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71.
C. Djurberg K. Jonason P. Nordblad 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,10(1):15-21
Experiments on the temperature and time dependence of the response function and the field cooled magnetisation of a Cu(Mn)
spin glass at temperatures below the zero field spin glass temperature are used to explore the non-equilibrium nature of the
underlying spin configuration. The results imply that a certain spin configuration is imprinted on the system as the temperature
is decreased at a constant cooling rate. The cooling rate governs the magnitude of the FC magnetisation ((H,T)). Any intermittent halt at a constant temperature, , imprints an extended spin configuration, a process that is reflected e.g. in a downward relaxation of . On continued cooling at the same rate, the magnitude of (T) remains at a lower level than that of a continuous cooling curve. These results are put into the context of the corresponding
behaviour of the response function as observed in measurements of the relaxation of the zero field cooled magnetisation.
Received 27 October 1998 and Received in final form 30 November 1998 相似文献
72.
研究了重金属氧氟硅铋酸盐玻璃 (50-x)SiO2 xBi2O3 50PbF2(x=0, 3, 5, 8, 10, 13, 15 mol%)中Er3+离子的吸收光谱、荧光光谱、荧光半高宽、荧光 寿命和热稳定性能.应用Judd Ofelt理论计算了玻璃的强度参数Ωt(t=2,4,6),应用 McCumber计算了能级4I13/2→4I15/2跃迁的受激发射截面. 结果发现荧光半高宽与Ω6有较大联系,Ω6越大,荧光半高宽越宽.对Er3+
关键词:
重金属氧氟硅铋酸盐玻璃
光谱性质
Er3+离子
Judd Ofelt参数 相似文献
73.
The effect of pressure on the conductivity of fast ion conducting AgI-Ag2O-MoO3 glasses has been investigated down to 150 K. The observed variation of conductivities appears to support the application
of cluster model to the ionic glasses.
Contribution No. 258 from the Solid State and Structural Chemistry Unit. 相似文献
74.
The Ising model with competing interactions is studied in a mean field effective medium approach. The phase diagram of such
model alloys is studied. We conclude that for all ratios of the competing interaction moments, a spin glass phase always exists
at low temperatures for certain concentration regimes. 相似文献
75.
The IR spectra of glasses of the ZnO—SrO—B2O3 system with constant additions of PbO, Al2O3, and Li2O (20 mol. % in sum) were studied. It is established that on replacement of B2O3 by ZnO, the structure of the glasses is characterized by the presence of groupings with the bridge bonds BIII— O—BIII, BIII—O—BIV, BIV—O—BIV and end groups BIII— O−; ZnO practically exerts no influence on the coordination transition [BO3] → [BO4]. At a high content of ZnO, zinc ions are present in both a six-and a four-coordinated state.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 6, pp. 778–781, November–December, 2005. 相似文献
76.
Jose G Jose G Thomas V Joseph C Ittyachen MA Unnikrishnan NV 《Journal of fluorescence》2004,14(6):733-738
Silica glass samples containing CdSe/Eu3+ ions were prepared by sol-gel route. Size distribution and optical band gap of the nanoparticles were calculated from absorption spectrum. It is observed that the presence of CdSe nanocrystallites enhances the fluorescence of europium in silica glass. The phonon sideband spectrum associated with the excitation transition 7F0-5D2 is used to analyze the electron-phonon coupling and nonradiative deexcitiation of the rare earth ions in the glass host, The observed fluorescence enhancement is discussed on the basis of phonon assisted energy transfer from electron-hole recombination of the CdSe nanocrystallites to the rare earth ion and multiphonon relaxation. 相似文献
77.
Peter?EichelsbacherEmail author Matthias?L?we 《Probability Theory and Related Fields》2004,130(4):441-472
We derive moderate deviation principles for the overlap parameter in the Hopfield model of spin glasses and neural networks. If the inverse temperature is different from the critical inverse temperature c=1 and the number of patterns M(N) satisfies M(N)/N 0, the overlap parameter multiplied by N, 1/2 < < 1, obeys a moderate deviation principle with speed N1–2 and a quadratic rate function (i.e. the Gaussian limit for = 1/2 remains visible on the moderate deviation scale). At the critical temperature we need to multiply the overlap parameter by N, 1/4 < < 1. If then M(N) satisfies (M(N)6 log N M(N)2N4 log N)/N 0, the rescaled overlap parameter obeys a moderate deviation principle with speed N1–4 and a rate function that is basically a fourth power. The random term occurring in the Central Limit theorem for the overlap at c = 1 is no longer present on a moderate deviation scale. If the scaling is even closer to N1/4, e.g. if we multiply the overlap parameter by N1/4 log log N the moderate deviation principle breaks down. The case of variable temperature converging to one is also considered. If N converges to c fast enough, i.e. faster than the non-Gaussian rate function persists, whereas for N converging to one slower than the moderate deviations principle is given by the Gaussian rate. At the borderline the moderate deviation rate function is the one at criticality plus an additional Gaussian term.Research supported by the Volkswagen-Stiftung (RiP-program at Oberwolfach, Germany).Mathematics Subject Classification (2000): 60F10 (primary), 60K35, 82B44, 82D30 (secondary) 相似文献
78.
J.A. Hodges P. Bonville A. Forget J.P. Sanchez P. Vulliet M. Rams K. Królas 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,33(2):173-181
Using 170Yb and 155Gd M?ssbauer measurements down to ∼ 0.03 K, we have examined the semiconducting pyrochlore Yb2Mo2O7 where the Mo intra-sublattice interaction is anti-ferromagnetic and the metallic pyrochlore Gd2Mo2O7 where this interaction is ferromagnetic. Additional information was obtained from susceptibility, magnetisation and 172Yb perturbed angular correlation measurements. The microscopic measurements evidence lattice disorder which is important in
Yb2Mo2O7 and modest in Gd2Mo2O7. Magnetic irreversibilities occur at 17 K in Yb2Mo2O7 and at 75 K in Gd2Mo2O7 and below these temperatures the rare earths carry magnetic moments which are induced through couplings with the Mo sublattice.
In Gd2Mo2O7, we observe the steady state Gd hyperfine populations at 0.027 K are out of thermal equilibrium, indicating that Gd and Mo
spin fluctuations persist at very low temperatures. Frustration is thus operative in this essentially isotropic pyrochlore
where the dominant Mo intra-sublattice interaction is ferromagnetic.
Received 13 January 2003 Published online 4 June 2003
RID="a"
ID="a"e-mail: hodges@drecam.saclay.cea.fr 相似文献
79.
研究了Er3+离子掺杂钡镓锗玻璃的吸收光谱、拉曼光谱和上转换光谱.分析了Er3+离子在钡镓锗玻璃中的上转换发光机理.结果表明:玻璃的最大声子能量为828cm-1,紫外截止波长为275nm.采用800nm和980nmLD激发玻璃样品,在室温下观察到强烈的上转换绿光和红光发射.随着Er3+离子浓度的增加,绿光发光强度先增加后减小,而红光发光强度呈单调递增趋势.能量分析表明:800nmLD激发产生的绿光主要源于Er3+离子4I13/2能级的激发态吸收过程;红光发射主要源于Er3+离子4I13/2能级与4I11/2能级之间的能量转移过程.980nmLD激发产生的绿光主要源于Er3+离子4I11/2能级之间的能量转移过程;而红光发射主要源于Er3+离子4I13/2能级与4I11/2能级之间的能量转移过程和4I13/2能级的激发态吸收过程.通过量子效率分析,发现采用800nmLD激发Er3+离子掺杂浓度为1mol% 的样品时,上转换绿光发光效率最高.
关键词:
上转换发光机理
3+离子掺杂')" href="#">Er3+离子掺杂
钡镓锗玻璃 相似文献
80.
If the variance of a Gaussian spin-glass Hamiltonian grows like the volume the model fulfills the Ghirlanda-Guerra identities
in terms of the normalized Hamiltonian covariance. 相似文献