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61.
激光诱导击穿光谱数据特征自动提取方法研究 总被引:1,自引:0,他引:1
根据激光诱导击穿光谱(LIBS)展宽主要为非线性Lorentz函数模型,利用Levenberg-Marquardt(L-M)算法对该理论模型中的待定参数进行优化估值,扣除了光谱信号中的连续背景,校正和还原了峰位和峰强,并对拟合数据点自动提取方法进行了分析;以MatrixVB与VB混合编程相结合,实现了基于L-M算法的L... 相似文献
62.
利用Nd ∶YAG脉冲激光器(波长:1064 nm)作为光源,在实验室自然大气环境下诱导产生土壤激光等离子体,通过等离子体原子发射光谱法定量分析了国家标准土壤样品中元素Cr的含量.实验上研究了在最佳实验条件下土壤中Cr的LIBS分析谱线,测定了Cr元素的定标曲线.实验结果表明,Cr元素浓度在(60—400)×10-6范围内,元素含量与光谱线强度之间有较好的线性关系;元素Cr浓度分析测量的相对标准偏差(RSD)为7.89%,定量分析结果与标准值的相对偏差为5.3%,Cr元素的检测限为1
关键词:
土壤污染
定量分析
激光诱导击穿光谱
定标曲线 相似文献
63.
We extend a hybrid DSMC/Navier–Stokes (NS) approach to unify the DSMC and the NS simulators in one framework capable of solving the mixed non‐equilibrium and near‐equilibrium flow regions efficiently. Furthermore, we use a one‐way state‐based coupling (Dirichlet–Dirichlet boundary‐condition coupling) to transfer the required information from the continuum region to the rarefied one. The current hybrid DSMC–NS frame is applied to the hypersonic flows over nanoflat plate and microcylinder cases. The achieved solutions are compared with the pure DSMC and NS solutions. The results show that the current hybrid approach predicts the surface heat transfer rate and shear stress magnitudes very accurately. Some important conclusions can be drawn from this study. For example, although the shock wave region would be a non‐equilibrium region, it is not necessary to use a pure DSMC simulator to solve it entirely. This is important when the researchers wish to predict the surface properties such as velocity slip, temperature jump, wall heat flux rate, and friction drag magnitudes accurately. Our investigation showed that our hybrid solution time would be at least 40% (for the flat plate) and 35% (for the cylinder) of the time that must be spent by a pure DSMC solver to attain the same accuracy.Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
64.
Parametric study of optical emission from two successive laser pulses produced chromium and magnesium plasma is presented.
The line emission from chromium and magnesium plasma showed an increase by more than six times for double laser pulse excitation
than for single-pulse excitation. An optimum increase in emission intensity was noted for inter-pulse delay of ∼2–3 μs for
all the elements. The experimental observations were qualitatively explained on the basis of absorption of second laser pulse
in the pre-formed (by first laser) coronal plasma by inverse Bremsstrahlung process, which were found responsible for the
excitation of more ions and atoms in the plasma. This process starts as the plasma scale length becomes greater than the laser
wavelength. This study further indicated the suitability of this technique in the field of elemental analysis 相似文献
65.
The estimation problems for the conventional step-up method (the observed breakdown voltages are not given at all) and the new step-up method (some of the observed breakdown voltages are given) are analyzed when the underlying probability distribution (of breakdown voltage level) is assumed to be gumbel distributions for minima and maxima. The new step-up test method has advantages compared to the conventional method: (1) the confidence intervals of the estimates become smaller and (2) the estimates can be obtained with higher probability. In some case of real step-up breakdown voltage test, a fit of the gumbel distribution to the data case is found to be superior to that of the normal distribution, which suggests the usefulness of the gumbel distribution for the underlying distribution in the step-up breakdown voltage test. 相似文献
66.
A good robust functional should, if possible, be efficient at the model, smooth, and have a high breakdown point. M-estimators can be made efficient and Fréchet differentiable by choosing appropriate ψ-functions but they have a breakdown point of at most 1/(p + 1) in p dimensions. On the other hand, the local smoothness of known high breakdown functionals has not been investigated. It is known that Rousseeuw's minimum volume ellipsoid estimator is not differentiable and that S-estimators based on smooth functions force a trade-off between efficiency and breakdown point. However, by using a two-step M-estimator based on the minimum volume ellipsoid we show that it is possible to obtain a highly efficient, Fréchet differentiable estimator whilst still retaining the breakdown point. This result is extended to smooth S-estimators. 相似文献
67.
Numerical solutions to the three-dimensional, unsteady, incompressible Reynolds-averaged Navier-Stokes equations have been obtained for bubble-type vortex breakdown. Two different turbulence models were employed: (1) standard K-ε and (2) an explicit, regularized algebraic Reynolds stress model. Results are computed at a Reynolds number of 10,000. The algebraic Reynolds stress model produced a breakdown bubble with a larger length-to-diameter ratio than did the K-ε model. Breakdown also occurred at lower levels of adverse pressure gradient for the algebraic stress model than for the K-ε model. In each case single-cell breakdown structures resulted. This is contrasted with numerical calculations for laminar breakdown which reveal the existence of complex multicell bubble breakdown structures. 相似文献
68.
V. I. Bukreev 《Fluid Dynamics》2005,40(5):769-776
Theoretical and experimental data which make it possible to find the flow-rate, momentum and energy of the fluid that enters the lower pool after a discontinuity breakdown (dam break) in a rectangular channel with an even bottom, a step (sharp downstream rise in the bottom), a shelf (sharp drop in the bottom), and a threshold on the bottom are presented. 相似文献
69.
70.
本文简介了前缘后掠角为75°的平板三角翼在西北工业大学NF-3低速风洞中的测力和相关的激光片光流动显示实验,给出了部分实验结果,并与文献[1-3]的结果进行了比较,虽然各种来源的结果存在着明显的差异,但NF-3风洞两种测试手段的实验结果却具有良好的相关性。 相似文献