C(膜)/Si(SiO2)(纳米微粒)/C(膜) 的光致发光性质研究

用直流辉光溅射法结合真空镀膜法制备出了一种“多层三明治结构”的光致发光材料—C(膜 ) /Si(SiO2 ) (纳米微粒 ) /C(膜 )夹层膜 ,然后分别在 40 0、6 5 0和 75 0℃退火 1h .在波长为 2 5 0nm的紫外光激发下 ,刚制备出来未经退火处理的样品具有一个在 398nm (3.12eV)处的紫光宽带PL1峰 .在 6 5 0℃退火后 ,又出现了一个在 36 0nm (3.44eV)附近的PL2 峰 .PL1和PL2 峰形状和峰位与退火温度和激发波长无关 ,但强度却与退火温度和激发波长密切相关 .结合形态结构分析可知 ,紫光PL1峰可用量子限制 -发光中心 (QC LCs)模型进行解释 :即光激发发生在SiO2 微粒内部 ,而光发射源于SiO2 与Si界面上的缺陷中心 .紫外荧光PL2 峰则源自SiC内部的电子 空穴复合发光     

RESEARCH ON THE COLLISION EFFICIENCY OF NANO-PARTICLE-TO-WALL WITH EXTERNAL ELECTRIC FIELD

着重考虑了电场作用下,壁面排斥力对颗粒-壁面碰撞效率的影响. 采用Matlab 中的龙格库塔方法,对颗粒-壁面碰撞的压缩阶段及回弹阶段的动力学方程组进行求解,并对Maxwell 速度分布进行积分获得不同速度方向下的碰撞效率. 研究表明,颗粒的碰撞效率随着碰撞角度的增加而增大,并最终达到一个临界值,即完全凝并时的碰撞效率;且颗粒的碰撞效率将因壁面排斥力的影响而减小,即壁面排斥力在一定程度上阻碍了颗粒的凝并.     

水下滑翔器位姿估计的改进高斯混合粒子滤波器设计与验证（英文）

近年用于水下滑翔器的低成本导航系统成为研究热点,导航器件的成本与精度之间的折中问题仍然是目前的难题。针对因使用低成本的导航元件而造成低精度位姿估计的问题,提出用于位姿估计的改进高斯混合粒子滤波(IGMPF)方法。用高斯混合模型来估计非高斯噪声,改进的粒子滤波进一步提高位姿估计精度。为了验证其效果,该方法应用于自主设计的水下滑翔器导航系统中并做了车载实验,实验结果表明所提IGMPF方法在实际应用中比传统的EKF和UKF表现更优,姿态角和位移误差比EKF和UKF减小了至少30%。     

Motion of a spherical particle in a fluid forced vortex by DO M and DTM

In this study, coupled equations of the motion of a particle in a fluid forced vortex were investigated using the differential transformation method （DTM） with the Pad6 approximation and the differential quadrature method （DO_M）. The significant contribution of the work is the introduction of two new, fast and efficient solutions for a spherical particle in a forced vortex that are improvements over the previous numerical results in the literature. These methods represent approximations with a high degree of accuracy and minimal computational effort for studying the particle motion in a fluid forced vortex. In addition, the velocity profiles （angular and radial） and the position trajectory of a particle in a fluid forced vortex are described in the current study.     

PM2.5 in China: Measurements,sources, visibility and health effects,and mitigation

Concern over the health effects of fine particles in the ambient environment led the U.S. Environmental Protection Agency to develop the first standard for PM_2.5 (particulate matter less than 2.5 μm) in 1997. The Particle Technology Laboratory at the University of Minnesota has helped to establish the PM_2.5 standard by developing many instruments and samplers to perform atmospheric measurements. In this paper, we review various aspects of PM_2.5, including its measurement, source apportionment, visibility and health effects, and mitigation. We focus on PM_2.5 studies in China and where appropriate, compare them with those obtained in the U.S. Based on accurate PM_2.5 sampling, chemical analysis, and source apportionment models, the major PM_2.5 sources in China have been identified to be coal combustion, motor vehicle emissions, and industrial sources. Atmospheric visibility has been found to correlate well with PM_2.5 concentration. Sulfate, ammonium, and nitrate carried by PM_2.5, commonly found in coal burning and vehicle emissions, are the dominant contributors to regional haze in China. Short-term exposure to PM_2.5 is strongly associated with the increased risk of morbidity and mortality from cardiovascular and respiratory diseases in China. The strategy for PM_2.5 mitigation must be based on reducing the pollutants from the two primary sources of coal-fired power plants and vehicle emissions. Although conventional Particulate Emission Control Devices (PECD) such as electrostatic precipitators in Chinese coal-fired power plants are generally effective for large particles, most of them may not have high collection efficiency of PM_2.5. Baghouse filtration is gradually incorporated into the PECD to increase the PM_2.5 collection efficiency. By adopting stringent vehicle emissions standard such as Euro 5 and 6, the emissions from vehicles can be gradually reduced over the years. An integrative approach, from collaboration among academia, government, and industries, can effectively manage and mitigate the PM_2.5 pollution in China.     

Space-time correlations in turbulent flow: A review

This paper reviews some of the principal uses, over almost seven decades, of correlations, in both Eulerian and Lagrangian frames of reference, of properties of turbulent flows at variable spatial locations and variable time instants. Commonly called space—time correlations, they have been fundamental to theories and models of turbulence as well as for the analyses of experimental and direct numerical simulation turbulence data.     

无皂乳液聚合法制备非球形聚苯乙烯粒子研究

采用苯乙烯(St)、二乙烯基苯(DVB)、甲基丙烯酰氧乙基三甲基氯化铵(DMC)为单体,在乙醇和水混合介质中通过无皂乳液聚合法制备了非球形聚苯乙烯(PS)粒子。通过FT-IR、TEM和激光粒度及电位分析仪对粒子的结构、形貌、粒径以及Zeta电位进行了表征。结果表明,所合成PS粒子均含三种单体结构单元,且形貌上均为非球形;随着DVB用量的增加,PS粒子形貌更趋于球形,粒径和单分散系数均逐渐增加;随DMC用量增加,PS粒子粒径随之增加,单分散系数逐渐减小,表面Zeta电位也逐渐增加;KHCO3用量的增加能使PS粒子粒径和单分散系数均增加;随着醇水比的减小,PS粒子粒径逐渐减小,而单分散系数则逐渐增加。     

Polymer phase separation in composite latex particles. 1. Considerations for the nucleation and growth mechanism

This study addresses the question of how polymer phase separation takes place during polymerization reactions within composite latex particles. Experiments resulted in acrylic/styrene latices with two-phase structures that were analyzed via TEM. Those that resulted from the use of semi-batch reactions allowed us to observe domains that likely did not undergo phase rearrangement after they were formed within the particles. We computed the critical size of the phase-separated domains by assuming that the nucleation and growth mechanism applied to such experiments. We also computed how much these domains would increase in size by subsequent polymerization within those domains. Comparisons of predicted and experimental domain sizes and distributions showed quite reasonable agreement. The domains formed in latex particles of about 350 nm were in the 30–50-nm range. Despite the close agreement between theory and experiment, we are not convinced that phase separation occurs by nucleation and growth, as it appears to us that given the relative rates of reaction and polymer diffusion, phase separation events will often be forced to occur within the spinodal region of the phase diagram. To cite this article: J.M. Stubbs, C. R. Chimie 6 (2003).     

Features of X-ray fluorescence determination of rock-forming elements in powder samples of peat sediments

The features of rock-forming elements determination in powder samples of peat sediments are considered. Based on theoretical calculations and experimental data, the mineralogical and particle size effects on the X-ray fluorescence intensity have been estimated. For routine analysis, powder rock samples are usually milled to a particle size of 10–60 μm. Theoretically, estimated variations of rock-forming elements analytical lines intensities in different minerals are up to 30%, and the particle size effect cannot be eliminated simultaneously for all rock-forming elements. Experimental estimation shows that the impossibility of the particle size distribution control can lead to significant variations in the intensities of the analytical lines (3%–18%) that is mainly corresponding to theoretical estimation. Fine milling allowed us to achieve an average particle size of fewer than 20 μm and reduce the measurement uncertainty by 1.5–2 times. 12 samples of peat sediments with organic matter content up to 70 wt% were analyzed by X-ray fluorescence analysis using different sample preparation techniques, as well as by certified methods. The accuracy of X-ray fluorescence analysis of peat sediments prepared as pressed pellets varies from 1.5 to 11 rel% depending on compound contents. It is more than for samples prepared as fused beads, however, the proposed method can be used to determine the variations of rock-forming elements contents in peat sediments where the content variations exceed the measurement uncertainty, and accuracy of analysis is sufficient for further paleoecological reconstructions.     

Gravity-induced geometric spin Hall effect of freely falling quantum particle

We discuss a new gravitational effect that the wave packet of a free-fall quantum particle undergoes a spin-dependent transverse shift in Earth's gravitational field. This effect is similar to the geometric spin Hall effect (GSHE) (Aiello 2009 et al Phys. Rev. Lett. 103 100401 ), and can be called gravity-induced GSHE. This effect suggests that the free-fall wave packets of opposite spin-polarized quantum particles can be split in the direction perpendicular to spin and gravity.