全文获取类型
收费全文 | 15034篇 |
免费 | 2464篇 |
国内免费 | 1370篇 |
专业分类
化学 | 11907篇 |
晶体学 | 92篇 |
力学 | 911篇 |
综合类 | 60篇 |
数学 | 1123篇 |
物理学 | 4775篇 |
出版年
2024年 | 9篇 |
2023年 | 107篇 |
2022年 | 180篇 |
2021年 | 540篇 |
2020年 | 443篇 |
2019年 | 523篇 |
2018年 | 521篇 |
2017年 | 495篇 |
2016年 | 569篇 |
2015年 | 703篇 |
2014年 | 927篇 |
2013年 | 1176篇 |
2012年 | 916篇 |
2011年 | 1098篇 |
2010年 | 934篇 |
2009年 | 1315篇 |
2008年 | 1221篇 |
2007年 | 1001篇 |
2006年 | 951篇 |
2005年 | 835篇 |
2004年 | 660篇 |
2003年 | 613篇 |
2002年 | 437篇 |
2001年 | 319篇 |
2000年 | 323篇 |
1999年 | 281篇 |
1998年 | 264篇 |
1997年 | 235篇 |
1996年 | 142篇 |
1995年 | 229篇 |
1994年 | 153篇 |
1993年 | 131篇 |
1992年 | 106篇 |
1991年 | 54篇 |
1990年 | 67篇 |
1989年 | 68篇 |
1988年 | 40篇 |
1987年 | 44篇 |
1986年 | 30篇 |
1985年 | 33篇 |
1984年 | 39篇 |
1983年 | 18篇 |
1982年 | 24篇 |
1981年 | 12篇 |
1980年 | 19篇 |
1979年 | 15篇 |
1978年 | 8篇 |
1977年 | 8篇 |
1973年 | 6篇 |
1957年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
81.
The vibronic spectra of charge transfer excitons (CTE) in a molecular one-component or alternatingly ordered two-component chain are treated in the framework of a dynamic approach (neglecting thermal excitations of the intramolecular vibrations). The model introduces two mechanisms of coupling between CTEs and vibrational quanta: (1) shift of the equilibrium positions of the nuclei in the ionized donor or acceptor; (2) change of the vibrational frequency in the ionized molecule. This model allows to generalize the simple CTE Hamiltonian and the vibronic Hamiltonian of Frenkel excitons. The linear optical susceptibility is calculated in the vibronic region (one CTE and one vibrational quantum). The double splitting of vibronics of CTEs was analyzed: (1) the splitting connected with the location of the intramolecular vibration on the donors or on the acceptors; (2) the splitting connected with the symmetry of the vibronic spectra (in the degenerate case). The general structure of the vibronic spectra of CTEs is established. It contains structureless absorption lines, which correspond to two-particle bands (the phonon is excited on a neutral molecule neighboring the donor or the acceptor) and Lorentz-type lines of one-particle states, which correspond to the bound propagation of the CTE and the phonon. 相似文献
82.
It is shown that data on the dissociation rate of deuterium obtained in an experiment at the Sudbury Neutrino Observatory provides evidence that the Continuous Spontaneous Localization wavefunction collapse model should have mass–proportional coupling to be viable. 相似文献
83.
The influence of the parameter of amplitude-phase coupling for nonlinear amplification on the phase-frequency characteristics of an injection laser in the regime of pumping current modulation has been investigated theoretically. The parameter is defined as the coefficient of proportionality between changes in the real and imaginary parts of the refractive index during variation of the density of photons in the cavity. The substantial dependence of the coefficient of phase modulation on the parameter of the amplitude-phase coupling for nonlinear amplification at small modulation frequencies is shown. A technique to determine the indicated parameter based on the frequency dependence of the ratio between the coefficients of phase and amplitude modulation is suggested. 相似文献
84.
A tight-binding (TB) hamiltonian for calcium is built with a high precision parametrization technique based on density functional calculations of the energy bands and the total energy at various lattice volumes. The new set of TB parameters is appropriate to study phenomena under pressures as high as 20 GPa. Specifically, both the metal to nonmetal transition at 4 GPa and the structural transition fcc to bcc at 19 GPa are well reproduced. These transitions and several static properties are in excellent agreement with experiments. Phonon frequencies, plasmon energy, melting temperature and the coefficient of thermal expansion were calculated with a molecular dynamics scheme of this TB hamiltonian. 相似文献
85.
Joji Ohshita Ryosuke Taketsugu Yuki Nakahara Atsutaka Kunai 《Journal of organometallic chemistry》2004,689(20):3258-3264
Selective dehydrogenative coupling of di- and trihydrosilanes with alcohols catalyzed by PdCl2 or NiCl2 afforded alkoxyhydro- and dialkoxyhydrosilanes in good yield. Further treatment of the resulting alkoxyhydrosilanes with carbon tetrachloride or allyl bromide in the presence of the same catalyst led to the formation of alkoxychloro- and alkoxybromosilanes, respectively. Similar reactions of dialkoxyhydrosilanes with carbon tetrachloride afforded dialkoxychlorosilanes in good yield, although contamination of small amounts of trialkoxysilanes and alkoxydichlorosilanes was detected in the products. Selective substitution of the alkoxyhalosilanes with nucleophiles is also reported. 相似文献
86.
Z. J. Yu L. J. Liu R. X. Zhuo 《Journal of polymer science. Part A, Polymer chemistry》2003,41(1):13-21
The ring‐opening polymerization of ε‐caprolactone (ε‐CL), initiated by carboxylic acids such as benzoic acid and chlorinated acetic acids under microwave irradiation, was investigated; with this method, no metal catalyst was necessary. The product was characterized as poly(ε‐caprolactone) (PCL) by 1H NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet spectroscopy, and gel permeation chromatography. The polymerization was significantly improved under microwave irradiation. The weight‐average molecular weight (Mw) of PCL reached 44,800 g/mol, with a polydispersity index [weight‐average molecular weight/number‐average molecular weight (Mw/Mn)] of 1.6, when a mixture of ε‐CL and benzoic acid (25/1 molar ratio) was irradiated at 680 W for 240 min, whereas PCL with Mw = 12,100 and Mw/Mn = 4.2 was obtained from the same mixture by a conventional heating method at 210 °C for 240 min. A degradation of the resultant PCL was observed during microwave polymerization with chlorinated acetic acids as initiators, and this induced a decrease in Mw of PCL. However, the degradation was hindered by benzoic acid at low concentrations. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 13–21, 2003 相似文献
87.
Vattoly J. MajoJaya Prabhakaran J.John MannJ.S. Dileep Kumar 《Tetrahedron letters》2003,44(47):8535-8537
A novel and convergent palladium catalyzed synthesis of 2-arylbenzothiazoles has been investigated. The key step in the synthesis is a Suzuki biaryl coupling of 2-bromobenzothiazole with aryl boronic acids to provide a variety of 2-arylbenzothiazole derivatives in good yield. The synthetic utility of this methodology is demonstrated by the synthesis of 2-(4-aminophenyl)-6-methoxybenzothiazole, a PET probe precursor for the in vivo imaging of Alzheimer's disease. 相似文献
88.
To improve the understanding of the electrochemical effects observed on an original potentiometric gas sensor, interactions of oxygen with the device were investigated. This gas sensor is made of a solid electrolyte (treated Na-β-alumina) associated with two metallic electrodes (gold and platinum) located in the same gas mixture. Adsorption of charged oxygen species, considered responsible for the electrical response developed by the sensor, was investigated by work function measurements. Results showed that charged oxygen species only form on partially gold or platinum covered solid electrolyte. Comparison of these results with those obtained in a previous calorimetric study of interactions between oxygen and the same materials suggests the existence of at least two different oxygen species adsorbed on the surface of the sensitive element. The first one, located on the solid electrolyte surface, is neutral and characterized by an endothermal reaction of formation. The second one is charged and probably produced at the gas/solid electrolyte/metallic electrode interface. A mechanism based on the concept of “three phase boundary” and similar to the “reverse spillover” phenomenon is proposed to account for the adsorption of these oxygen species. 相似文献
89.
D. Sasireka E. Palaniyandi K. Iyakutti 《International journal of quantum chemistry》2004,99(3):142-152
Local lattice relaxation of substitutional donors in silicon investigated using self‐consistent multiple scattering Xα (MSXα) method within the framework of the standard muffin‐tin potential approximation is extended to substitutional donors in germanium and substitutional acceptors in both silicon and germanium. Incorporating the effect of lattice relaxation surrounding the impurity makes the model suitable for both shallow and deep levels. Chemical trends of some aspects of impurity states, such as local lattice relaxation and charge transfer, of the impurities both in silicon and germanium are inferred. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2004 相似文献
90.
Alpeshkumar K. Malde Santosh A. Khedkar Evans C. Coutinho 《Journal of Physical Organic Chemistry》2007,20(2):151-160
Modification of peptides to produce peptidomimetics is of great interest, with the aim of designing potent, selective, and metabolically stable analogs having certain conformational properties. Organoboranes have been reported in the literature with a wide range of therapeutic applications. One of the therapeutically important class of molecules is amine‐carboxyboranes derived from amino acids by replacement of the Cα atom of an amino acid/peptide by boron. The conformational preferences of these peptides, with respect to backbone ω, ?, and ψ torsion angles, have been investigated by theoretical calculations. The amide bond in these molecules has the same geometry in the ground and transition states as the natural peptides. However, the boron isosteres of glycine and alanine peptides are less structured than their natural derivatives, but are distinguished by structures with a positive value for the ? angle, which is normally disfavored for natural peptides. This property could be used to build peptides with a geometry not usually seen in natural peptides. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献