全文获取类型
收费全文 | 19525篇 |
免费 | 3575篇 |
国内免费 | 2646篇 |
专业分类
化学 | 19732篇 |
晶体学 | 205篇 |
力学 | 450篇 |
综合类 | 127篇 |
数学 | 632篇 |
物理学 | 4600篇 |
出版年
2024年 | 58篇 |
2023年 | 272篇 |
2022年 | 396篇 |
2021年 | 1142篇 |
2020年 | 1190篇 |
2019年 | 865篇 |
2018年 | 709篇 |
2017年 | 780篇 |
2016年 | 1138篇 |
2015年 | 1033篇 |
2014年 | 1144篇 |
2013年 | 1832篇 |
2012年 | 1277篇 |
2011年 | 1111篇 |
2010年 | 983篇 |
2009年 | 1086篇 |
2008年 | 1172篇 |
2007年 | 1169篇 |
2006年 | 1090篇 |
2005年 | 967篇 |
2004年 | 951篇 |
2003年 | 872篇 |
2002年 | 596篇 |
2001年 | 534篇 |
2000年 | 534篇 |
1999年 | 486篇 |
1998年 | 425篇 |
1997年 | 327篇 |
1996年 | 275篇 |
1995年 | 262篇 |
1994年 | 217篇 |
1993年 | 138篇 |
1992年 | 137篇 |
1991年 | 79篇 |
1990年 | 60篇 |
1989年 | 76篇 |
1988年 | 51篇 |
1987年 | 41篇 |
1986年 | 39篇 |
1985年 | 47篇 |
1984年 | 31篇 |
1983年 | 13篇 |
1982年 | 18篇 |
1981年 | 28篇 |
1980年 | 26篇 |
1979年 | 18篇 |
1978年 | 11篇 |
1977年 | 8篇 |
1976年 | 7篇 |
1975年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 93 毫秒
51.
Jaedong Cho John Blackwell Sergei N. Chvalun Morton Litt Yuan Wang 《Journal of Polymer Science.Polymer Physics》2004,42(13):2576-2585
As‐cast films of poly(2,5‐benzimidazole) exhibit uniplanar orientation in which the planes of the aromatic rings lie parallel to the film surface. Upon doping with phosphoric acid, the original crystalline order is lost, but the doped film can be stretched to produce films with uniaxial orientation. After thermal annealing at 540 °C, nine Bragg reflections are resolved in the fiber diagram, and these are indexed by an orthorhombic unit cell with the dimensions a = 18.1 Å, b = 3.5 Å, and c = 11.4 Å, containing four monomer units of two chains. The absence of odd‐order 00l reflections points to a 21 chain conformation, which is probably planar so that the aromatic units can be stacked along the b axis. The water and phosphoric acid contents of the crystalline structure cannot be determined exactly because of the presence of extensive amorphous regions that probably have different solvation. The best agreement between the observed and calculated intensities is for an idealized structure containing two phosphoric acids and two water molecules per unit cell. However, the phosphoric acid is probably present mainly in the form of pyrophosphoric acid and its higher oligomers. In addition, the X‐ray data are consistent with a more disordered structure containing chains with random (up and down) polarity and a lack of c‐axis registry. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2576–2585, 2004 相似文献
52.
Per B. Zetterlund Kazuki Miyake Kunihiro Goto Bunichiro Yamada 《Journal of polymer science. Part A, Polymer chemistry》2004,42(11):2640-2650
A detailed investigation of addition–fragmentation chain transfer (AFCT) in the free‐radical polymerization of methyl methacrylate (MMA) in the presence of methyl α‐(bromomethyl)acrylate (MBMA) was carried out to elucidate mechanistic details with efficient macromonomer synthesis as an underlying goal. Advanced modeling techniques were used in connection with the experimental work. Curve fitting of simulated and experimental molecular weight distributions with respect to the rate coefficient for addition of propagating radicals to MBMA (kadd) over 60–120 °C resulted in Eadd = 21.7 kJ mol?1 and Aadd = 2.18 × 106 M?1 s?1 and a very weak temperature dependence of the chain‐transfer constant (Eadd ≈ Ep). The rate coefficient for fragmentation of adduct radicals at 60 °C was estimated as kf ≈ 39 s?1 on the basis of experimental data of the MMA conversion and the concentration of 2‐carbomethoxy‐2‐propenyl end groups. The approach developed is generic and can be applied to any AFCT system in which copolymerization does not occur and in which the resulting unsaturated end groups do not undergo further reactions. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2640–2650, 2004 相似文献
53.
54.
55.
A. B. Vasil’eva A. A. Plotnikov 《Computational Mathematics and Mathematical Physics》2006,46(5):762-767
A singularly perturbed parabolic equation with a nonlinear right-hand side of a special form is examined. A numerical analytical study of such equations is performed. 相似文献
56.
Junxiang Xu 《Proceedings of the American Mathematical Society》2007,135(3):805-814
In this paper we consider a class of non-conservative dynamical system with small perturbation. By the KAM method we prove existence of Floquet invariant tori under the weakest non-resonant conditions.
57.
用分子动力学方法模拟了空位在金刚石近(001)表面的扩散过程,研究了温度对空位扩散的影响.结果表明,当温度为1000K左右时,位于近表面第二层上的空位开始向表面运动;当温度在1400—2000K时,空位完全扩散到表面.这与实验结果和其他计算结果符合得很好.同时发现,温度为1400—1800K时,空位的扩散经历了两次迁移运动,其分别对应了均方位移图中的两个极大值.在不施加任何约束的条件下得到了空位的动态扩散路径,空位在金刚石近(001)表面的扩散势垒约为042eV.并探讨了一定温度下空位数目增多及其不同排列
关键词:
金刚石
空位
扩散
分子动力学 相似文献
58.
Jie Xue Liang Chen Li Zhou Zhifeng Jia Yanping Wang Xinyuan Zhu Deyue Yan 《Journal of Polymer Science.Polymer Physics》2006,44(15):2050-2057
α‐Cyclodextrin (α‐CD) has been complexed with various poly(ethylene glycol) (PEG) derivatives in aqueous solution. It has been found that the end groups of PEG derivatives affect the complexation kinetics greatly, but have only a little influence on the thermodynamic behavior. By increasing the hydrophobicity of end groups, the complexation speeds up rapidly. On the other hand, the bulky end groups slow down the threading of polymeric guests into the cavity of CD. By changing the hydrophobicity and the size of end groups, the complexation rate can be adjusted in the range of several orders of magnitudes, which should be quite useful in the design of new supramolecular systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2050–2057, 2006 相似文献
59.
ZHANG Lin-bo LIU Xiao-hua JIANG Yuan GUO Ping SHA Li-jin LI Yu 《高等学校化学研究》2006,22(2):139-144
After establishing hemi-Parkinsonian rat models, the relationships between neuron death and the expression of several proteins, such as c-Fos, GFAP, GDNF, NF-κB and some cytokines were determined. Therapeutics experiments with notoginsenoside-Rg1 were carried out. The research results show that the expressions of GFAP, NF-Kκ and c-Fos will obviously increase in the lesion side of the striatum and the expression of GDNF will decrease, which implies that the signal transduction pathway may participate in the apoptosis in neurons. The levels of some cytokines such as TNF-α, IL-1β in the striatum of PD rat models increased compared to those of normal rats. The results of the therapeutics experiments show that notoginsenoside-Rg1 may repress the immune inflammation response and regulate the immune function through the neuro-immune molecular network. Therefore, notoginsenoside-Rg1 can be used as an effective drug for anti-oxidation and anti-inflammation, and can be used in the therapy of Parkinson's disease(PD). 相似文献
60.
A. Ulyanenkov 《Applied Surface Science》2006,253(1):106-111
Several novel methods for evaluation and interpretation of X-ray data from modern nanostructures are presented along with their applications. The background of methods and their relations to fundamental problems of X-ray analysis is shortly described. The key features of LEPTOS software, which is designed for the analysis of X-ray data measured with various geometries and setups and implements all discussed techniques, are discussed. 相似文献