First high-resolution analysis of the 4ν1+ν3 band of nitrogen dioxide near 1.5 μm

The high-resolution absorption spectrum of the 4ν₁+ν₃ band of the ¹⁴N¹⁶O₂ molecule was recorded by CW-Cavity Ring Down Spectroscopy between 6575 and 6700 cm⁻¹. The assignments involve energy levels of the (4,0,1) vibrational state with rotational quantum numbers up to K_a=8 and N=48. A large majority of the spin-rotation energy levels were reproduced within their experimental uncertainty using a theoretical model which takes explicitly into account the Coriolis interactions between the spin-rotational levels of the (4,0,1) vibrational state and those of the (4,2,0) and of (0,9,0) dark states, the anharmonic interactions between the (4,2,0) and (0,9,0) states together with the electron spin-rotation resonances within the (4,0,1), (4,2,0) and (0,9,0) states. Precise vibrational energies, rotational, spin-rotational, and coupling constants were determined for the {(4,2,0), (0,9,0), (4,0,1)} triad of interacting states. Using these parameters and the value of the transition dipole-moment operator determined from a fit of a selection of experimental line intensities, the synthetic spectrum of the 4ν₁+ν₃ band was generated and is provided as Supplementary Material.     

Approximation by light maps and parametric Lelek maps

The class of metrizable spaces M with the following approximation property is introduced and investigated: M∈AP(n,0) if for every ε>0 and a map g:In→M there exists a 0-dimensional map g^′:In→M which is ε-homotopic to g. It is shown that this class has very nice properties. For example, if Mi∈AP(ni,0), i=1,2, then M₁×M₂∈AP(n₁+n₂,0). Moreover, M∈AP(n,0) if and only if each point of M has a local base of neighborhoods U with U∈AP(n,0). Using the properties of AP(n,0)-spaces, we generalize some results of Levin and Kato-Matsuhashi concerning the existence of residual sets of n-dimensional Lelek maps.     

零维理想关于变元正常与一般位置

设k[x_1,…,x_n]是域k上关于变量x_1,…,x_n的多项式环,I是k[x_1,x_2,…,x_n]中的零维理想.本文对I关于某个变元x_i正常与一般位置之同的关系进行探讨,并证明了零维理想对于变元x_i正常与一般位置在某种情况下的等价性.     

基于束流位置探测器的束团长度测量

分析了驱动电子束团的频域特性,研究了基于该特性进行长度测量的理论基础;使用三维模拟软件对束流位置探测器(BPM)进行建模,用模拟的方法对传输阻抗进行了数值计算;对不同长度的束团进行了测量和计算,并且分析了束团位置在真空管道中偏移对束团长度测量的影响。由测量结果可见,电子束团长度在10~100 ps(3~30 mm)时,测量误差均小于2%,满足中国工程物理研究院高平均功率自由电子激光太赫兹实验测量的使用要求。     

Fourier-transform spectroscopy of NNO in the 3800-9000 cm region and global modeling of its absorption spectrum

The absorption spectrum of ¹⁴N¹⁵N¹⁶O-enriched sample of nitrous oxide has been recorded at Doppler limited resolution with a Fourier-transform spectrometer in the spectral range 3500-9000 cm⁻¹. More than 12 000 transitions of ¹⁴N¹⁵N¹⁶O were observed and ro-vibrationally assigned on the basis of the global effective Hamiltonian model. The band-by-band analysis led to the determination of the ro-vibrational parameters of a total of 107 bands. Among the 107 bands, 80 are newly observed, for 27 others the rotational analysis is significantly extended and improved. The effective Hamiltonian parameters are determined from global fitting to the observed line positions presented in this paper and collected from the literature. As a result, a set of 117 obtained effective Hamiltonian parameters reproduces 16 134 observed line positions of 148 bands with RMS of 0.0014 cm⁻¹.     

一种投影式激光方向测量方法

为了在激光告警中实现全方位角度探测,且达到一定的探测精度,提出了一种投影式激光方向测量方法.通过计算激光照射在参量给定的遮光板上形成的投影量.求解在探测器上由不同探测象限产生的不同的探测电流的比值.再根据投影面积的比值与角度一一对应的关系可事先编码的原理.由对应程序判断激光入射方向.在软件Matlab仿真中计箅得到产生最小分辨率的四个极限角度分别为(0°,90°)、(33°,21°)、(33°,69°)、(45°,90°),并由实验得到最小分辨电压为0.05 V.通过仿真计算与实验数据证明该设计可达到最小识别角度1°的探测要求.     

Performance studies on high pressure 1-D position sensitive neutron detectors

The powder diffractometer and Hi-Q diffractometer at Dhruva reactor make use of five identical 1-D position sensitive detectors (PSDs) to scan scattering angles in the range 3° to 140°. In order to improve the overall throughput of these spectrometers, it is planned to install a bank of 15 high-efficiency and high-resolution PSDs arranged in three layers with five PSDs in each layer. With each high pressure PSD (³He 10 bar + Kr 2 bar) showing the efficiency gain of 1.8 at 1.2 Å, detector bank is expected to show overall gain of 5.5 times the present detection efficiency and reduction in data collection time by equivalent factor. The 1-D PSDs are developed in batches of five, and are characterized so that all PSDs operate at uniform parameters such as position resolution, uniformity of efficiency and linearity of response. Position spectrum indicates the differential position resolution to be ～1 mm and integral position resolution to be 3–4 mm. Broadening of position spectrum at the extreme end of sensitive length of PSD is analysed using fine shift of the beam. Dependence of position resolution and dynamic range of output pulse on the input impedance of pre-amplifier is also presented.     

分块镜扇形子镜驱动点位置优化计算

在光学综合孔径共相位检测微调系统中,分块镜子镜三自由度微动调节机构通常采用3个并联的微位移致动器来驱动各子镜,使单个分块镜具有独立的姿态调整能力,从而实现了光学共相位误差的纳米级精确校正。以理论力学原理作为切入点展开了分析,针对微动机构的稳定性、tilt-tip调节灵敏度等,根据所给定几何参数的子镜三驱动点位置对其进行了优化计算。经数学建模和仿真计算,得到了定参数子镜的三驱动点最佳位置坐标,进而归纳出了普遍适用的优化评价方法。     

CCD摄像系统镜头的畸变测量

从畸变定义出发,讨论了畸变数学模型,介绍了精密测角法与比长法综合测量畸变的原理。通过放大率法标定出CCD探测器的像素距离当量,通过质心法求出点目标的质心,质心与原点的像素距离乘以像素距离当量得到精确长度。利用正切函数求出绝对畸变值,用最小二乘法解多组数据超定方程,求出拟和公式的系数。实际计算和数据处理结果表明：畸变数学模型在中视场范围内拟合效果很好。     

The mesomorphic and photophysical properties of perylene liquid crystals with different bay-rigid spacers

Three novel perylene derivatives were prepared by introducing two phenyl (biphenyl or naphthyl)-bridging cholesterol units on bay positions and six alkyl chains on imides positions. The influences of different bay-bridging spacers on mesomorphic properties and photophysical properties were investigated. They presented the ordered hexagonal columnar liquid crystalline behaviours, although the large aromatic spacers were bridged on the bay positions. The mesomorphic and photophysical properties could be tuned effectively by the structures of spacers on bay positions. The larger and more rigid aromatic spacer on bay positions resulted in higher phase transition temperatures and stronger fluorescence emission.