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81.
A dual-electrode approach for highly selective detection of glucose based on diffusion layer theory: experiments and simulation 总被引:1,自引:0,他引:1
A dual-electrode configuration for the highly selective detection of glucose in the diffusion layer of the substrate electrode is presented. In this approach, a glassy carbon electrode (GCE, substrate) modified with a conductive layer of glucose oxidase/Nafion/graphite (GNG) was used to create an interference-free region in its diffusion layer by electrochemical depletion of interfering electroactive species. A Pt microelectrode (tip, 5 microm in radius) was located in the diffusion layer of the GNG-modified GCE (GNG-G) with the help of scanning electrochemical microscopy. Consequently, the tip of the electrode could sense glucose selectively by detecting the amount of hydrogen peroxide (H2O2) formed from the oxidization of glucose on the glucose oxidase layer. The influences of parameters, including tip-substrate distance, substrate potential, and electrolyzing time, on the interference-removing efficiency of this dual-electrode approach have been investigated systematically. When the electrolyzing time was 30 s, the tip-substrate distance was 1.8 a (9.0 microm) (where a is the radius of the tip electrode), the potentials of the tip and substrate electrodes were 0.7 V and 0.4 V, respectively, and a mixture of ascorbic acid (0.3 mM), uric acid (0.3 mM), and 4-acetaminophen (0.3 mM) had no influence on the glucose detection. In addition, the current-time responses of the tip electrode at different tip-substrate distances in a solution containing interfering species were numerically simulated. The results from the simulation are in good agreement with the experimental data. This research provides a concept of detection in the diffusion layer of a substrate electrode, as an interference-free region, for developing novel microelectrochemical devices. 相似文献
82.
J. Vzquez D. García-G. Barreda P.L. Lpez-Alemany P. Villares R. Jimnez-Garay 《Thermochimica Acta》2005,430(1-2):173-182
A method has been developed for analysing the evolution with time of the volume fraction transformed and for calculating the kinetic parameters at non-isothermal reactions in materials involving formation and growth of nuclei. By considering the assumptions of extended volume and random nucleation, a general expression of the fraction transformed as a function of time has been obtained in isothermal crystallization processes. Considering the mutual interference of regions growing from separate nuclei the Johnson–Mehl–Avrami equation has been deduced as a particular case. The application of the transformation rate equation to the non-isothermal processes has been carried out under the restriction of a nucleation which takes place early in the transformation and the nucleation frequency is zero thereafter. Under these conditions, the kinetic parameters have been deduced by using the techniques of data analysis of single-scan and multiple-scan. The theoretical method developed has been applied to the glass-crystal transformation kinetics of the semiconducting Ge0.13Sb0.23Se0.64 alloy. The kinetic parameters obtained according to both techniques differ by only about 2.5%, which confirms the reliability and accuracy of the single-scan technique when calculating the above-mentioned parameters in non-isothermal transformation processes. The phases at which the above-mentioned semiconducting glass crystallizes after the thermal process have been identified by X-ray diffraction. The diffractogram of the transformed material shows that microcrystallites of Sb2Se3 and GeSe are associated with the crystallization process, remaining a residual amorphous matrix. 相似文献
83.
《Arabian Journal of Chemistry》2022,15(12):104330
The present study was carried out to design and synthesize a number of novel aromatic carboxamide derivatives of dehydroabietylamine. The preliminary antifungal assay indicated that most of title compounds displayed moderate to good antifungal activity toward the six fungal strains in vitro. Compounds 3i, 3q, 4b and 4d showed significant antifungal activity against Sclerotinia sclerotiorum, with EC50 values ranging from 0.067 ~ 0.393 mg/L. Compounds 3i, 4b and 4d also showed pronounced mycelial growth inhibition activities against B. cinerea and A. solani. Furthermore, in the in vivo assay, compound 4b exhibited brilliant protective activity against S. sclerotiorum-infected rape leaves. Meanwhile, the in vivo bioassay on tomato plants infected by B. cinerea showed that compound 3i and 4d displayed excellent protective activity at 200 mg/L, which were near to boscalid. Primary mechanistic study revealed that 4b could inhibit sclerotia formation as well as reduce the exopolysaccharide level. SEM and TEM analysis indicated that 4b possessed a strong ability to destroy the surface morphology of mycelia, cell structure and seriously interfere with the growth of the fungal pathogen. In addition, 4b exhibited good inhibitory activity (IC50 = 23.3 ± 1.6 μM) toward succinate dehydrogenase (SDH). Molecular modeling study confirmed the binding modes between compound 4b and SDH. The above antifungal results and fungicidal mechanism study revealed that this class of dehydroabietylamine derivatives could be potential SDH inhibitors and lead compounds for novel fungicides development. 相似文献
84.
提出利用快速扫描光学延迟线(Rapid Scanning Optical Delay Line,RSOD)作为光学相干层析成像(Optical Coherence Tomography,OCT)系统的相位调制器,并采用正弦驱动方式(谐振扫描)来提高扫描频率,进而实现高频相位调制的方法.介绍了基于RSOD相位调制器的干涉信号包络解调方法,分析了大振镜低频率线性驱动、小振镜高频线性驱动和大振镜高速正弦驱动三种实施方案对OCT性能的影响,并针对谐振扫描方案中轴向扫描的非线性提出了图像畸变定量校正的方法.结果表明:RSOD大振镜谐振扫描的模式能够兼顾系统成像速度、成像范围以及系统信噪比的要求,是一种行之有效的相位调制方法. 相似文献
85.
86.
Andrey Galukhin Ilya Nikolaev Roman Nosov Sergey Vyazovkin 《Molecules (Basel, Switzerland)》2022,27(11)
This study highlights the value of nonisothermal kinetic methods in selecting temperature conditions for the isothermal preparation of microporous polymeric materials. A dicyanate ester is synthesized and the kinetics of its polymerization in diphenyl sulfone are studied by calorimetry under nonisothermal conditions. The kinetics are analyzed by a model-based approach, using the Kamal model, as well as by a model-free approach, using an advanced isoconversional method. Both approaches correctly predict the time to completion of polymerization at a given temperature. The material prepared independently at the predicted temperature is characterized by electron microscopy and CO2 adsorption measurements and is confirmed to possess a microporous structure with a multimodal distribution of micropores with two major maxima at ~0.5 and 0.8 nm. 相似文献
87.
88.
FOURIER ANALYSIS OF TEMPORAL AND SPATIAL OSCILLATIONS OF TUNNELING CURRENT IN SCANNING TUNNELING MICROSCOPY 下载免费PDF全文
Partially oxidized Si(111) surfaces and surfaces of highly oriented pyrolytic graphite (HOPG) were studied by two different ultrahigh vacuum scanning tunneling microscope (UHV-STM) systems and by an STM system working under ambient conditions, respectively. The STM current images of partially oxidized Si(111) surfaces and HOPG surfaces were analyzed by one/two-dimensional fast Fourier transformation (1D-FFT/2D-FFT). The phenomenon of temporal oscillations of tunneling current on the partially oxidized Si(111) surfaces was detected with both UHV-STM systems. Temporal as well as spatial oscillations of tunneling current appeared in highly resolved STM current images of the Si(111) surfaces simultaneously, but both kinds of oscillations could be discriminated according to their different influence on the 2D-FFT spectra of the current images, while varying the scanning range and rate. On clean HOPG surfaces only spatial oscillations of tunneling current induced by the surface structure were observed. 相似文献
89.
为提升量子点图像分割精度,降低特征识别误差,提出一种基于改进U-Net的量子点图像分割方法.首先,在预处理阶段,设计了以色彩通道为权值的灰度化算法,以提升后续分割效果.其次,在STM图像分割部分,在原始U-Net结构上引入中间过渡层以均衡网络各层特征.而后,建立数据集,并通过实验对比不同分割算法的精确度、召回率、F-measure.最后,将分割算法应用于量子点的特征识别,并测试了不同分割方式对应用的影响.实验结果显示,改进灰度化方法保留细节信息丰富,明显提升了量子点分割精度;改进U-Net的平均精确率、召回率、F-measure相较原始网络分别提升了13.83%、2.16%、8.13%.同时,实验数据表明由于分割精度的提升,量子点数量、纵横比等特征参数的识别更加精确. 相似文献
90.