全文获取类型
收费全文 | 45820篇 |
免费 | 5001篇 |
国内免费 | 7686篇 |
专业分类
化学 | 35697篇 |
晶体学 | 1934篇 |
力学 | 2889篇 |
综合类 | 388篇 |
数学 | 4957篇 |
物理学 | 12642篇 |
出版年
2024年 | 112篇 |
2023年 | 415篇 |
2022年 | 896篇 |
2021年 | 938篇 |
2020年 | 1312篇 |
2019年 | 1190篇 |
2018年 | 1064篇 |
2017年 | 1276篇 |
2016年 | 1722篇 |
2015年 | 1651篇 |
2014年 | 2026篇 |
2013年 | 3314篇 |
2012年 | 3574篇 |
2011年 | 2606篇 |
2010年 | 2256篇 |
2009年 | 2816篇 |
2008年 | 3058篇 |
2007年 | 3146篇 |
2006年 | 2924篇 |
2005年 | 2704篇 |
2004年 | 2591篇 |
2003年 | 2285篇 |
2002年 | 2368篇 |
2001年 | 1539篇 |
2000年 | 1557篇 |
1999年 | 1261篇 |
1998年 | 1112篇 |
1997年 | 904篇 |
1996年 | 893篇 |
1995年 | 773篇 |
1994年 | 748篇 |
1993年 | 552篇 |
1992年 | 563篇 |
1991年 | 333篇 |
1990年 | 276篇 |
1989年 | 211篇 |
1988年 | 208篇 |
1987年 | 148篇 |
1986年 | 132篇 |
1985年 | 157篇 |
1984年 | 119篇 |
1983年 | 96篇 |
1982年 | 97篇 |
1981年 | 88篇 |
1980年 | 81篇 |
1979年 | 80篇 |
1978年 | 57篇 |
1977年 | 62篇 |
1976年 | 47篇 |
1973年 | 50篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
R. Resel M. Oehzelt O. Lengyel T.U. Schülli G. Hlawacek C. Teichert G. Koller 《Surface science》2006,600(19):4645-4649
A para-sexiphenyl monolayer of near up-right standing molecules (nominal thickness of 30 Å) is investigated in-situ by X-ray diffraction using synchrotron radiation and ex-situ by atomic force microscopy. A terrace like morphology is observed, the step height between the terraces is approximately one molecular length. The monolayer terraces, larger than 20 μm in size, are extended along the [0 0 1] direction of the TiO2(1 1 0) substrate i.e. along the Ti-O rows of the reconstructed substrate surface. The structure of the monolayer and its epitaxial relationship to the substrate is determined by grazing incidence X-ray diffraction. Extremely sharp diffraction peaks reveal high crystalline order within the monolayer, which was found to have the bulk structure of sexiphenyl. The monolayer terraces are epitaxially oriented with the (0 0 1) plane parallel to the substrate surface (out-of-plane order). Four epitaxial relationships are observed. This in-plane alignment is determined by the arrangement of the terminal phenyl rings of the sexiphenyl molecules parallel to the oxygen rows of the substrate. 相似文献
122.
We have performed total-energy calculations to study theoretical scanning tunneling microscopy (STM) images of the Si(1 1 1)3 × 2 surfaces induced by the adsorption of alkaline-earth metals (AEMs). Previously, in a series of works on Ba/Si(1 1 1) system, we have found that the observed Si(1 1 1)3 × 1-Ba LEED phase indeed has a 3 × 2 periodicity with a Ba coverage of 1/6 ML and the HCC substrate structure. Based on results of the Ba case, we proposed that the HCC structure is also adopted for other AEM atoms, which was confirmed by our recent work. In this paper, we mainly report the STM simulations for different AEM systems to compare with existing experimental data. We discuss the difference in the detailed STM images for different AEM adsorbates. Especially, the difference in filled-state images between Mg and other AEM atoms is attributed to the strong Mg-Si interaction. 相似文献
123.
Cr-doped mullites were prepared from single-phase precursors containing up to 9.60 wt% Cr2O3 using a sol-gel technique followed by thermal treatment. Particle induced X-ray emission spectroscopy and X-ray powder diffraction were used to characterize the samples. Mullites were orthorhombic, space group Pbam. Cr doping caused the increase of unit-cell parameters. Strongest expansion was noticed along c-axis followed by a and b (Δc/c=0.089, Δa/a=0.061, Δb/b=0.045% per mole Cr2O3). A second phase, namely θ-(Al,Cr)2O3, was revealed by XRD in the sample containing 9.60 wt% Cr2O3. The structure of mullites was refined by the Rietveld method, location of Cr3+ was performed by the EPR spectroscopy. At low chromium doping level (Cr2O3 content less than ∼5 wt%) Cr3+ ions were substituted for Al3+ in the AlO6 octahedra of the mullite structure (M1 site). For higher doping level, Cr3+ ions were additionally substituted for Al3+ in the AlO6 octahedra of the second phase [θ-(Al,Cr)2O3 at 1400 °C, or α-(Al,Cr)2O3 at 1600 °C] which segregated in the system. Substitution of Cr3+ for Al3+ on M1 site in the mullite structure resulted in increase of average distances in (M1)O6 octahedron and decrease of average distances in T*O4 tetrahedron, while average distances in TO4 tetrahedron stayed almost constant. 相似文献
124.
基于超分子结构共掺杂纳米复合薄膜的制备与荧光特性 总被引:5,自引:0,他引:5
为改善功能分了的特性,提出一种基于金属纳米粒子-偶氮染料复合物共掺杂超分子结构功能材料的设计新方法.并依照此方法制备出复合材料,观测了其显微结构,测量了其紫外-可见光吸收,研究了该超分子结构复合体系的荧光特性.实验发现,由于金属银纳米粒子的掺杂,使得超分子结构复合体系中功能分子甲基橙在溶液态体系的荧光强度增强近5倍,而在两种不同结构(共混结构和包覆结构)的薄膜态超分子结构体系中,其荧光强度分别被猝灭15%和20%.研究结果表明,复合膜中采用超分子结构完全能够改善功能分子的特性. 相似文献
125.
Howel Tong 《应用数学学报(英文版)》2002,18(2):177-184
Abstract I reflect upon the development of nonlinear time series analysis since 1990 by focusing on five majorareas of development. These areas include the interface between nonlinear time series analysis and chaos,thenonparametric/semiparametric approach,nonlinear state space modelling,financial time series and nonlinearmodelling of panels of time series. 相似文献
126.
本文采用文[1,2]中提出的平衡结构法研究子系统s≥3的非线性大系统在近平衡区内的稳定性;得到了判别这类大系统稳定性的两个一般性准则. 相似文献
127.
Extension of a combined analytical/numerical initial value problem solver for unsteady periodic flow
Here we describe analytical and numerical modifications that extend the Differential Reduced Ejector/ mixer Analysis (DREA), a combined analytical/numerical, multiple species ejector/mixing code developed for preliminary design applications, to apply to periodic unsteady flow. An unsteady periodic flow modelling capability opens a range of pertinent simulation problems including pulse detonation engines (PDE), internal combustion engine ICE applications, mixing enhancement and more fundamental fluid dynamic unsteadiness, e.g. fan instability/vortex shedding problems. Although mapping between steady and periodic forms for a scalar equation is a classical problem in applied mathematics, we will show that extension to systems of equations and, moreover, problems with complex initial conditions are more challenging. Additionally, the inherent large gradient initial condition singularities that are characteristic of mixing flows and that have greatly influenced the DREA code formulation, place considerable limitations on the use of numerical solution methods. Fortunately, using the combined analytical–numerical form of the DREA formulation, a successful formulation is developed and described. Comparison of this method with experimental measurements for jet flows with excitation shows reasonable agreement with the simulation. Other flow fields are presented to demonstrate the capabilities of the model. As such, we demonstrate that unsteady periodic effects can be included within the simple, efficient, coarse grid DREA implementation that has been the original intent of the DREA development effort, namely, to provide a viable tool where more complex and expensive models are inappropriate. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
128.
Hui-Ling Li De-Jiang Qi Qing-Quan Jiang Shu-Zheng Yang 《International Journal of Theoretical Physics》2006,45(12):2428-2436
An extension of the Parikh-Wilczek's semi-classical quantum tunneling method, the tunneling radiation of the charged particle from a torus-like black hole is investigated. Difference from the uncharged mass-less particle, the geodesics of the charged massive particle tunneling from the black hole is not light-like, but determined by the phase velocity. The derived result shows that the tunneling rate depends on the emitted particle's energy and electric charge, and takes the same functional form as uncharged particle. It proves also that the exact emission spectrum is not strictly pure thermal, but is consistent with the underlying unitary theory.
PACS Numbers: 04.70.Dy, 97.60.Lf, 05.30.Ch. 相似文献
129.
Hu Haiyan 《Acta Mechanica Solida Sinica》1994,7(2):137-150
This paper deals with the numerical solution of high dimensional dynamic systems with nonsmooth characteristics, such as structural elastoplasticity, mechanical clearance and dry friction. As a stable periodic response of the system attracts its transient response, it may be extracted from the transient response somehow. The paper suggests a novel iteration scheme to extrapolate the periodic response from a short time history of its transient response by curve fitting. Compared with the current schemes such as shooting and incremental harmonic balancing, the present scheme makes full use of the information within the transient response and the system characters, then its computation efficiency has increased by an order and the numerical convergence depending on the initial iteration has greatly improved.The subject supported by the Chinese Foundation of Aeronautical Science 相似文献
130.
Non-Markovian Brownian motion in a periodic potential is studied by means of an electronic analogue simulator. Velocity spectra, the Fourier transforms of velocity autocorrelation functions, are obtained for three types of random force, that is, a white noise, an Ornstein—Uhlenbeck process, and a quasimonochromatic noise. The analogue results are in good agreement both with theoretical ones calculated with the use of a matrix-continued-fraction method, and with the results of digital simulations. An unexpected extra peak in the velocity spectrum is observed for Ornstein-Uhlenbeck noise with large correlation time. The peak is attributed to a slow oscillatory motion of the Brownian particle as it moves back and forth over several lattice spaces. Its relationship to an approximate Langevin equation is discussed. 相似文献