全文获取类型
收费全文 | 1283篇 |
免费 | 237篇 |
国内免费 | 58篇 |
专业分类
化学 | 433篇 |
晶体学 | 6篇 |
力学 | 56篇 |
综合类 | 1篇 |
数学 | 7篇 |
物理学 | 1075篇 |
出版年
2024年 | 4篇 |
2023年 | 50篇 |
2022年 | 60篇 |
2021年 | 82篇 |
2020年 | 75篇 |
2019年 | 11篇 |
2018年 | 52篇 |
2017年 | 89篇 |
2016年 | 83篇 |
2015年 | 39篇 |
2014年 | 139篇 |
2013年 | 45篇 |
2012年 | 102篇 |
2011年 | 77篇 |
2010年 | 73篇 |
2009年 | 75篇 |
2008年 | 59篇 |
2007年 | 64篇 |
2006年 | 66篇 |
2005年 | 46篇 |
2004年 | 44篇 |
2003年 | 33篇 |
2002年 | 28篇 |
2001年 | 18篇 |
2000年 | 19篇 |
1999年 | 22篇 |
1998年 | 25篇 |
1997年 | 18篇 |
1996年 | 20篇 |
1995年 | 17篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 6篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有1578条查询结果,搜索用时 281 毫秒
61.
62.
63.
Cupric oxide is a p‐type semiconductor with a narrow band‐gap which is suitable for catalysis, electrochemical cells, field emission devices and gas sensor applications. Despite considerable efforts devoted to the preparation of the nanosized CuO, there is a lack of information about ultrasonic‐assisted (US) preparation methods. Nanosized cupric oxide was successfully prepared through different ultrasonic‐assisted (US) preparation methods. Furthermore, the influence of preparation method on the structure, morphology and optical properties of nanosized CuO has been reported. XRD patterns were identical to the single‐phase pure CuO with a monoclinic structure. The enhancement of the crystallinity and crystallite size was observed for the sample prepared through the US thermal decomposition. The absorption band of CuO nanocrystals prepared through the US liquid hydrolysis shows a clear red shift of about 40 nm compared to those obtained with other preparation methods. Our results indicated that almost spherical CuO nanoparticles with an average size of 65 nm were prepared during the US thermal decomposition, while CuO rod‐like nanostructures with an average diameter of about 16 nm were obtained via the US liquid hydrolysis method. The band gap values of nanosized CuO samples were larger than the reported value for the bulk CuO. Synthesized CuO samples by US methods with adjustable and controllable properties make the applicability of cupric oxide even more versatile. 相似文献
64.
M.A. BramantyaT. Sawada 《Journal of magnetism and magnetic materials》2011,323(10):1330-1333
Structure of magnetorheological (MR) fluids depends on the strength of the magnetic field applied and on the mode of its application. The ultrasonic wave propagation velocity changes under the effect of an external magnetic field as a result of formation of clusters arranged along the direction of the field in the MR fluids. Therefore, we propose a qualitative analysis of these clustering structures by measuring properties of ultrasonic propagation. Since the MR fluids are opaque, the non-contact inspection using this ultrasonic technique can be very useful. In this study, we measured ultrasonic propagation velocity in MR fluid influenced by an external magnetic field for different swept rate precisely. With increasing magnetic field intensity, the changes of the ultrasonic wave velocity are more pronounced. Sedimentation effect takes place in certain time for different swept rate due to magnetic particle size and it follows linear relationship in log scale. Significant differences of the ultrasonic wave velocity are established between the case when the field is swept at a constant rate and the case when it is stepped up. 相似文献
65.
R.K. Shukla Atul Kumar Alok Shukla Kirti Srivastava 《Journal of Molecular Liquids》2008,140(1-3):117-122
Density, ultrasonic velocity, surface tension, excess volume and viscosity of quaternary non-electrolyte solution n-pentane+tolune+n-heptane+cyclohexane has been experimentally determined at 25 °C over a wide range of composition. Assuming a quaternary fluid solution to be made of six binaries, a statistical approach of Prigogine–Flory–Patterson (PFP) theory has been extended to develop the expressions for dynamic viscosity, surface tension excess volume and ultrasonic velocity of quaternary fluid system. A reasonable agreement has been achieved between theory and experiment. An attempt has also bee made to explain the nature of molecular interactions involved in the light of excess thermodynamic functions whose sign and magnitude depend upon the chain length and size of the component fluids and also studied the role of order breakers (toluene and cyclohexane) on these properties. 相似文献
66.
酸浆宿萼总黄酮提取工艺的研究 总被引:1,自引:0,他引:1
采用乙醇浸泡法、回流提取法、超声提取法探讨了从酸浆宿萼中提取总黄酮类物质的最佳工艺.试验结果表明超声提取效果最好.其最佳条件是:用浓度为70%、按料液比1 : 30的比例的乙醇浸泡24 h,再用超声提取45 min,其宿萼中总黄酮类物质的提出率可达1.702 mg·g-1;对超声提取酸浆宿萼黄酮的浓缩液用聚酰胺树脂进行纯化.并通过样品的总黄酮与FeCl3、浓H2SO4.等试剂的特征反应对所得提取物进行了定性分析,确定了所得提取物为黄酮类物质. 相似文献
67.
回顾性分析了46例临床被证实为宫内胎物组织残留的病例。结果表明,流产后较长时间有不规则阴道流血,而作B超检查能发现特征性改变。声像图显示,子宫增大,宫内有异常光团和不规则液性暗区或宫腔局部膨隆,周边见很亮光条。认为诊断宫内残留组织,可以结合病只与声像技术较易诊断出来。本组超声诊断符合率达98%。对减少因宫内残留造成的子宫收缩不良、不规则阴道流血等现象,避免并发感染及导致绒癌发生等不良后果,有重要的 相似文献
68.
Various empirical theories of ultrasonic velocity have been applied to three binary liquid mixtures, under pressures up to
200 MPa and their validity have been tested. A pressure dependent study of ultrasonic velocities has been made at 303.15 K.
The agreement between theory and experiment is found to be quite satisfactory. 相似文献
69.
Hong-Wei Ge Feng Qian Yan-Chun Liang Wen-li Du Lu Wang 《Nonlinear Analysis: Real World Applications》2008,9(4):1345-1360
In this paper, we first present a learning algorithm for dynamic recurrent Elman neural networks based on a dissimilation particle swarm optimization. The proposed algorithm computes concurrently both the evolution of network structure, weights, initial inputs of the context units, and self-feedback coefficient of the modified Elman network. Thereafter, we introduce and discuss a novel control method based on the proposed algorithm. More specifically, a dynamic identifier is constructed to perform speed identification and a controller is designed to perform speed control for Ultrasonic Motors (USM). Numerical experiments show that the novel identifier and controller based on the proposed algorithm can both achieve higher convergence precision and speed than other state-of-the-art algorithms. In particular, our experiments show that the identifier can approximate the USM's nonlinear input–output mapping accurately. The effectiveness of the controller is verified using different kinds of speeds of constant, step, and sinusoidal types. Besides, a preliminary examination on a randomly perturbation also shows the robust characteristics of the two proposed models. 相似文献
70.
N. Herrmann Y. Hemar P. Lemaréchal D.J. McClements 《The European physical journal. E, Soft matter》2001,5(2):183-188
The flocculation of silicone oil-in-water emulsions ( φ = 0.1) containing quasi-monodisperse droplets was studied by ultrasound.
The ultrasonic attenuation spectra of emulsions with different particle sizes (200-1600 nm) were measured between 0.5 and
10 MHz using an interferometer. Flocculation was induced by adding excess sodium dodecyl sulphate micelles to the emulsions
to increase the attractive forces between the droplets. Droplet flocculation decreased the ultrasonic attenuation at low frequencies
because of overlap of the thermal waves caused by the close proximity of the droplets within the flocs. A mean-field model
which takes into account this effect was used to determine the droplet volume fraction within the flocs and thus to estimate
the distance between the droplets.
Received 17 July 2000 相似文献