Instability of a black hole with f (R) global monopole under extended uncertainty principle

We consider the evolution of a black hole involving an f(R) global monopole based on the Extended Uncertainty Principle (EUP). The black hole evolutions refer to the instability due to the Parikh-Kraus-Wilczeck tunneling radiation or fragmentation. It is found that the EUP corrections make the entropy difference larger to encourage the black hole to radiate more significantly. We also show that the appearance of the EUP effects results in the black hole's division. The influence from the global monopole and the revision of general relativity can also adjust the black hole evolution simultaneously but cannot change the final result that the black hole will not be stable because of the EUP's effects.     

Joule–Thomson expansion of RN-AdS black hole immersed in perfect fluid dark matter

In this paper, we study the Joule–Thomson expansion for RN-Ad S black holes immersed in perfect fluid dark matter. As perfect fluid dark matter is one of the dark matter candidates, we are interested in how it influences the thermodynamic properties of black holes. Firstly, the negative cosmological constant could be interpreted as thermodynamic pressure and its conjugate quantity as the thermodynamic volume, which give us more physical insights into the black hole. Moreover, we derive the thermodynamic definitions and study the critical behaviour of the black hole. Secondly,the explicit expression of Joule–Thomson coefficient is obtained from the basic formulas of the pressure, the volume, the entropy and the temperature. Then, we obtain the inversion curves in terms of charge Q and parameter λ. Furthermore, we analyse the isenthalpic curve in T–P graph with the cooling–heating region determined by the inversion curve. At last, we derive the ratio of minimum inversion temperature to critical temperature and compare the result with that in the RN-Ad S case.     

Residual stress field and reduction of stress intensity factors in cold-worked holes

Closed-form and semi-analytical solutions are obtained for the residual stress distributions in a plate caused by pressure acting on a central circular hole, representing the cold-work process. The material is elastic–perfectly plastic. Both Tresca and von Mises yield criteria are used and the corresponding residual stress distributions are compared. The relation between the dimension of the plastic zone and the value of internal pressure is presented. The relation between the magnitude of the residual stresses and the remote uniform tensile stress required to open symmetrical radial cracks is also presented. The reduction of the stress intensity factors of cracked open and riveted holes as a function of the internal pressure applied (or mandrel radial displacement) is investigated using numerical models for both an elastic–perfectly plastic material and for an Al 2024-T3 Alclad aluminum alloy.     

Modeling study of non-line-narrowed hole-burned spectra in weakly coupled dimers and multi-chromophoric molecular assemblies

Several different models have been proposed to explain the origin of the complex anti-hole features observed in hole-burned (HB) spectra of excitonically coupled systems such as photosynthetic complexes. This lack of consensus presents a serious constraint on the interpretation of HB spectra and the underlying electronic structures of these systems. To resolve this problem we present results of modeling studies of non-resonant HB spectra taking uncorrelated excitation energy transfer and excitonic interactions into account. Simplified analytical results are compared with Monte Carlo simulations in which excitonic interactions are explicitly taken into account in order to disentangle a number of distinct effects. It is shown that these effects can accurately account for both hole shapes and the broad anti-hole structure observed in excitonically coupled systems. We argue that these models will provide a necessary framework for probing the electronic structure of these systems via HB spectroscopy.     

Modular Synthesis of Polybenzo[b]silole Compounds for Hole‐Blocking Material in Phosphorescent Organic Light Emitting Diodes

A diversity‐oriented synthetic strategy allowed us to design a series of conjugated molecules containing multiple benzosilole units that can be utilized as efficient hole‐blocking materials for phosphorescent organic light emitting diodes (OLEDs). Some of these compounds showed a performance surpassing that of the current standard, bathocuproine. The new compounds were easily synthesized in a modular fashion from a previously reported 3‐stannyl benzosilole building unit. Studies on the properties of these compounds in solution and in the solid state indicate that they possess high electron affinity, high ionization potential, and form stable amorphous films that show high electron‐drift mobility. The correlation between their molecular properties and the efficiency of the OLED device performance is also investigated.     

New implementations of MRCI in semiempirical frameworks

Multireference configuration interaction with single and double excitations (MRCISD) as well as its analytic CI gradients has been implemented in the semiempirical framework. The hole‐particle symmetry and a mixed driven model for computing coupling coefficients have been used in the new code that allows us to perform MRCI and gradient calculations with higher efficiency and less storage requirements. © 2010 Wiley Periodicals, Inc. J Comput Chem, 2010     

Quantum tunnelling of higher-dimensional Kerr-anti-de Sitter black holes beyond semi-classical approximaton

Based on the theory of Klein-Gordon scalar field particles,the Hawking radiation of a higher-dimensional Kerr-anti-de Sitter black hole with one rotational parameter is investigated using the beyond semi-classical approximation method.The corrections of quantum tunnelling probability,Hawking temperature and Bekenstein-Hawking entropy are also included.     

X‐ray collimation by crystals with precise parabolic holes based on diffractive–refractive optics

Two crystals with precise parabolic holes were used to demonstrate sagittal beam collimation by means of a diffractive–refractive double‐crystal monochromator. A new approach is introduced and beam collimation is demonstrated. Two Si(333) crystals with an asymmetry angle of α = 15° were prepared and arranged in a dispersive position (+,?,?,+). Based on theoretical calculations, this double‐crystal set‐up should provide tunable beam collimation within an energy range of 6.3–18.8 keV (Θ_B = 71–18.4°). An experiment study was performed on BM05 at ESRF. Using 8.97 keV energy, the beam profile at various distances was measured. The experimental results are in good agreement with theoretical predictions. Owing to insufficient harmonic suppression, the collimated (333) beam was overlapped by horizontally diverging (444) and (555) beams.     

Control of mixed protonic and electronic conductivity by mixing rare-earth ortho-borates

In order to develop mixed protonic and electronic conductors, we proposed a novel concept for material design that enables to control partial conductivities by fabricating solid solutions of protonic and electronic conductors. In this work, Sr-doped LaBO₃ and Sr-doped CeBO₃ were chosen as model compounds conducting protons and electron holes, respectively. Solid solutions of the above borates, Sr-doped La_1 − xCe_xBO₃, were prepared, and their electrical conductivities were investigated in 8.5 × 10²-4.2 × 10³ Pa of p(H₂O) and 1.0 × 10-1.0 × 10⁵ Pa of p(H₂) at 1073 K. From the experimental results of the gas partial pressure dependences of the conductivities, major charge carrier species were identified as a function of x. It was found that proton was the major charge carrier when x < 0.2 while the contribution of the electron hole conduction became remarkable as x increased above 0.2. The contribution of the electron hole conduction can be interpreted by the percolation model.