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41.
Reactive constituents have been investigated in a molecular beam generated in the cathode surface glow area and surface boundary layer. Mixtures of nitrogen and hydrogen form NHx(x=0–4) compounds, which are of relevance in heterogeneous, plasma vs. metal nitriding reactions. Ammonia decomposition leads to NHx(x=2–4). Strong cataphoretic enrichment of hydrogen has been observed in the cathode glow area. Heterogeneous reactions of NHx with iron lead to the formation of iron nitrides via intermediates such as FeNH2–3. In a pulsed d.c. glow discharge, increased sputtering and decreased hydrogen enrichment have been observed. 相似文献
42.
高效液相色谱-电喷雾电离三级四极杆质谱检测动物源食品中氯霉素、甲砜霉素、氟苯尼考残留量 总被引:6,自引:1,他引:6
建立了动物源产品中氯霉素、甲砜霉素、氟苯尼考残留量的高效液相色谱-电喷雾电离三级四极杆质谱(LC-ESI-MS/MS)的方法。前处理方法包括添加同位素内标氯霉素-d5,碱化乙酸乙酯提取,C18小柱净化。该方法采用负离子,多反应监测氯霉素四对离子(321.0/151.9,321.0/256.6,321.0/194.2,321.0/175.4),甲砜霉素两对离子(354.1/185.0,354.1/290.0),氟苯尼考两对离子(356.0/335.9,356.0/185.1)和同位素内标氯霉素-d5(326.0/157.1)。该方法线性范围为0.1~1.6μg/kg;对不同基质样品的加标回收率为80%~112.5%;相对标准偏差小于11%;方法的测定低限为0.1μg/kg。 相似文献
43.
Chitosan was partially N‐acylated by treatment with n‐fatty acid anhydrides in a homogeneous solution in 2 vol.‐% aqueous acetic acid‐methanol (1:2 v/v). The degree of substitution (d.s.) for N‐acyl groups in the water‐soluble N‐acylchitosan derivatives was in the range of 0.42–0.82 for N‐acetyl, 0.37–0.76 for N‐propionyl, 0.52–0.71 for N‐butyryl and 0.54–0.64 for N‐pentanoyl and ca. 0.58 for N‐hexanoyl, respectively.
44.
A. Bernasconi M. Mombelli Z. Fisk H. R. Ott 《Zeitschrift für Physik B Condensed Matter》1994,94(4):423-429
The electrical resistivity (T) and the thermal conductivity (T) have been measured for UCu5 in the temperature range between 0.02 and 20 K. Two distinct anomalies in (T) are due to previously established phase transitions at approximately 15 and 1 K, respectively. They indicate considerable changes in the electronic structure of this compound, implying sizeable truncations of the Fermi surface with decreasing temperature at both transitions. In almost the entire covered temperature range the thermal conductivity is dominated by phonon contributions. Its temperature dependence is fairly well reproduced by a calculation considering phonon scattering by electrons and by point defects. At very low temperatures, asT approaches 0 K, the Wiedemann-Franz law
e
L
0
T, where
e
is the electronic part of (T) andL
0 is the Lorenz number, is almost perfectly fulfilled. 相似文献
45.
One-particle properties of the spinless fermion model with repulsion at half filling are calculated within an approach correct to first order in the inverse of the lattice dimensiond. Continuity of the limitd requires a scaling of the nearest-neighbour hopping proportional to
and of the nearest-neighbour interaction proportional to 1/d. Due to this scaling the Hartree approximation becomes exact in infinite dimensions. We show that 1/d corrections comprise the Fock diagram and the local correlation diagram in the self-consistent Dyson equation. This approach is applied to simple-cubic systems in dimensiond=1, 2 and 3. Ground state properties and the charge-density wave phase diagram are calculated. AtT=0 the inclusion of 1/d terms gives only small corrections to the leading Hartree contribution ind=2, 3. ForT>0, however, the 1/d corrections are important. They lead to a non-negligible reduction of the critical temperature. Ind=1 the 1/d corrections are very large, but they do not succeed in removing the spurious phase transition atT>0. The 1/d approach provides a good and tractable approximation ind=3 and probably ind=2, which allows also further systematic improvement. 相似文献
46.
Investigations of the superradiating cascade of sodium vapour 4P-4S-3P
1 = 2.21 µm and
2=1.14 µm) arising on the leading edge of the exciting laser pulse were carried out. The dependences of the actual delay time
D
of the
1 pulse on the population rise time of the laser-excited 4P state were measured and compared with those calculated following the existing theoretical model. The dependence of the actual delay time
D
on the inverse density of excited atoms 1/N* is also presented. Analysis of this dependence revealed the influence of the Doppler dephasing and of the second,
2, transition on the formation of the
1 superradiance. 相似文献
47.
48.
B. Vezin Ph. Dugourd D. Rayane P. Labastie J. Chevaleyre M. Broyer 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1993,26(Z1):128-130
Ionization Potentials of LinHm clusters have been measured by photoionization. As in Lin, odd-even alternations and shell closing effects are observed. In a first approximation, we find that LinH clusters behave like Lin–1 and LinH2 like Lin–2. The results may be interpreted by assuming that the bonding of one hydrogen localizes one electron and that the other electrons remain delocalized. 相似文献
49.
50.
Anna B. DenisovaVyacheslav Ya. Sosnovskikh Wim Dehaen Suzanne ToppetLuc Van Meervelt Vasiliy A. Bakulev 《Journal of fluorine chemistry》2002,115(2):183-192
Reaction of 2-hydrazinothiazoles 1 with 1-thienyl- and 1-furyl-1,3-butanediones 2a,b in methanol in the presence of hydrochloric acid mainly leads to a mixture of pyrazoles 3 and pyrazolines 4 or pyrazoles 3 and 5 in strong acidic conditions. Isomeric hydrazones 6 and pyrazolines 4 were formed and isolated in these reactions in the absence of hydrochloric acid. It has been shown that the regioselectivity in the reaction of diketones 2 with hydrazine 1 is governed by both the concentration of acid and the nature of substituents in the 1,3-diketones 2. Cyclization of hydrazones 6 is shown to occur under milder conditions than dehydration for pyrazolines 4. The new heterocyclic compounds were prepared and fully characterized by NMR spectra and by X-ray analysis for 3c. 相似文献