全文获取类型
收费全文 | 316篇 |
免费 | 34篇 |
国内免费 | 10篇 |
专业分类
化学 | 49篇 |
晶体学 | 1篇 |
数学 | 2篇 |
物理学 | 308篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 2篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2017年 | 2篇 |
2016年 | 3篇 |
2015年 | 2篇 |
2014年 | 4篇 |
2013年 | 5篇 |
2012年 | 6篇 |
2011年 | 12篇 |
2010年 | 12篇 |
2009年 | 52篇 |
2008年 | 58篇 |
2007年 | 42篇 |
2006年 | 32篇 |
2005年 | 11篇 |
2004年 | 5篇 |
2003年 | 11篇 |
2002年 | 21篇 |
2001年 | 17篇 |
2000年 | 10篇 |
1999年 | 14篇 |
1998年 | 12篇 |
1997年 | 6篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1987年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有360条查询结果,搜索用时 46 毫秒
41.
G.D. Dracoulis G.J. Lane A.P. Byrne P.M. Davidson T. Kibédi P. Nieminen H. Watanabe A.N. Wilson 《Physics letters. [Part B]》2008
The level scheme of 212Rn has been extended to spins of ∼38? and excitation energies of about 13 MeV using the 204Hg(13C, 5n)212Rn reaction and γ-ray spectroscopy. Time correlated techniques have been used to obtain sensitivity to weak transitions and channel selectivity. The excitation energy of the 22+ core-excited isomer has been established at 6174 keV. Two isomers with τ=25(2) ns and τ=12(2) ns are identified at 12211 and 12548 keV, respectively. These are the highest-spin nuclear isomers now known, and are attributed to configurations involving triple neutron core-excitations coupled to the aligned valence protons. Semi-empirical shell-model calculations can account for most states observed, but with significant energy discrepancies for some configurations. 相似文献
42.
We study linear excitations to a one-dimensional dark soliton described by a defocusing nonlinear Schödinger equation. By solving an eigenvalue problem for the excitations we obtain all eigenvalues and eigenfunctions and prove rigorously that these eigenfunctions are orthonormal and form a complete set. We then use the eigenfunctions to obtain the exact form of linear excitations for any given initial condition and to investigate the transverse stability of the dark soliton. The rigorous results reported in the present work can be applied to study the dynamics of dark solitons in various nonlinear optical media and Bose-Einstein condensates. 相似文献
43.
We address the dynamics of solitons in the optical lattices with periodic modulation of the nonlinearity coefficient. Based on the quasi-particle approach, the properties of fundamental soliton localized in optical lattices are theoretically analyzed and shown its potential application for controllable soliton switching. Moreover, the phenomena of multi-soliton splitting and the single-soliton constituent trapping in the optical lattices are illustrated and discussed. 相似文献
44.
Highly-chirped dissipative solitons of the cubic-quintic Ginzburg-Landau equation found in this work may provide a roadmap to design passively mode-locked laser oscillators that generate pulses of extremely high energy. We provide a region in the space of the system parameters where high-energy dissipative solitons are found, along with their typical spectral and temporal features. 相似文献
45.
A general phenomenological theory is presented for the phase behavior of ferromagnetic superconductors with spin-triplet electron Cooper pairing. The theory accounts in detail for the temperature-pressure phase diagram of ZrZn2, while the main features of the diagram for UGe2 are also described. Quantitative criteria are deduced for the U-type (type I) and Zr-type (type II) unconventional ferromagnetic superconductors with spin-triplet Cooper electron pairing. Some basic properties of quantum phase transitions are also elucidated. 相似文献
46.
Long Jiao Yanna Zhang Zhijun Du Xuemin Dai Hanfu Wang Zhixin Dong Haibo Yao Xuepeng Qiu 《Journal of polymer science. Part A, Polymer chemistry》2022,60(16):2454-2464
To tolerate high processing temperature during the fabrication of low-temperature polycrystalline silicon thin-film transistors (LTPS–TFT) in flexible OLED devices, the polyimide (PI) films, which are used as substrate, should have ultra-high glass transition temperature (Tg > 450°C) and ultra-low coefficient of thermal expansion (CTE at 0–5 ppm K−1). In this paper, two novel heterocyclic monomers, namely, N,N'-(xanthone-2,7-diyl)bis(4-aminobenzamide) (p-DAXBA) and N,N'-(xanthone-2,7-diyl)bis(3-aminobenzamide) (m-DAXBA), which contain a xanthone moiety, are prepared and polycondensed with pyromellitic dianhydride (PMDA), respectively. PI films (PIa and PIb) with intrinsic high Tg and low CTE are designed from the perspective of rigid conjugate xanthone structure and hydrogen bonding interaction. It is found that the PIa films prepared by p-DAXBA have better linear structure of molecular chains and show relatively higher Tg and lower CTE. The Tg of PIa-40 is greater than 450°C, and CTE can reach as low as 2.7 ppm K−1, tensile strength of 179 MPa, modulus of 5.67 GPa, indicating potential application prospect as a flexible OLED substrate. 相似文献
47.
Cr3+-doped α-Al2O3 nanoparticles (Al2−xCrxO3, 0.005 ≤ x ≤ 0.05) were synthesized by co-precipitation method. X-ray diffraction (XRD) patterns of Cr3+:Al2O3 nanoparticles revealed the crystallite size of ∼53 nm and electron microscopy (SEM & TEM) confirmed the spherical nanoparticle formation. Diffuse reflectance spectra (DRS) displayed peaks at 406 and 558 nm corresponding to the Cr3+ transitions which became prominent with the increase in Cr3+ concentration which was also evidenced by the gradually increasing pink coloration of the samples. Photoluminescence (PL) studies showed the sharp red emission at 694 nm (ruby line) which was observed for all samples. The Dq/B value for all samples was found to be greater than 2.3 confirming the presence of Cr3+ ions in the octahedral sites. Chromaticity diagrams displayed the maximum red appearance for the sample with x = 0.01 and a lifetime of 4 ms. The synthesized Cr3+:Al2O3 nanoparticles with smaller crystallite sizes and narrow near monochromatic emission can be used in various applications including sensing, lasing, and bioimaging applications. 相似文献
48.
Time-resolved fluorescence spectroscopy was used to characterize water-soluble organic matter (WSOM) which plays an important
role in soil ecosystem processes. WSOM was extracted from plant biomass, animal manures, and soils from controlled cropping
systems studies with known histories of organic amendments. Lifetime constants were derived using the multi-way PowerSlicing
method which provides a non-iterative, multi-exponential fitting of decay profiles. The lifetimes obtained by PowerSlicing
were not significantly different from those obtained using the traditional discrete components analysis. The three components
attributed to WSOM had lifetimes of 0.38 ± 0.14, 2.11 ± 0.72, and 7.08 ± 1.18 ns which are in agreement with previous lifetimes
reported for humic substances. This study provides further support for the new paradigm for the structure of soil organic
matter where the organic matter is composed of low-molecular-weight components held together by hydrogen bonding and hydrophobic
interactions. 相似文献
49.
Jiahong Yu Zhiyu Sun Huili Ma Chengyun Wang Wenbin Huang Zikai He Wenjun Wu Honglong Hu Weijun Zhao Wei-Hong Zhu 《Angewandte Chemie (International ed. in English)》2023,62(52):e202316647
The development of ultra-long room-temperature phosphorescence (UL-RTP) in processable amorphous organic materials is highly desirable for applications in flexible displays, anti-counterfeiting, and bio-imaging. However, achieving efficient UL-RTP from amorphous materials remains a challenging task, especially with activation by visible light and a bright afterglow. Here we report a general and rational molecular-design strategy to enable efficient visible-light-excited UL-RTP by multi-esterification of a rigid large-plane phosphorescence core. Notably, multi-esterification minimizes the aggregation-induced quenching and accomplishes a ′four birds with one stone′ possibility in the generation and radiation process of UL-RTP: i) shifting the excitation from ultraviolet light to blue-light through enhancing the transition dipole moment of low-lying singlet-states, ii) facilitating the intersystem crossing process through the incorporation of lone-pair electrons, iii) boosting the decay process of long-lived triplet excitons resulting from a significantly increased transition dipole moment, and iv) reducing the intrinsic triplet nonradiative decay by substitution of high-frequency vibrating hydrogen atoms. All these factors synergistically contribute to the most efficient and stable visible-light-stimulated UL-RTP (lifetime up to 2.01 s and efficiency up to 35.4 % upon excitation at 450 nm) in flexible films using multi-esterified coronene, which allows high-tech applications in single-component time-delayed white light-emitting diodes and information technology based on flashlight-activated afterglow encryption. 相似文献
50.
J. Ekman D. Rudolph C. Fahlander R.J. Charity W. Reviol D.G. Sarantites V. Tomov R.M. Clark M. Cromaz P. Fallon A.O. Macchiavelli M. Carpenter D. Seweryniak 《The European Physical Journal A - Hadrons and Nuclei》2000,9(1):13-17
Eighteen previously unknown γ-ray transitions were identified in the T
z = - 1/2 nucleus 51Fe following the fusion-evaporation reaction 32S(28Si,2α1n)51Fe. The level scheme reaches the fully aligned I
π = 27/2- terminating state of the five holes in the f
7/2 shell. The 17/2- state was found to be isomeric, and the lifetime was measured to be 2.87 ns. The mirror symmetry of 51Fe and 51Mn is discussed, and the level scheme of 51Fe is compared to shell-model calculations.
Received: 20 July 2000 / Accepted: 1 August 2000 相似文献