排序方式: 共有49条查询结果,搜索用时 16 毫秒
41.
Satish G. Bodige Miguel Mendez-Rojas William H. Watson 《Journal of chemical crystallography》1999,29(8):931-942
The syntheses and structure of 2-triarylphosphoranimine-1,2,3-triazole derivatives from vicinal diazides have been investigated. Compounds derived from dichloronapththoquinone, 2,3-dichloro-5,6-dimethylbenzoquinone, and 2,3,5,6-tetrachlorobenzoquinone are included. X-ray structures, NMR, IR, UV, and cyclic voltammetry data are reported. Compound 2 crystallizes in space group
with a = 12.31(1), b = 12.469(3), c = 10.088(3) Å, = 97.19(3), = 103.79(6), = 101.84(4)°, and D
calc = 1.466 g/cm for Z = 2. Compound 4 crystallizes in space group P21/c with a = 9.044(2), b = 10.882(2), c = 19.110(4) Å, = 99.06(2)°, and D
calc = 1.324 g/cm for Z = 2. Compound 6 crystallizes in space group P21/a with a = 8.85(1), b = 14.841(8), c = 11.372(8) Å, = 107.19(3)°, and D
calc = 1.397 g/cm for Z = 4. Compound 11 crystallizes in space group P21/n with a = 8.823(3), b = 16.501(6), c = 16.221(3) Å, = 103.58(2)°, and D
calc = 1.309 g/cm for Z = 4. Compound 12 crystallizes in space group
with a = 11.606(8), b = 11.671(5), c = 10.734(3) Å, = 101.62(3), = 93.70(4), = 64.33(4)°, and D
calc = 1.438 g/cm for Z = 2. Compound 13 crystallizes in space group C2/c with a = 13.337(7), b = 9.217(6), c = 24.78(1) Å, = 102.85(5)°, and D
calc = 1.478 g/cm for Z = 8. 相似文献
42.
Highly swollen ion-exchange resins result from the polymerization of diallylamine in the presence of 2 mol% of a bis-diallyl-amino compound as the cross-linking reagent. It is shown that post cross-linking with a dihalo compound is an acceptable method for decreasing the swelling propensity of the resins. The secondary amino groups are then converted to tertiary types, although there is some formation of quaternary ammonium groups which is detrimental in ion-exchange resins which are to be regenerated thermally. The aromatic compound α,α-dichloro-p-xylene is more suitable than the less rapidly reacting aliphatic compound Br(CH2)4Br and the even slower reacting reagent Cl(CH2)4Cl. However, satisfactory products are obtained with the use of Br(CH2)6Br. The additional cross-linking of the poly-diallylamine results in a lowering of the basicity level by one to two orders of magnitude, with the electron-withdrawing aromatic product exhibiting the greatest effect. Better pH buffering properties are usually obtained when the product is subsequently treated with hot alkali, which transforms any quaternary ammonium groups present to tertiary amino types. 相似文献
43.
Pterocaryquinone,a novel 1,4-naphthoquinone derivative,was isolated from Pterocarya tonkinesis and itsstructure was elucidated by spectroscopic methods.Pterocaryquinone is a new dimeric 1,4-naphthoquinone deriva-tive having a pentacyclic skeleton with two five-membered carbon rings,which provided a novel structural skeletonfor 1,4-naphthoquinone derivatives and showed apoptosis-inducing activity toward mouse cancer tsFT210 cells. 相似文献
44.
A new naphthoquinoneimine derivative from the marine algal-derived endophytic fungus Aspergillus niger EN-13 总被引:2,自引:1,他引:2
Yi Zhang Xiao Ming Li Chang Yun Wang Bin Gui Wang 《中国化学快报》2007,18(8):951-953
Cultivation of an endophytic fungus Aspergillus niger EN-13 that was isolated from the inner tissue of the marine brown alga Colpomenia sinuosa resulted in the characterization of a new naphthoquinoneimine derivative,namely,5,7-dihydroxy-2-[1-(4- methoxy-6-oxo-6H-pyran-2-yl)-2-phenylethylamino]-[1,4]naphthoquinone.The structure of the new compound was established on the basis of various NMR spectroscopic analyses including 2D NMR techniques,EI-MS,and HR-ESI-MS.This compound displayed moderate antifungal activity. 相似文献
45.
Kamal M. El‐Shaieb 《中国化学会会志》2007,54(5):1353-1358
When 2,3‐dichloro‐1,4‐naphthoquinone (DCHNQ) ( 1 ) is allowed to react with 1‐phenylbiguanide (PBG) ( 2 ), 4‐chloro‐2,5‐dihydro‐2,5‐dioxonaphtho[1,2‐d]imidazole‐3‐carboxylic acid phenyl amide ( 4 ), 6‐chloro‐8‐phenylamino‐9H‐7,9,11‐triaza‐cyclohepta[a]naphthalene‐5,10‐dione ( 5 ) and 4‐dimethyl‐amino‐5,10‐dioxo‐2‐phenylimino‐5,10‐dihydro‐2H‐benzo[g]quinazoline‐1‐carboxylic acid amide ( 6 ) were obtained. While on reacting 1 with 2‐guanidinebenzimidazole (GBI) ( 3 ) the products are 3‐(1H‐benzoimidazol‐2‐yl)‐4‐chloro‐3H‐naphtho[1,2‐d]imidazole‐2,5‐dione ( 7 ) and 3‐[3‐(1H‐benzoimidazol‐2‐yl)‐ureido]‐1,4‐dioxo‐1,4‐dihydronaphthalene‐2‐carboxylic acid dimethylamide ( 8 ). 相似文献
46.
Mohsen Abdel-Motaal Gomaa 《Tetrahedron letters》2003,44(17):3493-3496
New substituted 3-amino-5,7,8-trihalo-6-hydroxycinnoline-4-carbonitriles 7 and 8 and the 3-amino-5-chloro-6-hydroxy-benzo[h]cinnoline-4-carbonitrile 9 were synthesized in two-steps starting from tetrahalo-1,4-benzoquinones or dichloro-1,4-naphthoquinones, malononitrile and hydrazine. 相似文献
47.
Sergey G. Il'yasov Vera S. Glukhacheva Valentina A. Yermoshina Ilia V. Eltsov 《无机化学与普通化学杂志》2019,645(11):792-796
Nitro compounds of octaaza derivatives of reduced anthracene were synthesized for the first time by reaction of 2,3,4a,6,7,8a,9,10‐octaaza‐4,8‐dioxo‐3,4,4a,7,8,8a,9,9a,10,10a‐decahydroanthracene with nitric acid, mixed nitric acid/sulfuric acid, and nitric acid/acetic anhydride at between –20 and –30 °C. In addition, 1,2,4,5‐tetrazine azido derivatives were obtained by hydrolytic decomposition of the starting compound by nitrous acid. All the resultant compounds exhibit high thermal stability. 相似文献
48.
49.
《Journal of Coordination Chemistry》2012,65(4):529-539
Abstract Two new naphthoquinone derivatives, 5-dodecanoylamine-8-hydroxy-l,4-naphthoquinone (1) and 5-dodecanoylamine-8-acetoxy-l,4-naphthoquinone (2), have been prepared and characterized. Their chelating ability with Ni(II) and Co(II) have been studied. Compound (1) coordinates to the divalent metal ions as a monoanionic bidentate ligand. The complexes were found to contain two ligands and two molecules of coordinated water. The structure and bonding of the chelates are discussed based on the spectroscopic data. 相似文献