分子导体:[NCBzPy][TCNQ]2和[FBzPy][TCNQ]2的合成及光谱研究

合成了两种新的取代苄基吡啶盐[NCBzPy]Cl(1)和[FBzPy]cl(2),1(或2)与LiTCNQ,TCNQ进一步反应生成[NCBzPy][TCNQ]2(3){或[FBzPy][TCNQ]2(4)}。IR研究表明：TCNQ盐中存在TCNQ^o和TCNQ^-,并形成了一维TCNQ分子柱,且TCNQ^o和TCNQ^-之间存在相互作用,有部分电荷发生转移。     

Small band gap and high ionic conduction in Cu2S

Far-infrared reflectivity spectra of Cu₂S have been measured from 20 to 700 cm⁻¹ at several temperatures through the superionic transition temperature T_c. Many bands and two broad bands were observed at low and high temperatures, respectively. From the spectra, we determined optical dielectric constant _∞, the angular frequencies of longitudinal (LO) and transverse (TO) optical phonons, and transverse effective charge. Based on these values, we suggest significant role of small band gap for high ionic conduction with small activation energy and the possibility of lattice distortion arising from an enhanced effective charge. Anomalous temperature dependence has been found for _∞ and TO–LO splitting.     

Energy Gap and Charge Transfer in Doped Quasi-One-Dimensional π-Conjugated Organic Ferromagnetic

The effects of polarons along main chain and spin-soliton-like along side-radical lattice in doped quasi-one-dimensional π-conjugated organic ferromagnets are studied by selfconsistent method. It is shown that the gap of spin-down and spin-up mid energy bands of the system decreases because new energy levels of localization states appear. The stability of organic ferromagnetic system is weakened with decreasing of the gap. In addition, it is also shown that there is charge transfer between main chain and side-radical lattice of the doped system.     

Nucleon Tensor Charge from the Quark Model

The ndcleon tensor charge is studied in the quark model. It is found that the contributions from valence constituent quarks are δu_q = 1.17 and δu_g = -0.29, while the contributions from valence current quarks are δu_v = 0.89 and δu_v = -0.22 at scale about 1 Ge V.     

利用具有非常规插入场的QCD求和规则计算核子张量荷

利用外张量场下的QCD求和规则计算了核子张量荷,其中核子插入场的核子流算符取最一般形式或称为非常规型,计算包括至维度8的项的贡献.详细分析了不同核子插入场及张量磁化率对计算核子张量荷求和规则的影响.计算表明,改变核子插入场及张量磁化率仍不能得到求和规则的稳定解,但如取最佳插入场的形式,对同位旋矢量和同位旋标量的求和规则解的稳定性有所改善.给出了在通常的对核子“QCD求和规则窗口”标度下核子张量荷的平均值.     

双掺杂LiNbO3晶体中的稳态空间电荷场

建立了包括扩散、漂移和光伏打三种输运机制下双掺杂LiNbO3晶体在用双色光进行光存储的带输运方程,并得出了小调制度下稳态空间电荷场的分析解。对双色光的光强比、体光栅的波矢、双掺杂的浓度和晶体的 氧化还原程度对空间电荷场的影响进行了数值计算和讨论。     

The REX-ISOLDE project

The Radioactive Beam Experiment REX-ISOLDE [1–3] is a pilot experiment at ISOLDE (CERN) testing the new concept of post acceleration of radioactive ion beams by using charge breeding of the ions in a high charge state ion source and the efficient acceleration of the highly charged ions in a short LINAC using modern ion accelerator structures. In order to prepare the ions for the experiments singly charged radioactive ions from the on-line mass separator ISOLDE will be cooled and bunched in a Penning trap, charge bred in an electron beam ion source (EBIS) and finally accelerated in the LINAC. The LINAC consists of a radiofrequency quadrupole (RFQ) accelerator, which accelerates the ions up to 0.3 MeV/u, an interdigital H-type (IH) structure with a final energy between 1.1 and 1.2 MeV/u and three seven gap resonators, which allow the variation of the final energy. With an energy of the radioactive beams between 0.8 MeV/u and 2.2 MeV/u a wide range of experiments in the field of nuclear spectroscopy, astrophysics and solid state physics will be addressed by REX-ISOLDE. This revised version was published online in July 2006 with corrections to the Cover Date.     

共振、混沌与束晕形成

研究强流束中的非线性共振、混沌与束晕形成的关系.给出强流束中非线性共振范围的表达式及其随束流空间电荷效应变化的数值结果和图表曲线,提出由非线性共振而激发的束晕形成的空间电荷效应极限,并分析束晕形成的过程.     

Theta-terms in nonlinear sigma-models

We trace the origin of θ-terms in nonlinear σ-models as a nonperturbative anomaly of current algebras. The nonlinear σ-models emerge as a low energy limit of fermionic σ-models. The latter describe Dirac fermions coupled to chiral bosonic fields. We discuss the geometric phases in three hierarchies of fermionic σ-models in space-time dimension (d+1) with chiral bosonic fields taking values on d-, d+1-, and d+2-dimensional spheres. The geometric phases in the first two hierarchies are θ-terms. We emphasize a relation between θ-terms and quantum numbers of solitons.     

高选择性氟离子识别受体的设计与识别机理

将酰胺识别基团耦合至基态具有分子内电荷转移特征的对硝基苯基偶氮苯胺分子中,设计合成了受体分子N-苯甲酰基4-(4'-硝基苯基偶氮基)苯胺(3),对氟离子表现出极高的识别选择性.乙腈中该受体3的最大吸收峰位于380 nm,加入氟离子后,该吸收峰强度逐渐减弱,同时在530 nm处出现新的吸收峰,后者为受体分子与氟离子形成的1:1配合物的吸收峰.溶剂极性效应实验表明,该吸收峰具有电荷转移特征.引入氟离子后受体3溶液的颜色由浅黄色转变为紫红色,可实现氟离子的裸眼检测.质子溶剂效应,1H NMR滴定为受体分子3与阴离子间的氢键作用本质提供了直接证据.