Phase transitions and critical phenomena of tiny grains carbon films synthesized in microwave-based vapor deposition system

Different peak trends of tiny grains carbon film have been observed under the investigations of the Raman spectroscopy and energy loss spectroscopy. Carbon films known in nanocrystalline and ultrananocrystalline diamond films are synthesized by employing microwave-based vapor deposition system. Carbon atoms exhibit several state behaviors depending on the incurred positions of their electrons. Different morphology of tiny grains under different chamber pressure is related to different rate of arriving typical energies at/near substrate surface. Those tiny grains of carbon film, which evolved in graphitic state atoms are converted to structure of smooth elements where elongation of atoms of one-dimensional arrays is as per exerting surface format forces along opposite poles from their centers. Such tiny grains in the film are the cause of v₁ peak under the investigation of the Raman spectrum because of the enhanced propagation of input laser signals through channelized inter-state electron gaps of elongated graphitic state atoms. Those tiny grains of carbon film, which evolved in fullerene state are the cause of v₂ peak. The tiny grains related to v₁ peak possess a low intensity as compared with the ones which comprised atoms having state behaviors known in their exceptional hardness. Tiny grains representing v₁ peak in the Raman spectrum are also the cause of field emission characteristic of a carbon film. Different peak recordings were made for the Raman at defined positions indicating a different state of carbon atoms for a different phase of deposited tiny grains, which is in line to their energy loss spectroscopy.     

Chemotaxonomic and morphological classification of six Indigofera species in Jazan region,KSA

The chemical constituent pattern and morphological traits of six species of Indigofera; I. argentea, I. articulata, I. colutea, I. oblongifolia, I. hochstetteri and I. sessiliflora were surveyed and compared. The chemical characters revealed one series for all species using total estimation of secondary metabolites; alkaloids, flavonoids, saponins, tannins, terpenoids and phenolic compounds by using TLC and HPLC analysis. 26 main morphological studies were distinguished as macro and micro- characters. The studied species showed different active phytochemical constituents and high number of morphological characters. Similarity matrix and cluster analysis were constructed based on all traits. The results illustrated that there were some related and distant species by using the tree display graph besides I. hochstetteri is regarded as the transitional species among the studied species. The study confirmed that more studies should be carried out to investigate about unknown phenolic compounds.     

Numerical simulation of fully nonlinear irregular wave tank in three dimension

A fully nonlinear irregular wave tank has been developed using a three‐dimensional higher‐order boundary element method (HOBEM) in the time domain. The Laplace equation is solved at each time step by an integral equation method. Based on image theory, a new Green function is applied in the whole fluid domain so that only the incident surface and free surface are discretized for the integral equation. The fully nonlinear free surface boundary conditions are integrated with time to update the wave profile and boundary values on it by a semi‐mixed Eulerian–Lagrangian time marching scheme. The incident waves are generated by feeding analytic forms on the input boundary and a ramp function is introduced at the start of simulation to avoid the initial transient disturbance. The outgoing waves are sufficiently dissipated by using a spatially varying artificial damping on the free surface before they reach the downstream boundary. Numerous numerical simulations of linear and nonlinear waves are performed and the simulated results are compared with the theoretical input waves. Copyright © 2006 John Wiley & Sons, Ltd.     

基于球形颗粒几何排列的离散元试样高效生成方法

在球体离散元数值模拟中,颗粒的初始排列状态是影响计算效率和计算结果的重要环节。本文采用前进面几何构造算法,提出了一种基于网格搜索的球形颗粒随机排列高效算法。通过求解空间三边方程,满足了粒径设置的任意大小的颗粒依次置入前进面的外侧,并与构成前进面的三个颗粒相互接触。为获得高体积分数的颗粒簇,该算法允许颗粒改变其粒径大小。采用颗粒网格化方法可以简化前进面的搜索,并由此提高排列效率。通过计算平均配位数、体积分数和二阶结构张量的特征值,对不同粒径比下得到的立方体试样进行了分析,得到试样配位数及体积分数均随着粒径比的增大而增大,且得到的试样为各向同性。此外,空间网格的大小和初始颗粒的生成点对随机排列的效率均会产生显著的影响。最后,对非规则铁路道砟进行了精细构造及压碎模拟,发现DEM模拟得到的应力-应变曲线与试验结果基本吻合,验证了该算法得到的颗粒试样在模拟道砟裂纹起裂、扩展等过程的有效性。     

若干点不交的n阶路的并图的非正规强度

本文研究了若干点不交的n阶路的并图的非正规强度.利用构造矩阵的方法,获得了若干点不交的n阶路的并图(n=1(mod 4))的非正规强度,推广了文献[5]中的结论.     

Photopolymerized silver-containing conducting polymer films. Part II. Physico-chemical characterization and mechanism of photopolymerization process

Physico-chemical and mechanical characterizations of nanophase silver-containing polypyrrole films prepared using a new photopolymerization process were performed. In general, the recorded physical, chemical, and mechanical data characteristic of these films was similar to corresponding literature data obtained from electropolymerized or chemically polymerized polypyrrole. However, photopolymerized polypyrrole films possessed an unusually high anion-to-monomer ratio of 0.8:1. Also, the photopolymerized material contained silver nanoparticles, having diameters of 2 μm or less, uniformally distributed throughout the polymer matrix. While the photopolymerization mechanism is complex, it is suggested that a pyrrole–silver cation complex is most likely the key component involved in the photopolymerization initiation step. Paper submitted for inclusion in the special issue of the Journal of Solid State Electrochemistry honoring the 85th birthday of Professor John O’M. Bockris.     

Edge irregular total labellings for graphs of linear size

As an edge variant of the well-known irregularity strength of a graph G=(V,E) we investigate edge irregular total labellings, i.e. functions f:V∪E→{1,2,…,k} such that f(u)+f(uv)+f(v)≠f(u^′)+f(u^′v^′)+f(v^′) for every pair of different edges uv,u^′v^′∈E. The smallest possible k is the total edge irregularity strength of G. Confirming a conjecture by Ivan?o and Jendrol’ for a large class of graphs we prove that the natural lower bound is tight for every graph of order n, size m and maximum degree Δ with m>111000Δ. This also implies that the probability that a random graph from G(n,p(n)) satisfies the Ivan?o-Jendrol’ Conjecture tends to 1 as n→∞ for all functions p∈[0,1]^N. Furthermore, we prove that is an upper bound for every graph G of order n and size m≥3 whose edges are not all incident to a single vertex.     

The future of coproducts from corn processing

Increased demand for ethanol as a fuel additive has resulted in dramatic growth in ethanol production. Ethanol is produced from corn by either wet milling or dry-grind processing. In wet milling, the corn kernel is fractionated into different components, resulting in several coproducts. Wet-milling plants are capital intensive because of equipment requirements; they produce large volumes of ethanol and are corporate owned. In dry-grind processing, the corn kernel is not fractionated and only one coproduct, distillers’ dried grains with solubles (DDGS), is generated. Dry-grind plants require less equipment and capital than wet mills. They generate smaller volumes of ethanol, are producer owned, and add direct benefits to rural economies. Most of the increase in ethanol production during the past decade is attributed to growth in the dry-grind industry. The marketing of coproducts provides income to offset processing costs. For dry-grind plants, this is especially important, because only one coproduct is available. Several issues could affect DDGS marketing. The increasing volume of DDGS accompanying ethanol production could reduce market value; high phosphorous content could limit the use of DDGS, because of animal waste disposal issues. Water removal is a costly processing step and affects the economics of ethanol processing. Technologies to remove germ and fiber from DDGS could produce a new coproduct suitable for feeding to nonruminants; this would expand the markets for DDGS. Reducing phosphorus in DDGS would sustain markets for conventional DDGS. The development of more efficient methods of water removal would increase the efficiency of ethanol processing and reduce the costs of processing. New technologies could contribute to greater stability of dry-grind plants.     

A numerical study of 2D integrated RBFNs incorporating Cartesian grids for solving 2D elliptic differential problems

This article reports a numerical discretization scheme, based on two‐dimensional integrated radial‐basis‐function networks (2D‐IRBFNs) and rectangular grids, for solving second‐order elliptic partial differential equations defined on 2D nonrectangular domains. Unlike finite‐difference and 1D‐IRBFN Cartesian‐grid techniques, the present discretization method is based on an approximation scheme that allows the field variable and its derivatives to be evaluated anywhere within the domain and on the boundaries, regardless of the shape of the problem domain. We discuss the following two particular strengths, which the proposed Cartesian‐grid‐based procedure possesses, namely (i) the implementation of Neumann boundary conditions on irregular boundaries and (ii) the use of high‐order integration schemes to evaluate flux integrals arising from a control‐volume discretization on irregular domains. A new preconditioning scheme is suggested to improve the 2D‐IRBFN matrix condition number. Good accuracy and high‐order convergence solutions are obtained. © 2009 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2010     

岩石类材料裂纹分叉非规则性几何的分形效应

本文考察了岩石裂纹(从晶粒尺寸的微裂纹到几千米的断层构造)的分叉在几何上存在的非规则性,在文献[10,11]的基础上,应用分形(fractal)几何建立了裂纹分叉的分形模型,分析了裂纹分叉的分形效应,从几何的角度研究了裂纹分叉使断裂韧性提高的物理力学现象,导出了一个比smith公式更合理的断裂韧性计算式。