全文获取类型
收费全文 | 5028篇 |
免费 | 302篇 |
国内免费 | 392篇 |
专业分类
化学 | 3736篇 |
晶体学 | 50篇 |
力学 | 14篇 |
综合类 | 25篇 |
数学 | 3篇 |
物理学 | 1894篇 |
出版年
2024年 | 8篇 |
2023年 | 160篇 |
2022年 | 94篇 |
2021年 | 100篇 |
2020年 | 94篇 |
2019年 | 109篇 |
2018年 | 109篇 |
2017年 | 133篇 |
2016年 | 161篇 |
2015年 | 152篇 |
2014年 | 187篇 |
2013年 | 498篇 |
2012年 | 326篇 |
2011年 | 298篇 |
2010年 | 273篇 |
2009年 | 320篇 |
2008年 | 269篇 |
2007年 | 369篇 |
2006年 | 316篇 |
2005年 | 269篇 |
2004年 | 184篇 |
2003年 | 199篇 |
2002年 | 171篇 |
2001年 | 129篇 |
2000年 | 119篇 |
1999年 | 113篇 |
1998年 | 78篇 |
1997年 | 68篇 |
1996年 | 57篇 |
1995年 | 51篇 |
1994年 | 43篇 |
1993年 | 40篇 |
1992年 | 45篇 |
1991年 | 24篇 |
1990年 | 18篇 |
1989年 | 16篇 |
1988年 | 30篇 |
1987年 | 12篇 |
1986年 | 11篇 |
1985年 | 5篇 |
1984年 | 11篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1981年 | 9篇 |
1980年 | 12篇 |
1978年 | 7篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1973年 | 4篇 |
1966年 | 1篇 |
排序方式: 共有5722条查询结果,搜索用时 453 毫秒
31.
V. V. AntiĆ M. P. AntiĆ M. N. Govedarica P. R. DvorniĆ 《Journal of polymer science. Part A, Polymer chemistry》2007,45(11):2246-2258
The kinetics of the formation of poly(carbosiloxane), as well as of alkyl-substituted poly(siloxane), by Karstedt's catalyst catalyzed hydrosilylation were investigated. Linear poly(carbosiloxane), poly[(1,1,3,3-tetramethyldisiloxanyl)ethylene], (PTMDSE), was obtained by hydrosilylation of 1,3-divinyltetramethyldisiloxane (DVTMDS) and 1,1,3,3-tetramethyldisiloxane (TMDS), while alkyl-substituted poly(siloxane), poly(methyldecylsiloxane), (PMDS), was synthesized by hydrosilylation of poly(methylhydrosiloxane) (PMHS) and 1-decene. To investigate the kinetics of PTMDSE formation, two series of experiments were performed at reaction temperatures ranging from 25 to 56 °C and with catalyst concentrations ranging from 7.0 × 10−6 to 3.1 × 10−5 mol Pt/mol CHCH2. A series of experiments was performed at reaction temperatures ranging from 28 to 48 °C, with catalyst concentrations of 7.0 ×10−6 mol of Pt per mol of CHCH2, when kinetics of PMDS formation was investigated. All reactions were carried out in bulk, with equimolar amounts of the reacting Si H and CHCH2 groups. The course of the reactions was monitored by following the disappearance of the Si H bands using quantitative infrared spectroscopy. The results obtained showed typical first order kinetics for the PTMDSE formation, consistent with the proposed reaction mechanism. In the case of PMDS an induction period occurred at lower reaction temperatures, but disappeared at 44 °C and the rate of Si H conversion also started to follow the first-order kinetics. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2246–2258, 2007 相似文献
32.
33.
A novel copolymer, poly(N‐hexyl‐3,7‐phenothiazylene‐1,2‐ethenylene‐2,6‐pyridylene‐1,2‐ethenylene) ( P3 ), containing N‐hexyl‐3,7‐phenothiazylene and 2,6‐pyridylene chromophores was synthesized to investigate the effect of protonation, metal complexation, and chemical oxidation on its absorption and photoluminescence (PL). Poly(N‐hexyl‐3,8‐iminodibenzyl‐1,2‐ethenylene‐1,3‐phenylene‐1,2‐ethenylene) and poly(N‐hexyl‐3,7‐phenothiazylene‐1,2‐ethenylene‐1,3‐phenylene‐1,2‐ethenylene) ( P2 ), consisting of 1,3‐divinylbenzene alternated with N‐hexyl‐3,8‐iminodibenzyl and N‐hexyl‐3,7‐phenothiazylene, respectively, were also prepared for comparison. Electrochemical investigations revealed that P3 exhibited lower band gaps (2.34 eV) due to alternating donor and acceptor conjugated units (push–pull structure). The absorption and PL spectral variations of P3 were easily manipulated by protonation, metal chelation, and chemical oxidation. P3 displayed significant bathochromic shifts when protonated with trifluoroacetic acid in chloroform. The complexation of P3 with Fe3+ led to a significant absorption change and fluorescence quenching, and this implied the coordination of ferric ions with the 2,6‐pyridylene groups in the backbone. Moreover, both phenothiazylene‐containing P2 and P3 showed conspicuous PL quenching with a slight redshift when oxidized with NOBF4. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1272–1284, 2004 相似文献
34.
35.
The increasing use of Ultraviolet (UV) light in medicine, industrial environments, for cosmetic use, and even in consumer products necessitates that greater attention be paid to the potential hazards of this type of electromagnetic radiation. To avoid any adverse effects of exposure to this type of radiation, four suitable protection filters were produced to block three UV bands (UVA, UVB, and UVC). The design structure of the required dielectric multilayer filters was done by optical thin film technology using the absorbing property of UV radiation for the substrates and dielectric materials. The computer analyses of the multilayer filter formulas were prepared using Macleod Software for the production processes. The deposition technique was achieved on optical substrates (Glass BK-7 and Infrasil 301) by dielectric material combinations including Titanium dioxide (Ti2O3), Hafnium dioxide (HfO2), and Lima (mixture of oxides SiO2/Al2O3); deposition being achieved using an electron beam gun. The output results of the theoretical and experimental transmittance values for spectral band from 200 nm to 800 nm were discussed in four processes. To analyze the suitability for use in ‘real world’ applications, the test pieces were subjected to the durability tests (adhesion, abrasion resistance, and humidity) according to Military Standard MIL-C-675C and MIL-C-48497A. 相似文献
36.
37.
采用5d-4f跃迁的稀土Ce3+-冠醚配合物(Ce-二环己基并-18-冠-6,Ce-DC18C6)作为发光掺杂剂,4,4'-二(9-咔唑基)联苯(CBP)为基质,设计制备了紫外发光器件:ITO/CuPc/Ce-DC18C6:CBP/Bu-PBD/LiF/Al,首次观测到峰位于376nm的Ce3+离子的紫外电致发光。通过对比器件的EL谱与Ce3+-冠醚配合物薄膜的PL谱发现,EL光谱中有部分来自Ce3+配合物中的Ce3+离子的。这种5d-4f电子跃迁的掺杂质量分数为3%时,该UV-发光器件的最大辐射功率为13μW/cm2。 相似文献
38.
熔制了掺铒碲铌玻璃样品(100-X)TeO2-XNb2O5(X=5,10,15,20mol%),测试了其密度、折射率、转变温度、析晶温度、维氏机械强度、吸收光谱、荧光光谱、荧光寿命等参量。利用Judd-Ofelt和McCumber理论分别计算了铒离子强度参量Ωt(t=2,4,6)和受激发射截面σemi的大小,研究了掺铒碲铌玻璃样品光谱参量对Nb2O5成分的依赖性,并与典型的碲锌钠玻璃(75TeO2-20ZnO-5Na2O)在热学、机械强度、光谱性质和放大品行四个方面进行了比较. 相似文献
39.
采用UV/H2O2技术对污染水体中的MTBE进行了氧化降解试验,考察了不同MTBE初始浓度,不同H2O2浓度,不同pH值,不同波长的紫外光对降解效果的影响,以及不同Cl^-、HCO3^-浓度的抑制作用.结果表明,在室温条件下,当紫外光波长为254nm,H2O2为15mmol/L,pH为3.0时对起始浓度为1mmol/L的MTBE具有较好的降解效果;反应60min,MTBE去除率可达97.6%.实验证明,UV/H2O2氧化技术是降解MTBE的一种有效方法. 相似文献
40.
E. M. Glebov V. P. Grivin V. F. Plyusnin A. V. Udaltsov 《Journal of Structural Chemistry》2006,47(3):476-483
Interaction between MnCl2 and diethylamine (DEA) in aqueous solutions has been studied by UV, IR, and EPR spectroscopy as part of the design and research program on models of natural photosystems. The composition of the precipitate for comparable concentrations of reagents and solute oxygen has been investigated. Mn(II) was found to be oxidized with oxygen to give MnO2·H2O as a precipitate. In the solution over the precipitate, Mn(III) complexes with DEA are formed; the complex molecule has four and six amine molecules in the coordination sphere. 相似文献