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101.
X. Yang 《Applied Surface Science》2006,252(10):3647-3657
The room-temperature adsorption and thermally induced processes of propionic acid and pyruvic acid on Ni(1 0 0) have been investigated by electron energy loss spectroscopy (EELS). Computational vibrational analysis of the optimized bidentate structures for acid-Ni model complexes (involving the organic acid and a Ni atom) has been performed by using the two-layer ONIOM method with the Density Functional Theory and used to interpret the vibrational EELS data. Dehydrogenation of the hydroxyl group is found to result in bonding of the carboxylate group in the propionate and pyruvate adspecies to either a single Ni surface atom in a bidentate configuration or two neighbouring Ni atoms in a bridge configuration. Given the similarities in the total energies and related vibrational frequencies obtained by the calculations in the case of pyruvate adspecies, it is difficult to differentiate the alternate adsorption structure, in which the keto O and hydroxyl O atoms are bonded to a Ni atom in a five-member chelate ring configuration. Furthermore, temperature-dependent EELS studies show that both the propionate and pyruvate adspecies could decompose upon annealing to above 400 K and further dissociate to CO adspecies above 550 K and to C and/or O above 600 K. 相似文献
102.
The enthalpies of formation of simple nonmetal or metalloid oxyanions in aqueous solution are discussed. Archival values are cited and estimates are made. Trends prove evasive. 相似文献
103.
We prove equivalence of the definitions by the author and by Korevaar and Schoen of the Sobolev classes of mappings of a domain of an arithmetic n-dimensional space to a metric space. 相似文献
104.
CuPc molecules adsorbed on Au(1 1 0)-(1 × 2): growth morphology and evolution of valence band states
Fabrizio Evangelista A. RuoccoValdis Corradini M.P. DonzelloCarlo Mariani Maria Grazia Betti 《Surface science》2003,531(2):123-130
We present the growth morphology, the long-range ordering, and the evolution of the valence band electronic states of ultrathin films of copper phthalocyanine (CuPc) deposited on the Au(1 1 0)-(1 × 2) reconstructed surface, as a function of the organic molecule coverage. The low energy electron diffraction patterns present a (5 × 3) reconstruction from the early adsorption stages. High-resolution UV photoelectron spectroscopy data show the disappearance of the Au surface states related to the (1 × 2) reconstruction, and the presence of new electronic features related to the molecule-substrate interaction and to the CuPc molecular states. The CuPc highest occupied molecular orbital gradually emerges in the valence band, while the interface electronic states are quenched, upon increasing the coverage. 相似文献
105.
P. Mun F. C. Fonseca R. Muccillo R. F. Jardim 《Physica C: Superconductivity and its Applications》2003,390(4):363-373
A systematic study of the magnetic hysteresis in transport properties of polycrystalline YBa2Cu3O7−δ–Ag compounds has been made based on two kinds of measurements at 77 K and under applied magnetic fields up to 30 mT: critical current density Jc(Ba) and magnetoresistance R(Ba). The R(Ba) curves show a minimum in their decreasing branch occurring at B=Bmin which was found to be both the excitation current Iex and the maximum applied magnetic field Bam dependent. In addition, for a certain value of Bam>5 mT, we have observed that Bmin increases with increasing Iex and reaches a saturation value. The Jc(Ba) curves show a maximum in decreasing applied magnetic fields occurring at B=Bmax. We have also found that Bmax increases with increasing Bam and reaches a saturation value. The minimum in the R(Ba) and the maximum in Jc(Ba) curves were found to be related to the trapped flux within the grains. All the experimental results are discussed within the context of the flux dynamics and transport mechanisms in these high-Tc materials. 相似文献
106.
Surface free energy of a solid surface gives a direct measure of intermolecular interactions at interfaces and has a strong influence on adsorption and adhesion behaviour. However few data are available for the surface free energies of electroless Ni–P based composition coatings. In this paper, the electroless Ni–P, Ni–P-surfactant, Ni–Cu–P, Ni–P–PTFE and Ni–Cu–P–PTFE composite coatings were prepared under various coating conditions. The chemical compositions, surface morphology and thickness of the coatings were measured using an energy dispersive X-ray microanalysis (EDX), a scanning electron microscope (SEM) and a digital micrometer respectively. The contact angles of water, diiodomethane and ethylene glycol on the coatings were measured automatically using dataphysics OCA-20 contact angle analyser. The surface free energy of the coatings and their components (e.g. dispersion, polar or acid/base portions) were calculated using various methods. The experimental results showed that the incorporation of surfactant or PTFE particles into Ni–P matrixes has a significant influence on the surface free energy of the coatings, while the incorporation of copper into Ni–P matrixes has no significant influence on the surface free energy of the coatings. 相似文献
107.
108.
109.
A suitable derivative of Einstein's equations in the framework of the teleparallel equivalent of general relativity (TEGR) yields a continuity equation for the gravitational energy‐momentum. In particular, the time derivative of the total gravitational energy is given by the sum of the total fluxes of gravitational and matter fields energy. We carry out a detailed analysis of the continuity equation in the context of Bondi and Vaidya's metrics. In the former space‐time the flux of gravitational energy is given by the well known expression in terms of the square of the news function. It is known that the energy definition in the realm of the TEGR yields the ADM (Arnowitt‐Deser‐Misner) energy for appropriate boundary conditions. Here we show that the same energy definition also describes the Bondi energy. The analysis of the continuity equation in Vaidya's space‐time shows that the variation of the total gravitational energy is determined by the energy flux of matter only. 相似文献
110.