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121.
为比较X射线光电子能谱(XPS)与紫外光电子能谱(UPS)测量材料功函数结果间的差异,依次对经氩离子清洁表面吸附层的Au、Ag薄膜样品和单晶硅片,以及未进行表面清洁的Au、Ag、MoO_3薄膜样品,单晶硅片及ITO导电玻璃的功函数进行测量。给出了XPS和UPS测量功函数的计算方法,并探讨了影响材料功函数测量结果不确定性的因素。研究发现XPS及UPS在测量表面清洁的金属样品时,测量结果基本一致,具有较高的准确度,表面清洁的Au、Ag样品一经暴露空气后其表面覆盖一层吸附层,功函数很快发生变化。利用UPS或XPS测量金属和半导体的功函数时应避免暴露空气,若金属样品在空气中暴露时建议使用氩离子清洁表面。研究结果对科研人员按实际测试需求合理选择测量方法具有一定的指导意义。 相似文献
122.
Is there a relationship between protein thermal stability and the denaturation heat capacity change?
G. Graziano 《Journal of Thermal Analysis and Calorimetry》2008,93(2):429-438
It is shown the non-occurrence of a correlation between the values of the denaturation temperature and those of the denaturation
heat capacity change for a set of 13 proteins possessing the ‘SH3-type’ fold from both mesophilic and thermophilic microorganisms.
This seems to be a rather general result, because, fixed the size and the folding pattern, the denaturation heat capacity
change is a nearly constant quantity, within the uncertainty limits of experimental determinations, regardless of the thermal
stability of the protein. A precise definition of the thermodynamics of the hydrophobic effect is presented to clarify that
the above finding does not imply that the hydrophobic effect does not play a role in the extra-thermal stability of thermophilic
and hyperthermophilic proteins. 相似文献
123.
Shahzeb Ahmad Shazia Bashir Mahreen Akram Rizwan Amir Muhammad Shahid Rafique Wolfgang Husinsky Mubashir Javed 《Surface and interface analysis : SIA》2023,55(2):113-126
The present paper reports the investigation of surface morphology, elemental composition, phase changes and field emission properties of Si ion irradiated nickel (Ni) and titanium (Ti). The Ni and Ti targets have been irradiated with 500 keV Si ions generated by Pelletron accelerator at various fluences ranging from 6.9 × 1013 to 77.1 × 1013 ions/cm2. Stopping range of ions in matter analysis revealed higher values of electronic stopping and sputtering yield for Ni as compared with Ti. For both irradiated metals, electronic energy loss dominant over the nuclear stopping. The growth of induced surface structures have been analysed by using field emission scanning electron microscopy (FESEM) analysis. In case of Ni, as the ion fluence increases from 6.9 × 1013 to 65.8 × 1013 ions/cm2, the formation of spherical particulates, agglomers and sputtering is observed. Although in the case of Ti, with the increase of Si ion fluence from 11.6 × 1013 to 77.1 × 1013 ions/cm2, the formation of irregular-shaped particulates along with crater and sputtered channels is observed. X-ray diffraction (XRD) analysis shows that no new phase is identified. However, a significant increase in peak intensity is observed with increasing ion fluence. The variation in crystallite size and dislocation line density is also observed as a function of Si ion fluence. Fourier transform infrared spectroscopy analysis shows that no bands are formed after the Si ion irradiation. Field emission properties of ion-structured Ni and Ti are well correlated with the growth of surface structures observed by SEM and dislocation line density evaluated by XRD analysis. 相似文献
124.
Ranveer Singh Maxime Vallet Vijay Singh Sanjeev K. Srivastava Alain Claverie Tapobrata Som 《Surface and interface analysis : SIA》2023,55(2):151-161
Due to its outstanding physical properties, CdTe is used to fabricate high efficiency solar cells. However, its high work function poses a challenge, and hence, to fabricate an efficient CdTe-based solar cell, Cu-doping may be useful. Here, we present the role of temperature-dependent Cu-doping in radio frequency sputter-deposited CdTe films and the related changes occurring in their optical, electrical, structural and microstructural properties. For instance, Cu-doping at different temperatures leads to an increase in the grain size and a reduction in the optical reflectance with increasing temperature. In addition, Kelvin probe force microscopy measurements reveal that the work function is found to be smaller corresponding to the annealing temperature of 473 K, whereas resistivity measurements show that it decreases with increasing temperature (the lowest value of resistivity is found to be 1.8 × 10−2 Ω-cm). To understand the electronic structure of CdTe before and after Cu-doping, we have carried out first-principles density functional theory (DFT) simulation, which reveals a strong hybridization among Cu, Cd and Te atoms. This study paves the way to fabricate efficient Cu-doped CdTe-based solar cells. 相似文献
125.
Charge exchange in ion–surface collisions may be influenced by surface adsorbates to alter the charge state of the scattered projectiles. We show here that the positive‐ion yield, observed during ion scattering on metal surfaces at low incident energies, is greatly enhanced by adsorbing electronegative species onto the surface. Specifically, when beams of N+ and O+ ions are scattered off of clean Au surfaces at hyperthermal energies, no positive ions are observed exiting. Partial adsorption of F atoms on the Au surface, however, leads to the appearance of positively charged primary ions scattering off of Au, a direct result of the increase in the Au work function. The inelastic energy losses for positive‐ion exits are slightly larger than the corresponding ionization energies of the respective N and O atoms, which suggest that the detected positive ions are formed by surface reionization during the hard collision event. 相似文献
126.
127.
A New Method for Assessment of Performing Mechanical Works of Energetic Compounds by the Cylinder Test 下载免费PDF全文
Farshad Fotouhi‐Far Hadis Bashiri Masood Hamadanian Mohammad Hossein Keshavarz 《无机化学与普通化学杂志》2016,642(19):1086-1090
A new method is introduced for assessment of performing mechanical works of energetic compounds by cylinder wall velocities of CHNOFCl energetic compounds on the basis of the cylinder test. Four suitable decomposition paths are used to evaluate the number of moles of gaseous detonation products per gram of explosive, the average molecular weight of these gases, and the heat of detonation in calories per gram by considering different decomposition products HF, HCl, CO, N2, H2O, H2, and CO2. For CHNO and fluoro energetic compounds, the predicted cylinder wall velocities of these compounds give more reliable results than one of the best available empirical methods. The predicted root mean square (rms) deviations of cylinder wall velocities of the new model for some chloro explosives at actual radial expansions 0.6 and 1.9 mm are 0.010 and 0.062 km · s–1, which show high reliability of the new method. 相似文献
129.
By expanding the yielding function according to Taylor series and neglecting the high order terms, the elastoplastic constitutive
equation is written in a linear complementary form. Based on this linear complementary form and the principle of virtual work,
a finite element-complementary method is derived for elastoplastic problem. This method is available for materials which satisfy
either associated or nonassociated flow rule. In addition, the existence and uniqueness of solution for the method are also
discussed and some useful conclusions are given.
The project is supported by the National Natural Science Foundation of China 相似文献
130.
Guastello Stephen J. Johnson Elizabeth A. Rieke Mark L. 《Nonlinear dynamics, psychology, and life sciences》1999,3(3):259-273
Motivational flow is the experience of intrinsic motivation, which is in turn the result of the levels of challenge and skill involvement for a particular task. The level of flow is predictive of the amount of time a person will spend in that task, and it is thought to form a basis for an individual's time allocation between occupational and leisure activities. In this study, 28 university students, many of whom were employed, completed a 7-day log of their daily activities, their duration, and provided ratings of the level of skills and challenges inherent in the task. The logs provided a time series of several hundred points for each participant, which were each subjected to nonlinear dynamical analysis through nonlinear regression. Principal results were: (1) Flow was chaotic for all subjects. (2) The average R
2
for the nonlinear models was .22, compared to .02 for the linear counterpart. (3) R
2
was higher for people who spent more time at paying jobs. Evidence for individual differences in dynamical character were uncovered. 相似文献