全文获取类型
收费全文 | 10091篇 |
免费 | 753篇 |
国内免费 | 566篇 |
专业分类
化学 | 8810篇 |
晶体学 | 10篇 |
力学 | 565篇 |
综合类 | 109篇 |
数学 | 512篇 |
物理学 | 1404篇 |
出版年
2024年 | 6篇 |
2023年 | 122篇 |
2022年 | 260篇 |
2021年 | 327篇 |
2020年 | 301篇 |
2019年 | 300篇 |
2018年 | 313篇 |
2017年 | 455篇 |
2016年 | 523篇 |
2015年 | 447篇 |
2014年 | 454篇 |
2013年 | 709篇 |
2012年 | 788篇 |
2011年 | 681篇 |
2010年 | 565篇 |
2009年 | 641篇 |
2008年 | 509篇 |
2007年 | 621篇 |
2006年 | 484篇 |
2005年 | 466篇 |
2004年 | 412篇 |
2003年 | 291篇 |
2002年 | 227篇 |
2001年 | 198篇 |
2000年 | 148篇 |
1999年 | 154篇 |
1998年 | 117篇 |
1997年 | 119篇 |
1996年 | 116篇 |
1995年 | 97篇 |
1994年 | 79篇 |
1993年 | 72篇 |
1992年 | 83篇 |
1991年 | 59篇 |
1990年 | 66篇 |
1989年 | 45篇 |
1988年 | 25篇 |
1987年 | 33篇 |
1986年 | 19篇 |
1985年 | 12篇 |
1984年 | 13篇 |
1983年 | 11篇 |
1982年 | 13篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 7篇 |
1977年 | 2篇 |
1971年 | 1篇 |
1966年 | 1篇 |
1959年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
31.
32.
33.
34.
采用超声波提取法提取中药何首乌中磷脂类化合物,探讨了提取溶剂用量、提取时间及超声功率等因素对磷脂提取率的影响,结合ICP-AES分析法对提取的磷脂类化合物进行了测定.结果表明,对于1.5 g何首乌,用20 mL Folch试剂,超声提取35 min,超声功率为24 kHz的条件下磷脂提取率较高. 相似文献
35.
Sarah Josefsson Rikard Westbom Lennart Mathiasson Erland Bjrklund 《Analytica chimica acta》2006,560(1-2):94-102
Pressurized liquid extractions were performed on eight sediments in order to investigate if a modified US EPA method (100 °C, 100 bar, n-heptane/acetone (1:1), 2 × 5 min) provided exhaustive extractions of polychlorinated biphenyls (PCBs) from sediment, and to study if the extractability of PCBs from the different sediments was affected by characteristics of the sediment. The recovery from the eight native sediments, contaminated in nature, was between 96.4% and 98.9%, as an average of the recoveries from 10 PCB congeners. Hundred percent recovery was defined as the sum of two consecutive extractions (2 × 5 min each) at the stated conditions. The recoveries of the individual congeners were above 94%, except for one congener in one sediment, which had a recovery of 92%. When the recoveries and different characteristics of the sediments were compared, no correlation appeared between recoveries and sediment PCB concentration, total organic carbon (TOC), soot carbon (SC) or amorphous carbon (AC). The fact that carbon did not influence the extractions was somewhat surprising, since previous experiments have indicated a connection. Instead, statistically significant (p < 0.05) correlations were observed for water content and carbon/nitrogen (C/N) ratio. The decrease in recoveries with decreased water content was attributed to less access of the solvent to the analytes due to less matrix swelling. The lowered recoveries with increased C/N ratio can indicate that a difference in structure of the organic matter exists, which influences the binding strength between the analytes and the matrix. The difference in structure can possibly be explained by different origin of the organic matter or by aging effects. Overall the method was found to be exhaustive and the excellent recoveries show that sediment characteristics do not influence the extractions markedly. 相似文献
36.
“后配额时代”中国纺织品服装出口预测 总被引:2,自引:0,他引:2
本文利用单整自回归移动平均模型,依据2000年1月至2004年12月中国纺织品服装出口额数据,对2005年和2006年中国纺织品服装出口走势进行预测分析。 相似文献
37.
Ryuhei Wakita Masanori Miyakoshi Yohji Nakatsuji Mitsuo Okahara 《Journal of inclusion phenomena and macrocyclic chemistry》1991,10(1):127-139
A series of noncyclic neutral ionophores has been synthesized by the reaction of oligoethylene glycol dihalides with 8-quinolinol. Complexation properties for alkali metal picrates were evaluated from solvent extraction and bulk liquid membrane transport experiments. Complexation profiles of the newly synthesized ionophores with a hexyl chain were similar to those of their homologues without the hexyl chain in the extraction experiments. Among them, the pentaethylene glycol derivatives showed the highest extraction efficiency and selectivity towards potassium ion. From the1H NMR spectra (400 MHz), the change in chemical shifts of the aromatic protons upon the addition of alkali metal thiocyanates suggested the existence of a stabilization effect which is caused by intramolecular stacking conformations between the quinoline rings during complexation. Aryl stacking interactions depend on the size of the cations and on the chain length of the oligoethylene glycol. The relationship between transport ability towards alkali metal cations and lipophilicity of these ionophores is also discussed. 相似文献
38.
奇异类内离差矩阵条件下的Fisher最优判据 总被引:1,自引:0,他引:1
特征提取是模式分类与识别的重要环节,Fisher最优判据是特征提取的基本方法之一.本文提出了一种计算奇异类内离差矩阵条件下Fisher最优判据的新方法,并给出了计算步骤. 相似文献
39.
The motion of a moored floating body under the action of wave forces, which is influenced by fluid forces, shape of the floating body and mooring forces, should be analysed as a complex coupled motion system. Especially under severe storm conditions or resonant motion of the floating body it is necessary to consider finite amplitude motions of the waves, the floating body and the mooring lines as well as non-linear interactions of these finite amplitude motions. The problem of a floating body has been studied on the basis of linear wave theory by many researchers. However, the finite amplitude motion under a correlated motion system has rarely been taken into account. This paper presents a numerical method for calculating the finite amplitude motion when a floating body is moored by non-linear mooring lines such as chains and cables under severe storm conditions. 相似文献
40.
鲤鱼体中鱼腥味物质的提取和鉴定 总被引:2,自引:0,他引:2
采用同时蒸馏萃取法提取鲤鱼鱼体中的挥发和半挥发性有机物,用GC/MS从提取物中分析鉴定出鱼腥味和疑是鱼腥味物质16种。包括醛、烯醛、酮和呋喃4类化合物。其中己醛、庚醛和2,4-二烯癸醛被确认为鱼腥味的化合物。研究发现,这些物质总量在鲤鱼体的鱼鳞、鱼鳃和鱼肉的分布呈现下降趋势,且其总量与鱼腥味强度之间具有可比较的对应关系。 相似文献