉仪光纤布拉格光栅应变温度传感器及其应用

介绍了光纤布拉格光栅非本征型法布里珀罗干涉仪集成复用传感器的结构、应变和温度同时监测的原理 ;观察到光纤布拉格光栅反射谱和非本征型法布里珀罗干涉仪干涉谱间的串扰 ,用 3dB带宽平均波长法减小了该串扰 ,提高了测量精度 ;将该传感器应用于三维编织复合材料的应变及温度同时监测。实验结果表明温度精度为± 1℃ ,应变精度为± 2 0 μ ,可满足实际应用的要求     

WO3掺杂的La2/3Sr1/3MnO3电输运与磁电阻特性

通过溶胶-凝胶法制备了La2／3Sr1／3MnO3＋xWO3（x=0～25％）系列多晶陶瓷样品．结果表明。随着WO3掺杂量的增加，样品的电阻率增大，金属-绝缘体相变温度（Tp）值下降．在1．4T磁场下，当0≤x≤12．5％时，样品的室温磁电阻值从5％增大到15％，提高了200％．当12．5％〈x≤25％时，室温磁电阻值从15％降低到0．这对磁电阻材料在室温下的应用提供实验依据．     

一些高Tc超导体的弹性性质

 本文用超声相比较方法测定了高T_c超导体La_1.85Sr_0.15CuO₄，La₂CuO₄和YBa₂Cu₃O₇的纵波和横波声速，进而导出了它们的纵向模量、切变模量、杨氏模量、泊松比、德拜温度及定体比热。在La_1.85Sr_0.15CuO₄样品上，还进行了压力实验，发现所有弹性模量都是随压强增加而增加。定体比热c_V和泊松比σ在高压下则略有下降。德拜温度是随压强增加而增加的。     

Behaviors of the positive temperature coefficient of resistance of poly(styrene‐co‐n‐butylacrylate) filled with Ni‐plated core‐shell polymeric particles

Conductive composite films of poly(styrene‐co‐n‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007     

Study on the Photophysical Process in N-Phenyl Phenothiazine and N-(2-Pyridine) Phenothiazine

By the measurements of the solvent and temperature effects of the fluorescence emission spectra and lifetime of N-phenyl phenothiazine (PHZ) and N-(2-pyridine) phenothiazine (PYZ),the existence of strongly twisted intramolecular charge transfer (TICT) state in PYZ emission spectra is proved.The exciplex formed by PHZ, PYZ and dimethyl terephthalate (DMTP) is investigated, and moreover, the transient absorption spectra of positive and negative ions as the results of the dissociation of the exciplex in the polar solvents is observed through the flash photolysis.     

A New Flow Instrument for Conductance Measurements at Elevated Temperatures and Pressures: Measurements on NaCl(aq) to 458 K and 1.4 MPa

A new flow electrical conductance instrument was constructed and tested on dilute NaCl solutions up to 458 K, and on more concentrated solutions (maximum 0.436 mol⋅kg⁻¹) at 373 K. The results of the new instrument agreed with those of previous authors within the estimated experimental errors. The model of Bernard et al. (J. Phys. Chem. 96, 3833–3840 (1992), MSA) was found to represent the high-temperature results without introducing an ion-pairing equilibrium constant. The Fuoss–Hsia conductance equation as given by Fernandez-Prini was found to represent the dilute concentrations with Λ° (NaCl) as the only adjustable parameter. It was found that Λ° (NaCl) could be expressed as a function of solvent viscosity and density by using three parameters found by regression of literature results between 278.15 and 523 K. This equation along with the FHFP theory permits the equivalent conductivity of dilute sodium chloride solutions to be calculated within the accuracy of the existing experimental measurements.     

STS investigations of temperature dependence of Au(1 1 1) surface state energy position

High temperature scanning tunneling spectroscopy (HT-STS) was used to investigate the electronic structure of Au(1 1 1) at different temperatures in the energy range 0-1 eV below the Fermi level. We concentrated on the influence of temperature on the Shockley surface state (SS) appearing on noble metals surface due to a surface projected bulk bang gap in [1 1 1] direction. The influence of temperature on the projected band gap edge (BE) was also investigated. The experiment was carried out in the temperature range 294-580 K. As the result of the experiment a delicate shift of the SS and the BE in direction of the Fermi level was reported.     

Decomposition of organic salts of some d and f metals

The thermal decomposition in non-isothermal conditions of formates, acetates, propionates and butyrates of Mn, Co, Zn, Cd, Eu, Sm and Ni was studied. The observed compensation effect allows us to calculate the isokinetic temperature. A selective activation mechanism was suggested. This leads to a good agreement between kinetic and spectroscopic data. This revised version was published online in July 2006 with corrections to the Cover Date.     

荧光光纤温度传感器激励光源的选择

本文分析计算了荧光光纤温度传感器的温敏元件——GsAlAs/GaAs双异质结半导体材料的荧光辐射效率与激励光波长的关系。讨论了温度测量范围及温敏元件GaAlAs层铝含量对激励光源的限制,在0～200℃测温范围内,若采用LED作激励光源,其峰值波长应在0.70～0.76μm之间选择。