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991.
A recyclable gold catalyst is synthesized from readily available reagents by immobilizing gold nanoparticles in aluminum oxyhydroxide support through a simple sol-gel method. The catalyst showed the high activity even at room temperature in the aerobic oxidation of various alcohols and in the coupling reaction between primary alcohols and ketones. 相似文献
992.
Huixia Hu Yonggang Shangguan Min Zuo Qiang Zheng 《Journal of Polymer Science.Polymer Physics》2008,46(18):1923-1931
The liquid–liquid phase‐separation (LLPS) behavior of poly(n‐methyl methacrylimide)/poly(vinylidene fluoride) (PMMI/PVDF) blend was studied by using small‐angle laser light scattering (SALLS) and phase contrast microscopy (PCM). The cloud point (Tc) of PMMI/PVDF blend was obtained using SALLS at the heating rate of 1 °C min?1 and it was found that PMMI/PVDF exhibited a low critical solution temperature (LCST) behavior similar to that of PMMA/PVDF. Moreover, Tc of PMMI/PVDF is higher than its melting temperature (Tm) and a large temperature gap between Tc and Tm exists. At the early phase‐separation stage, the apparent diffusion coefficient (Dapp) and the product (2Mk) of the molecules mobility coefficient (M) and the energy gradient coefficient (k) arising from contributions of composition gradient to the energy for PMMI/PVDF (50/50 wt) blend were calculated on the basis of linearized Cahn‐Hilliard‐Cook theory. The kinetic results showed that LLPS of PMMI/PVDF blends followed the spinodal decomposition (SD) mechanism. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 1923–1931, 2008 相似文献
993.
994.
用等值宽度法测量fs脉冲宽度 总被引:2,自引:0,他引:2
本文提出利用等值宽度测量fs光脉冲持续时间的方法.给出了脉冲形状为sech~2 (t/T)、exp(-2t~2/T~2)和exp(-2|t|/T)的干涉相关曲线上包络与相应二阶强度相关曲线半宽度等值的位置,它们分别是3.984、4.875和4.928.定义了两种相关测量的临界延迟速度.理论分析与实验结果符合得很好.所得结果表明,该测量方法可将常规超短脉冲相关测量的时间分辨率提高几倍至几十倍. 相似文献
995.
L. Q. Ji 《Journal of Thermal Analysis and Calorimetry》2008,91(3):885-889
Three rational fraction approximations for the temperature integral have been proposed using the pattern search method. The
validity of the new approximations has been tested by some numerical analyses. Compared with several published approximating
formulas, the new approximations is more accurate than all approximations except the approximations proposed by Senum and
Yang in the range of 5≤E/RT≤100. For low values of E/RT, the new approximations are superior to Senum-Yang approximations as solutions of the temperature integral. 相似文献
996.
无源高温超导磁浮轴承两种方案比较 总被引:2,自引:0,他引:2
无源磁浮轴承的优点是结构简单、造价低廉、无需有源控制。文中探讨了两种无源磁浮轴承的方案 ;对两种方案的悬浮力、悬浮品质因数、悬浮刚度与悬浮稳定性进行了讨论、计算、比较 ;并且讨论了两种方案的优缺点及应用。比较结果表明 ,方案 1更适合于小型的飞轮储能系统 ,方案 2较适合于大中型飞轮储能系统。 相似文献
997.
Hakvoort G. Hol C. M. van Ekeren P. J. 《Journal of Thermal Analysis and Calorimetry》2001,64(1):367-375
A number of compounds is investigated for DSC calibration during cooling. Adamantane and Zn show fast reversible transitions
and can be applied both for temperature and for heat calibrations. A third compound, namely 4,4’-azoxyanisole, has a liquid
crystal to isotropic liquid transition at 409K. This compound can be used for temperature calibration. Heat calibration with
this compound is more problematic because of the small heat effect and the construction of the baseline. Other compounds like
NaNO3, In, Hg and Pb, show a slight supercooling. Nevertheless they can be used for heat calibration. The use of large samples
of NaNO3 and In gives the possibility to construct the equilibrium onset temperatures of the cooling peaks, so these two compounds
are also appropriate for temperature calibration on cooling.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
998.
Cauchy problem on non-globally hyperbolic space-times 总被引:1,自引:0,他引:1
I. Ya. Aref’eva T. Ishiwatari I. V. Volovich 《Theoretical and Mathematical Physics》2008,157(3):1646-1654
We consider solutions of the Cauchy problem for hyperbolic equations on non-globally hyperbolic space-times containing closed
timelike curves (time machines). We prove that for the wave equation on such space-times, there exists a solution of the Cauchy
problem that is discontinuous and in some sense unique for arbitrary initial conditions given on a hypersurface at a time
preceding the formation of closed timelike curves. If the hypersurface of initial conditions intersects the region containing
closed timelike curves, then the solution of the Cauchy problem exists only for initial conditions satisfying a certain self-consistency
requirement.
To Vasilii Sergeevich Vladimirov with best wishes on his 85th birthday
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 157, No. 3, pp. 334–344, December, 2008. 相似文献
999.
1000.