Micro-CT参数对骨质疏松性椎体压缩性骨折术后复发的预测价值

本研究探讨Micro-CT参数对骨质疏松性椎体压缩性骨折(OVCF)患者术后复发的预测价值。选取OVCF患者127例,根据术后6个月骨折复发情况分为复发组(n=41)与未复发组(n=86)。患者均接受Micro-CT检查,对比两组Micro-CT参数,即骨体积分数(BV/TV)、骨小梁厚度(Tb.Th)、骨小梁间隙(Tb.Sp)、结构模型指数(SMI),以及骨密度(BMD)、骨矿含量(BMC),分析各参数与BMD、BMC及术后复发相关性,并评价各参数对术后复发的预测价值。结果显示,复发组骨体积分数(BV/TV)、骨小梁厚度(Tb.Th)低于未复发组,骨小梁间隙(Tb.Sp)、结构模型指数(SMI)高于未复发组(P<0.05);BV/TV、Tb.Th与骨密度(BMD)、骨矿含量(BMC)呈正相关,Tb.Sp、SMI与BMD、BMC呈负相关(P<0.05);将年龄、BMD、BMC等其他因素控制后,BV/TV、Tb.Sp、Tb.Th、SMI与OVCF术后骨折复发显著相关(P<0.05);BV/TV、Tb.Sp、Tb.Th、SMI联合预测OVCF术后骨折复发的曲线下面积(AUC)最大,为0.888(P<0.05)。提示Micro-CT参数在OVCF患者中呈异常表达,采用Micro-CT检查可为临床预测OVCF术后骨折复发提供科学指导。     

Ni(OH)2修饰的三聚氰胺泡沫用于可压缩超级电容器电极

通过化学镀和电化学镀的方法制备了一种Ni(OH)₂电化学活性材料修饰三聚氰胺泡沫(MF)可压缩骨架的超级电容器电极材料MF/Ni(OH)₂。MF/Ni(OH)₂可压缩电极材料表现出最佳的电容性能,例如循环稳定性(即使在40 mA/cm^-3的电流密度下经过2000次充放电循环后,可压缩电极仍能保持90.63%的初始电容)和可压缩稳定性(即使在压缩率为50%时,仍具有97.88%的电容保持率)。层状可压缩超级电容器由MF/Ni(OH)₂弹性材料作为阳极,镍/碳(Ni/C)为阴极以及实验室中常用的滤纸作隔膜材料组成。这种超级电容器装置在不同的压缩下表现出良好的电化学性能和优异的压缩稳定性。最后,使用可压缩的超级电容器来点亮LED灯,以展示其在柔性电子设备中的应用。这些优化的电化学和机械性能表明MF/Ni(OH)₂可作为可压缩超级电容器的应用中的候选电极。     

掺氧化钙及相变对高压下立方氧化锆电子结构和光吸收的影响

研究表明,立方氧化锆可作为冲击波实验中的窗口材料.为了使得该材料在常态下保持结构稳定,需添加稳定剂——氧化钙.然而,掺杂会导致其在29 GPa的冲击压力下从立方转变为斜方Ⅱ结构相.因此,该材料在冲击压缩下的电子结构和光学吸收性质以及作为光学窗口的适用压力范围是值得研究的重要问题.本文运用第一性原理的方法,分别计算了在100 GPa范围内两种结构氧化锆的电子结构和光学吸收性质.结果表明:(1)在立方结构相区,冲击压力将导致其吸收边蓝移,而在斜方Ⅱ结构相区,却使得其吸收边红移;(2)在立方结构相区,掺杂将引起能隙变窄(吸收边红移),但对于斜方II相区,却导致能隙变宽(吸收边蓝移);(3)冲击结构相变使得能隙变窄,吸收边红移.本文数据建议,掺氧化钙的立方氧化锆在95GPa的冲击压力范围内可作为光学窗口材料.     

The Compressibility of pH‐Sensitive Microgels at the Oil–Water Interface: Higher Charge Leads to Less Repulsion

pH‐responsive microgels are unique stabilizers for stimuli‐sensitive emulsions that can be broken on demand by changing the pH value. However, recent experiments have indicated that electrostatic interactions play a different role to that in conventional Pickering emulsions. The influence of charges on the interactions between microgels at the oil–water interface is now described. Compression isotherms of microgels with different charge density and architecture were determined in a Langmuir trough, and counter‐intuitive results were obtained: Charged microgels can be compressed more easily than uncharged microgels. The compressibility of microgels is thus not determined by direct Coulomb repulsion. Instead, the different swelling of the microgels in the charged and the uncharged states is proposed to be the key parameter.     

Intrinsic Flexibility of the Zeolitic Imidazolate Framework ZIF‐7 Unveiled by CO2 Adsorption and Hg Intrusion

ZIF‐7, built as an assembly of Zn^II centers and benzimidazolate ligands, shows prominent S‐shaped isotherms upon CO₂ adsorption that can be attributed to sorbate‐induced gate‐opening phenomena involving a narrow‐to‐large pore phase transition. This peculiar sorption pattern can be captured via the formulation of thermodynamic isotherms, providing a direct enthalpic and entropic view of the gate‐opening process. Relying on such an approach, an energy barrier with preferential enthalpic nature for CO₂ adsorption/desorption in the gate‐opening region could be unveiled. Moreover, the elastic energy involved during the gate‐opening process was revisited to 1.4–2.8 kJ mol^?1 of solid in the temperature range 273–323 K, matching the value measured by isostatic compression of a ZIF‐7_lp sample filled with DMF and showing a dominant entropic contribution.     

A Pressure-Induced Inverse Order–Disorder Transition in Double Perovskites

Given the consensus that pressure improves cation ordering in most of known materials, a discovery of pressure-induced disordering could require recognition of an order–disorder transition in solid-state physics/chemistry and geophysics. Double perovskites Y₂CoIrO₆ and Y₂CoRuO₆ polymorphs synthesized at 0, 6, and 15 GPa show B-site ordering, partial ordering, and disordering, respectively, accompanied by lattice compression and crystal structure alteration from monoclinic to orthorhombic symmetry. Correspondingly, the long-range ferrimagnetic ordering in the B-site ordered samples are gradually overwhelmed by B-site disorder. Theoretical calculations suggest that unusual unit-cell compressions under external pressures unexpectedly stabilize the disordered phases of Y₂CoIrO₆ and Y₂CoRuO₆.     

Anisotropic compressive behavior of rigid PVC foam at strain rates up to 200 s−1

The elevated strain rate compressive response of closed-cell polyvinyl chloride (PVC) foam at various densities is investigated. Two loading directions, (i.e., parallel and perpendicular to foam rise direction) were considered to investigate structural anisotropy. The elevated strain rates tests (up to 200 s⁻¹) were performed using a customized drop tower device. Engineering stress/strain behavior, energy dissipation, and maximum stress capacity were obtained for each density and compared against each other. Except for the lowest density of 45 kg/m³, strain rate effects were clearly observed through increased compressive strength and plateau stress when loading in the foam rise direction. The strain rate effect is more evident at higher densities. However, no significant strain rate effect was observed when loading perpendicular to the foam rise direction. Scanning electron microscopy (SEM) analysis showed that plastic hinges are the primary deformation mechanism for PVC foam cells. An analytical model has been calibrated using the experimental results and successfully predicted the mechanical response of the foam. Shape anisotropy has been measured employing the SEM images. The analytical approach was also able to predict the foam's anisotropic mechanical response.     

A Pressure‐Induced Inverse Order–Disorder Transition in Double Perovskites

Given the consensus that pressure improves cation ordering in most of known materials, a discovery of pressure‐induced disordering could require recognition of an order–disorder transition in solid‐state physics/chemistry and geophysics. Double perovskites Y₂CoIrO₆ and Y₂CoRuO₆ polymorphs synthesized at 0, 6, and 15 GPa show B‐site ordering, partial ordering, and disordering, respectively, accompanied by lattice compression and crystal structure alteration from monoclinic to orthorhombic symmetry. Correspondingly, the long‐range ferrimagnetic ordering in the B‐site ordered samples are gradually overwhelmed by B‐site disorder. Theoretical calculations suggest that unusual unit‐cell compressions under external pressures unexpectedly stabilize the disordered phases of Y₂CoIrO₆ and Y₂CoRuO₆.     

[100]LiF单晶在60 GPa以内冲击加载下的高压屈服强度特性

获取光学窗口自身的高压强度特性是开展材料高压高应变率冲击响应行为精密测量和数据反演的重要基础。利用平板撞击和双屈服面法,通过冲击-卸载、冲击-再加载原位粒子速度剖面精细测量和数据反演,获得了约60 GPa范围内[100]LiF屈服强度特性随冲击压力的变化规律。结果表明:在实验压力范围内,[100]LiF的屈服强度随加载压力的提高而显著提高,压力硬化效应显著;同时,LiF在冲击加载下的屈服强度高于磁驱准等熵加载结果,应变率硬化效应强于热软化效应。采用Huang-Asay模型确定了可描述冲击加载[100]LiF强度特性的本构模型参数,为LiF在强度、相变、层断裂等加窗测量实验中的深入应用和数据准确解读提供了重要支撑。