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61.
62.
黎勇 《数学物理学报(B辑英文版)》2007,27(2):437-448
In this article, two relaxation time limits, namely, the momentum relaxation time limit and the energy relaxation time limit are considered. By the compactness argument, it is obtained that the smooth solutions of the multidimensional nonisentropic Euler-Poisson problem converge to the solutions of an energy transport model or a drift diffusion model, respectively, with respect to different time scales. 相似文献
63.
Novel oscillatory flow results of phenoxy/organoclay nanocomposites are analysed considering the blocking effect of nanostructure on polymer chain mobility. The modification provoked by this hindering effect on loss tangent spectrum is investigated. The study of three different systems, involving a pristine montmorillonite and two montmorillonites modified with one alkyl tail and two alkyl tails, respectively, leads to conclude that polymer-alkyl repulsive interactions play the most important role in the chain mobility obstruction process. Our results suggest that polymer-alkyl interactions increase with temperature. 相似文献
64.
Matthew M. Malwitz Paul D. Butler Lionel Porcar Drew P. Angelette Gudrun Schmidt 《Journal of polymer science. Part A, Polymer chemistry》2004,42(17):3102-3112
The influence of shear on viscoelastic solutions of poly(ethylene oxide) (PEO) and clay [montmorillonite, i.e., Cloisite NA+ (CNA)] was investigated with rheology and small-angle neutron scattering (SANS). The steady-state viscosity and SANS were used to measure the shear-induced orientation and relaxation of the polymer and clay platelets. Anisotropic scattering patterns developed at much lower shear rates than in pure clay solutions. The scattering anisotropy saturated at low shear rates, and the CNA clay platelets aligned with the flow, with the surface normal parallel to the gradient direction. The cessation of shear led to partial and slow randomization of the CNA platelets, whereas extremely fast relaxation was observed for laponite (LRD) platelets. These PEO–CNA networklike solutions were compared with previously reported PEO–LRD networks, and the differences and similarities, with respect to the shear orientation, relaxation, and polymer–clay interactions, were examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3102–3112, 2004 相似文献
65.
M. Stenger S. Baumhoff J.-Y. Prieur J. Joffrin J.-P. Contour 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,2(2):177-182
We present measurements of the attenuation and phase velocity of surface acoustic waves in thin YBa2Cu3O films as a function of temperature, in magnetic fields up to 3.6 T applied parallel to the c-axis of the films. We have observed anomalies in both, the attenuation and the phase velocity in the vicinity of the superconducting
critical temperature which do not depend on the magnetic field. Possible origins of these anomalies, observed, to our knowledge,
for the first time in YBa2Cu3O thin films, are discussed and compared to bulk acoustic wave experiments. We present a kind of feedback technique for surface
acoustic waves which improves the sensitivity of this type of measurement. The actual sensitivity limits are mentioned.
Received: 7 August 1997 / Revised: 7 November 1997 / Accepted: 17 November 1997 相似文献
66.
E.C. Reynhardt L. Latanowicz 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,130(2):195-208
Equations for the temperature dependence of proton and deuteron spin–lattice relaxation rates and second moments due to a complex motion consisting of classical jumps over a potential barrier and quantum mechanical tunneling through the barrier have been derived. Asymmetric double and triple potential wells are considered. These equations have been employed to analyze proton spin–lattice relaxation data for solid naphthazarin in the laboratory and rotating frames as a function of temperature. It is shown that tunneling plays an important role in the proton transfer dynamics of this compound. 相似文献
67.
Nicholas J. Curro Charles P. Slichter 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,130(2):186-194
Measurement ofT2G, the Gaussian component of the spin-echo envelope of planar Cu nuclei in high-temperature superconductors, gives important information about the real part of the Cu electron spin susceptibility. In the traditional picture of the planar Cu echo decay, the internuclear coupling is assumed to remain static with respect to spin–lattice relaxation and mutual exchange fluctuations. In some circumstances, however, this assumption breaks down. We calculate the internuclear corrections arising from spin–lattice relaxation to the conventional theory ofT2Gand show thatT2Gcan be easily corrected for these effects. We argue that mutual exchanges due to the perpendicular indirect couplings are suppressed in these materials. For YBa2Cu4O8, we find a correction on the order of 10% inT2Gand using the corrected values we find that the isotope ratio63T2G/65T2Gagrees with theory. 相似文献
68.
S.F. Lienin R. Brüschweiler R.R. Ernst 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,131(2):184-190
The viscosity-dependent retarding effect of a polymeric solvent on the rotation of small solute molecules is investigated by13C NMR relaxation measurements. It is found that the relaxation data of 1,3-dibromoadamantane in highly viscous polymeric chlorotrifluoroethene can be explained neither by isotropic nor by realistic anisotropic tumbling in a single environment. The experimental data are rationalized in terms of fast exchange between at least two environments with correlation times differing by up to two orders of magnitude. The study shows that a uniform retardation of molecular tumbling by a polymeric solvent, desirable for shifting the NMR observation window in studies of intramolecular mobility, is not always feasible. 相似文献
69.
70.
The dynamics of the one-dimensional spin glass with asymmetric interactions between neighboring spins is considered. We confine ourselves to discrete couplings with values ±J. We show that the algebraic decay of the remanent magnetization of the infinite ±J-spin chain at zero temperature is only valid for symmetric couplings. Our analytical investigations as well as computer simulations show stretched exponential decay for any finite concentration of antisymmetric bonds. Thus, the asymmetric ±J-spin chain shows an asymmetry-induced phase transition at zero temperature. 相似文献