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61.
将介观无损耗传输线中的驻波场看成作相对运动的两列同频率的行波的叠加,此电路量子化后成为两个频率相同、不同模的光子场。计算和分析了激发相干态下电压和电流梯度的量子涨落,指出了双模传输线与一般的LC电路、双模传输线与单模传输线量子涨落的异同之处。 相似文献
62.
Yong Lee Kazuhiko Hosomi Hiroyuki Uchiyama Toshio Katsuyama Shinya Kominami Tomoyoshi Mishima 《Optical Review》2003,10(1):38-42
An InGaAsP slab-type asymmetric-coupled-waveguide-based dispersion compensator with a mode selector has been designed and fabricated. The mode selector is necessary to select either a symmetric [with a positive group-velocity dispersion (GVD)] or antisymmetric (with a negative GVD) supermode. These supermodes exist simultaneously in the dispersion-compensation region of the device. Pulse-compression experiments were used to test the dispersion compensator, evaluating the function of the mode selector. A theoretical study of the experimental results shows that the mode selector obtains a very strong selectivity (nearly 100%) for the antisymmetric supermode. 相似文献
63.
S. A. Kirillov A. Morresi M. Paolantoni P. Sassi 《Journal of Physical Organic Chemistry》2007,20(8):568-573
The most obvious consequence of the concept of aromaticity is the common confidence that in aromatic compounds, bond lengths do not alternate and are between typical to the single and double ones. However, in 1994, performing crystal structure investigations of substituted pyridines and their salts, Krygowski and co‐workers have discovered a very surprising angular group induced bond alteration (AGIBA) effect: It appears that some angular substituents, like methoxy or nitrozo groups, can induce bond alternation in aromatic rings. Crystal studies do not allow one to operate with liquids that are more common in organic chemistry. This paper presents the first possible evidence of spectroscopic manifestations of the AGIBA effect. Raman spectra of the liquid toluene are analyzed. It is found that instead of being single, the line corresponding to the ring breathing vibrations is clearly split by 1.0–1.4 cm?1, thus indicating the presence of two (cis‐ and trans‐) AGIBA isomers. The energy difference between these isomers estimated in temperature dependent Raman studies is found equal to 6.68 kJ mol?1. The low‐wavenumber line therefore corresponds to the cis‐AGIBA isomer and the high‐wavenumber line to the trans‐AGIBA isomer stabilized by the AGIBA effect. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
64.
65.
Werner WinterGünther W.H Höhne 《Thermochimica Acta》2003,403(1):43-53
A method for measuring heat capacities of small samples using a chip-calorimeter and a heat pulse technique is described. The theoretical background to calculate the heat transport properties and the heat capacity of the sample from the pulse response function is given. Problems and potentials of the method are discussed. An example is given. 相似文献
66.
Monia Belhabri Jack Legrand Nathalie LeSauze Abdellah Arhaliass 《Particle & Particle Systems Characterization》2004,21(5):365-371
Emulsions are of great importance to industry. They are involved in many engineering operations, including chemical reactions, extraction, emulsification and suspension polymerization, etc. However, an important problem for these processes is how to control the size distribution of the dispersed phase. Indeed, off‐line analysis of the emulsion may generate uncertainties due to sampling and dilution of the product, which are likely to change the dispersion state and physico‐chemical properties. In this work, an on‐line optical method is proposed to characterize dispersed media in real flowing conditions. This method is based on the time‐analysis of back‐scattered light fluctuations. The present paper deals with the development of this method and its application to dispersions of alumina in water. The results obtained with the on‐line optical method are compared with those acquired by classical laser light scattering and microscopy. 相似文献
67.
Fluorescence line narrowing (FLN) spectroscopy was used to study the role of the polypeptide chain in influencing the spectrum of Zn-substituted cytochrome c (Zn cyt c) and metal-free cyt c (porphyrin cyt c). For both derivatives the spectra show characteristics of relaxed fluorescence from an inhomogeneously broadened sample. Zero phonon lines and phonon wings can be clearly distinguished, and vibrational frequencies of the ground and excited states were identified. The inhomogeneous distribution width for porphyrin cyt c is slightly wider than that of Zn cyt c and a second population of molecules was apparent in the porphyrin cyt c. The phonon coupling was greater for Zn cyt c than for porphyrin cyt c, which may be due to the extra coupling to the polypeptide chain by metal ligation.This work has been done in partial fulfillment of the requirements for the Doctor of Philosophy degree. 相似文献
68.
类锂硅离子软X射线激光研究 总被引:1,自引:0,他引:1
在激光等离子体典型参数条件下,利用碰撞-辐模型计算了类锂硅离子5f-3d和4f-3d跃的粒子数反转比率和激光增益系数。讨论了不同热带条件和不同冷却速度下,激光增益系统数的变化。计算结果表明,高功率,短脉冲激光生产的高温等离子体在快速冷却条件下能产生软X射的线激光增益。 相似文献
69.
群色散光纤中高强度光脉冲传输与压缩的研究 总被引:1,自引:0,他引:1
考虑非线性四阶折射率,推导了光脉冲在群色散单模光纤中传输的非线性方程,并得到孤子型解析解.同时指出在Sech型光纤脉冲压缩实验中,光强度的阈值. 相似文献
70.
单模光纤中皮秒啁啾脉冲压缩 总被引:11,自引:2,他引:9
对单模光纤正群速色散区秒啁啾脉冲的非线性传进行了近似的解析分析和定量的数值计算。结果表明,负啁啾脉冲在传输过程中能得到有效压缩。压缩比与脉冲初始峰值功率和初始啁啾程度有关。初始峰值功率一定的脉冲,其压缩比随初始啁啾程度的增大面大,初始啁啾程度一定的脉冲,压缩比随初始峰值功率的增大而减小,表明自相位调制效应导致脉冲压缩效果变差。计算结果还表明,在脉冲时域宽度得到压缩的同时,光谱宽度也能得到同步压缩。 相似文献