自发参量下转换双光子场的产生及其在光学计量中的应用

讨论自发参量魃光子场的产生机理，提出一种基于自发参量下转换双光子场绝在量子效率新方法。基于这一方法地光子计数型电倍增管的量子效率进行测量，并将实验结果与常规方法没得的结果进行比较。     

Superiority of zoom lens coupling in designing a novel X-ray image detector

We design a novel X-ray image detector by lens coupling a Gd2O2S:Tb intensifying screen with a high performance low-light-level (L3,which often means luminescence less than 10-3 Lux) image intensifier.Different coupling effects on imaging performance between zoom lens and fix-focus lens are analyzed theoretically.In experiment,for designing a detector of 15-inch visual field,the system coupled by zoom lens is of 12.25-1p/cm resolution,while the one with fix-focus lens is 10 lp/cm.The superiority of zoom lens is validated.It is concluded that zoom lens preserves the image information better than fix-focus lens and improves the imaging system's performance in this design,which is referential to the design of other optical imaging systems.     

Effect of polarization on the trajectory of dissipative solitons

We show that the optical Magnus effect for dissipative solitons is determined not only by the helicity but also by the topological index, i.e., by the magnetic quantum number or by the projection of the soliton orbital moment on its trajectory. In the case of inhomogeneous media, we find a relation between the optical Magnus effect and the nonholonomy of the field of unit vectors tangent to the trajectory. __________ Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 158, No. 1, pp. 126–134, January, 2009.     

Synthesis and characterization of fluorene‐based rod–coil liquid crystal polymers

A series of fluorene‐based rod–coil liquid crystal polymers with different lengths of the coil segments on backbones were designed and synthesized by a palladium‐catalyzed Suzuki coupling‐reaction. The thermal stability, the UV–Vis absorption and fluorescence spectra in chloroform solution and thin film, the electrochemical properties, thermal behavior, and morphology of these rod–coil polymers were investigated. The thermal stability of these polymers steadily decreased on increasing the length of the coil segments on the backbone; their optical and electrochemical properties did not exhibit noticeable dependence on the weight fraction of the coil segments. However, the shoulder emission and the full width at the half‐maximum (FWHM) in PL spectra of the films increased, whereas the oxidation onset potentials and the corresponding HOMO energy levels decreased with the increase in the weight fraction of the coil segments, which was assigned to microphase separation and formation of folded chain conformation as the weight fraction of the coil segments increased. These polymers displayed a characteristic liquid crystalline texture. The variation of the weight fraction of the coil segments obviously affected the thermal behavior and morphology of these rod–coil polymers. Copyright © 2008 John Wiley & Sons, Ltd.     

Suzuki cross‐coupling reaction of aryl and heterocyclic bromides and aromatic polybromides on a Pd(II)‐hydrotalcite catalyst

The Suzuki cross‐coupling reaction of various bromine‐containing substrates and phenylboronic acid in toluene at 90 °C on a Pd(AcO)₂Py₂ catalyst supported on an Mg? Al hydrotalcite, using K₂CO₃ as the base, was studied. The conversion and selectivity results obtained for many of the substrates were excellent and similar to those provided by more active or even homogeneous catalysts. The reactions of aryl polybromides and phenylboronic acid gave the corresponding polyaromatic compounds in variable yields depending on the particular substrate. Arylation occurred in a consecutive manner by substitution of the different Br atoms. ICP‐MS measurements of the palladium content of the catalyst performed prior to and after the reaction revealed that part of the metal is incorporated into the bulk solution; therefore, the catalytic process is not purely heterogeneous. Copyright © 2008 John Wiley & Sons, Ltd.     

Analytical approaches to the delta-Eddington model of the radiative transfer through vertically inhomogeneous optical depths

Analytical approaches have been developed for one-dimensional monochromatic delta-Eddington radiative transfer equation through a vertically inhomogeneous medium. They are based on the solution of the Riccati equation that arises from the decoupling of the two-stream radiances, and seek to approximate the exponent functions in the solution as opposed to finding the solution as a whole. Depending on the case, Green–Liouville approximation or other techniques presented in this paper are utilized for finding these exponents. Though developed for atmospheric radiative transfer problems applicable to the global climate change modelling, and for non-invasive medical applications on tissue–light interactions, the techniques considered here are quiet general in nature. Hence, they can also be useful in other boundary value problems of the diffusion type that involve linear second order ordinary differential equations with variable coefficients.     

Wigner Transforms and Fractional Fourier Transforms of the First Order Optical Systems

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光学相干层析系统的耦合效率分析

在高斯光束传输理论的基础上，利用矩阵光学原理和高斯光束耦合理论，得出光学相干层析系统中参考反射镜的空间位置对系统耦合效率影响的表达式，并用计算机模拟系统的耦合效率与参考反射镜和棒透镜间的距离及参考反射镜偏转角度的关系曲线。实验结果和理论分析相符合。     

Effect of chelating agent (1,10-phenanthroline) on potassium hydrogen phthalate crystals

The influence of a new organic additive, chelating agent 1,10-phenanthroline (Phen) (∼5.0·10⁻³ M L⁻¹) on potassium hydrogen phthalate (KHP) single crystals at 30° is investigated. The crystals were grown from the aqueous solutions of pH ∼4.5 at constant temperature by solvent evaporation technique. The chelating agent leads to an increase in metastable zone width and assists the bulk growth process. The growth rate of crystals in the presence of Phen decreases considerably with an increase in impurity concentration. Not much variation is observed in FTIR and cell parameter values, determined by XRD analysis. It appears that the growth promoting effect (GPE) of Phen is caused by the adsorption of the organic additive on the prism of KHP crystals. Differential scanning calorimetry (DSC) and TG-DTA studies reveal the purity of the sample and no decomposition is observed up to the melting point. Scanning electron microscope (SEM) photographs exhibit the effectiveness of the impurity in changing the surface morphology of KHP crystals. Contrary to expectations, Phen depresses the NLO efficiency of KHP, suggesting that the molecular alignments in the presence of Phen results in cancellation effects disturbing the non-linearity.