首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1326篇
  免费   142篇
  国内免费   101篇
化学   645篇
晶体学   4篇
力学   82篇
综合类   22篇
数学   569篇
物理学   247篇
  2024年   2篇
  2023年   10篇
  2022年   24篇
  2021年   22篇
  2020年   27篇
  2019年   42篇
  2018年   25篇
  2017年   35篇
  2016年   60篇
  2015年   50篇
  2014年   65篇
  2013年   96篇
  2012年   58篇
  2011年   82篇
  2010年   73篇
  2009年   83篇
  2008年   84篇
  2007年   78篇
  2006年   76篇
  2005年   82篇
  2004年   77篇
  2003年   88篇
  2002年   61篇
  2001年   53篇
  2000年   38篇
  1999年   32篇
  1998年   27篇
  1997年   16篇
  1996年   19篇
  1995年   10篇
  1994年   12篇
  1993年   10篇
  1992年   9篇
  1991年   7篇
  1990年   7篇
  1989年   2篇
  1988年   1篇
  1987年   2篇
  1986年   1篇
  1985年   3篇
  1984年   4篇
  1983年   3篇
  1982年   1篇
  1981年   3篇
  1980年   2篇
  1979年   2篇
  1978年   3篇
  1977年   1篇
  1936年   1篇
排序方式: 共有1569条查询结果,搜索用时 234 毫秒
991.
We present recent work of harmonic and signal analysis based on the complex Hardy space approach.  相似文献   
992.
A combinatorial approach is described for screening homogeneous CO2 reduction electrocatalysts by means of a high‐throughput 25‐well parallel electrolyzer. Active catalysts were then screened by three methods: (1) the presence of CO gas in the electrolyzer head space; (2) a pH change for the individual solutions before and after bulk electrolysis due to proton consumption during CO2 reduction; and (3) other physical attributes. Based on these screening methods, two solutions out of the 25 were selected for further study. One out of two selected solutions, nickel cyclam, a well‐known CO2 reduction electrocatalyst, was correctly identified to be the most active.  相似文献   
993.
In this paper, we consider the numerical solution of the time‐fractional telegraph equation with a nonlocal boundary condition. A novel barycentric Lagrange interpolation collocation method is developed to solve this equation. Two difficulties have been sorted: the singularity of the integration and the higher accuracy. At the same, we put forward a steady barycentric Lagrange interpolation technique to overcome the new “Runge” phenomenon in computation. Error estimates of the barycentric Lagrange interpolation and the time‐fractional telegraph system for the present method are presented in Sobolev spaces. High convergence rates of the proposed method are obtained and are consisted with the numerical values. Especially in the time dimension, we get the error bound, for h‐refinement and for nt‐density in the L2 norms. The numerical results obtained show that the proposed numerical algorithm is accurate and computationally efficient for solving time‐fractional telegraph equation. Experiments demonstrate the high convergence rates of the proposed method are consisted with the theoretical values.  相似文献   
994.
Homogeneous tertiary N,N-dimethyl-N-β-lauryl/myristyl 7/3 polyethyleneoxy n = 3–18 ethylamines, LM(EO)nAT, are niche intermediates in the synthesis of homogeneous N-alkyl (C1–C18)-N,N-dimethyl-N-β-lauryl/myristyl 7/3 polyethyleneoxy n = 3–18 ethylammonium chlorides (unitary degree of oligomerization of ethylene oxide in the polyoxyethylene chain). This paper synthetically presents the dependence of the reductive methylation yields of homogeneous primary β-lauryl/myristyl 7/3 polyethyleneoxy n = 3–18 ethylamines, LM(EO)nAP, on the reaction time (10–90 min), the temperature (70 °C), the molar ratio formic aldehyde /LM(EO)nAP (1.1/1–2.5/1), the molar ratio HCOOH/LM(EO)nAP (5/1), the degree of oligomerization of ethylene oxide in the homogeneous polyoxyethylene chain in the 3,6,9,12,18 series, and the structure of the phase-transfer catalysts. The steric effects of hydrophobic groups CH3 and C18H37 grafted onto the ammonium function, and the micellar phenomena in the vicinity of their critical micellar concentration, directly proportional to the homogeneous degree of oligomerization, were highlighted. In all cases, a steady increase in reductive methylation yields was observed, with even quantitative values obtained. The high purity of the homologous series LM(EO)nAT will allow their personalization as reference structures for the study of the evolution of basic colloidal characteristics useful in forecasting technological applications. LM(EO)nAP were obtained either by direct amidoethylation (nucleophilic addition under basic catalysis of homogeneous lauryl/myristyl 7/3 polyethoxylated n = 3, 6, 9, 12, 18 alcohols, LM(EO)nOH, to acrylamide monomer) or by cyanoethylation of LM(EO)nOH under basic catalysis at 25–50 °C, in the presence of Fe2+ cations as oligomerization/polymerization inhibitor, followed by partial acid hydrolysis of homogeneous β-alkyl (C12H25/C14H29) 7/3 polyethyleneoxy n = 3, 6, 9, 12, 18 propionitriles, LM(EO)nPN, to β-alkyl (C12H25/C14H29) 7/3 polyethyleneoxy n = 3, 6, 9, 12, 18 propionamides, LM(EO)nPD, which led to LM(EO)nAP by Hoffmann degradation. Homogeneous higher tertiary polyetheramines LM(EO)nAT were structurally characterized.  相似文献   
995.
This present study investigated engineering students’ conceptions and misconceptions related to derivative, particularly interpreting the graph of a function and constructing its derivative graph. Participants were 147 first year engineering students from four universities enrolled in first year undergraduate calculus courses with or without the incorporation of computers for the purposes of seeing the power of visualization, investigating worked examples given in steps and solving various questions related to the worked examples, assisting conceptual understanding, and/or providing feedback besides lectures in the classroom. Students were tested before and after being exposed to instruction on differentiation and integration by a diagnostic test measuring their understanding of major aspects of calculus. Follow-up interviews were conducted with 18 students. Analyses of the results revealed that A-level student's performance was improving more than non-A-level students, particularly in computer groups. The analyses of the students’ written and oral responses in all groups indicated that prototypes, poor understanding of the notion of limit, confusion between the process and the product, and difficulties in using graphical information to give meaning to symbolic representation account for the errors and the misconceptions identified.  相似文献   
996.
Adopting a discrete-time cohort-type model to represent the dynamics of a population, the problem of achieving a desired total size of the population under a balanced growth (contraction) and the problem of maintaining the desired size, once achieved, are studied. Properties of positive-time systems and M-matrices are used to develop the results, which are illustrated using simple examples. The material is presented in a format that makes it appropriate as background material for interesting applications based modelling assignments on undergraduate programmes in the mathematical sciences, applied sciences, economics and technology. All relevant properties of both positive-time systems and M-matrices are presented and clarified at the outset.  相似文献   
997.
998.
We use a computer to verify that the ideal N of all weight zero elements of any (not necessarily finite dimensional) Bernstein algebra is solvable of index ≤4. We also use a computer to verify that N 2 is nilpotent of index ≤9. We give three examples of Bernstein algebras which show that various hypotheses like finite dimensionality, finitely generatedA 2 = A, are separately not enough to force N to be nilpotent.  相似文献   
999.
1000.
In this article, we theoretically investigate relative intensity noise (RIN) in optical communication systems with fiber nonlinearities due to optical Kerr effects and higher order dispersion. The impact of modulation frequencies, launch power, and laser bias current on RIN has been illustrated. We show that RIN increases with modulating frequencies up to the resonance frequency and launch power, and decreases in the laser bias current. We also show that higher order dispersion terms have no impact on the RIN, but with first order dispersion compensation the higher order dispersion terms have significant impact at high modulating frequencies. The RIN with and without fiber nonlinearities is further investigated. It has been shown that the RIN with fiber nonlinearity is more than the RIN without nonlinearity and the effect of nonlinearity appears at higher modulation frequencies only.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号