全文获取类型
收费全文 | 20672篇 |
免费 | 2512篇 |
国内免费 | 4074篇 |
专业分类
化学 | 17563篇 |
晶体学 | 2616篇 |
力学 | 301篇 |
综合类 | 60篇 |
数学 | 138篇 |
物理学 | 6580篇 |
出版年
2024年 | 41篇 |
2023年 | 145篇 |
2022年 | 411篇 |
2021年 | 431篇 |
2020年 | 593篇 |
2019年 | 610篇 |
2018年 | 597篇 |
2017年 | 735篇 |
2016年 | 942篇 |
2015年 | 742篇 |
2014年 | 1130篇 |
2013年 | 2187篇 |
2012年 | 1209篇 |
2011年 | 1184篇 |
2010年 | 1108篇 |
2009年 | 1241篇 |
2008年 | 1336篇 |
2007年 | 1426篇 |
2006年 | 1490篇 |
2005年 | 1347篇 |
2004年 | 1354篇 |
2003年 | 1040篇 |
2002年 | 846篇 |
2001年 | 583篇 |
2000年 | 574篇 |
1999年 | 589篇 |
1998年 | 484篇 |
1997年 | 435篇 |
1996年 | 491篇 |
1995年 | 416篇 |
1994年 | 386篇 |
1993年 | 297篇 |
1992年 | 286篇 |
1991年 | 176篇 |
1990年 | 76篇 |
1989年 | 67篇 |
1988年 | 57篇 |
1987年 | 45篇 |
1986年 | 22篇 |
1985年 | 41篇 |
1984年 | 26篇 |
1983年 | 13篇 |
1982年 | 10篇 |
1981年 | 11篇 |
1980年 | 7篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 6篇 |
1975年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
41.
The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials. 相似文献
42.
液晶显示器用导电粉的形状、尺寸及偏差对于液晶显示屏的质量控制来说是非常重要的。论述了液晶显示器(LCD)用导电粉的作用和性能要求。给出了液晶显示器用导电粉的扫描电镜图像。该图像对观测导电粉的粒径分布、导电粉在导电点中的浓度和分析导电点缺陷、提高液晶显示器的产品质量具有一定的意义。 相似文献
43.
Zhen‐Feng Chen Hong‐Li Zhou Hong Liang Yan Li Ren‐Gen Xiong Xiao‐Zeng You 《应用有机金属化学》2003,17(11):883-884
The centrosymmetric binuclear structure of [Pb2(H‐Norf)2(ONO2)4]shows the geometry around each lead(II) atom to be distorted trigonal bipyramidal with Pb–O distances ranging from 2.357(3) to 2.769(4) Å. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
44.
45.
单晶光纤损耗谱测量装置 总被引:4,自引:1,他引:3
本文描述了一套用以测量单晶光纤损耗谱的装置。本装置由卤钨灯,单色仪,积分球,AgORbCs光电倍增管以及数据采集,处理和控制系统组成。可测量300~1150nm的光谱范围。利用本装置可获得单晶光纤的吸收光谱,透过率谱,散射光谱以及散射位置谱。 相似文献
46.
47.
N. S. Oliveira J. Dorgan J. A. P. Coutinho A. Ferreira J. L. Daridon I. M. Marrucho 《Journal of Polymer Science.Polymer Physics》2007,45(5):616-625
The sorption of carbon dioxide in glassy Poly(lactic acid) (PLA) films was studied by quartz crystal microbalance (QCM) at high pressures. Two thermal treatments, melted and quenched, were performed in PLA with two different L:D contents, 80:20 and 98:2, films and compared with a third thermal protocol, annealed, and used in a previous work. The results obtained show that for pressures higher than 2 MPa, the carbon dioxide solubility is larger in PLA 80:20 than in PLA 98:2, indicating that the L:D plays a dominant role on this property. The thermal treatments only affect the gas solubility in PLA 98:2. Sorption isotherms at temperatures 303, 313, and 323 K, below the glass transition temperature of the polymer, and pressures up to 5 MPa were measured and analyzed with three different models, the dual‐mode sorption model, the Flory–Huggins equation, and a modified dual‐mode sorption model where the Henry's law term was substituted by the Flory–Huggins equation. This last model performs especially well for CO2 in PLA 80:20, due to the convex upward curvature of the solubility isotherms for that system. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 616–625, 2007 相似文献
48.
Alistair Savage 《Algebras and Representation Theory》2006,9(2):161-199
For irreducible integrable highest weight modules of the finite and affine Lie algebras of type A and D, we define an isomorphism between the geometric realization of the crystal graphs in terms of irreducible components of Nakajima
quiver varieties and the combinatorial realizations in terms of Young tableaux and Young walls. For type An(1), we extend the Young wall construction to arbitrary level, describing a combinatorial realization of the crystals in terms
of new objects which we call Young pyramids.
Presented by P. Littleman
Mathematics Subject Classifications (2000) Primary 16G10, 17B37.
Alistair Savage: This research was supported in part by the Natural Sciences and Engineering Research Council (NSERC) of Canada
and was partially conducted by the author for the Clay Mathematics Institute. 相似文献
49.
J. Mass M. Avella J. Jimnez M. Callahan E. Grant K. Rakes D. Bliss B. Wang 《Superlattices and Microstructures》2007,42(1-6):306
Understanding the luminescence of ZnO is very important for some applications. In spite of the many studies carried out, there are still some points concerning the origin of some of the luminescence emissions in ZnO crystals that require additional study; in particular, the role of extended defects remains to be a matter of controversy. We present here a cathodoluminescence analysis of the defects generated by Vickers indentation in hydrothermal HTT crystals. Special emphasis was paid to the luminescence band peaking around 3.3 eV. The origin of this band is a matter of controversy, since it has been related to different causes, extended defects being one of the candidates for this emission. The CL images were acquired around crystal defects. It is observed that the 3.3 eV emission is enhanced around the crystal defects; though it is also observed, but weaker, out of the defect regions, which suggests that there exist two luminescence emissions peaking very close to 3.3 eV. The two emissions, one related to structural defects and the other to the LO phonon replica of the free excitonic band, appear very close each other and their relative intensity should determine the shape of the spectrum. 相似文献
50.
All-electron full-potential linearized augmented plane-wave calculations of the surface energy, work function, and interlayer spacings of close-packed metal surfaces are presented, in particular, for the free-electron-like metal surfaces, Mg(0 0 0 1) and Al(1 1 1), and for the transition metal surfaces, Ti(0 0 0 1), Cu(1 1 1), Pd(1 1 1), and Pt(1 1 1). We investigate the convergence of the surface energy as a function of the number of layers in the slab, using the Cu(1 1 1) surface as an example. The results show that the surface energy, as obtained using total energies of the slab and bulk from separate calculations, converges well with respect to the number of layers in the slab. Obviously, it is necessary that bulk and surface calculations are performed with the same high accuracy. Furthermore, we discuss the performance of the local-density and generalized gradient approximations for the exchange-correlation functional in describing the various surface properties. 相似文献