全文获取类型
收费全文 | 738篇 |
免费 | 106篇 |
国内免费 | 27篇 |
专业分类
化学 | 166篇 |
晶体学 | 3篇 |
力学 | 22篇 |
数学 | 44篇 |
物理学 | 636篇 |
出版年
2023年 | 11篇 |
2022年 | 8篇 |
2021年 | 9篇 |
2020年 | 5篇 |
2019年 | 12篇 |
2018年 | 15篇 |
2017年 | 21篇 |
2016年 | 21篇 |
2015年 | 19篇 |
2014年 | 23篇 |
2013年 | 47篇 |
2012年 | 60篇 |
2011年 | 55篇 |
2010年 | 46篇 |
2009年 | 51篇 |
2008年 | 57篇 |
2007年 | 59篇 |
2006年 | 50篇 |
2005年 | 39篇 |
2004年 | 41篇 |
2003年 | 34篇 |
2002年 | 26篇 |
2001年 | 22篇 |
2000年 | 15篇 |
1999年 | 20篇 |
1998年 | 10篇 |
1997年 | 3篇 |
1996年 | 12篇 |
1995年 | 12篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1992年 | 9篇 |
1991年 | 9篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 7篇 |
1987年 | 2篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1979年 | 8篇 |
1977年 | 1篇 |
1973年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有871条查询结果,搜索用时 234 毫秒
51.
D. Nikolić S. Djurović Z. Mijatović R. Kobilarov N. Konjević 《Journal of Applied Spectroscopy》2001,68(6):902-910
A method of simulating the contour of the asymmetric spectral lines of neutral nonhydrogen-like atoms in a plasma is suggested. The methods of nonlinear regression are used to approximate the experimental data by a model function. The method has been checked on the spectral lines emitted by the electric arc stabilized by the walls. The method makes it possible to evaluate the Stark parameters directly from the experimentally obtained shapes of isolated or overlapping spectral lines. 相似文献
52.
Resolution in 1H NMR spectra of solids can be significantly enhanced with fast magic-angle spinning and high magnetic fields. A variable field and spinning speed study up to 25 T and 40 kHz shows that the homogeneous line broadening is inversely proportional to the product of magnetic field strength and spinning speed. The combination of high field and fast speed yields a 1H linewidth approaching the intrinsic limit determined by anisotropy of magnetic susceptibility. An analysis of the anisotropic magnetic susceptibility line broadening is presented. 相似文献
53.
对啁啾高斯脉冲光束在色散介质中的时间和光谱特性作了研究.给出了远场光谱蓝移和脉冲展宽的解析式.结果表明:通过选择适当的啁啾参量,啁啾高斯脉冲光束沿轴上传输色散长度时,脉冲可恢复到初始值.随啁啾参量增加,谱线宽度展宽,轴上光谱蓝移增加,在远场蓝移趋于一渐近值.随啁啾参量增加,离轴光谱红移增加. 相似文献
54.
The temporal and spectral properties of ultrashort pulsed Laguerre-Gaussian (LG) beams propagating in dispersive media are studied both theoretically and numerically. It is shown that the on-axis pulse broadens with increasing propagation distance and the on-axis spectrum is blueshifted. For the off-axis spectrum the blueshifts decrease and then the spectrum becomes redshifted as the radial distance increases. The propagation of ultrashort pulsed LG beams in free space and of ultrashort pulsed Gaussian beams can be regarded as special cases of our results, and some interesting properties are discussed. 相似文献
55.
Eric Jourdanneau Tony Gabard Frdric Chaussard Robert Saint-Loup Hubert Berger Elena Bertseva Frdric Grisch 《Journal of Molecular Spectroscopy》2007,246(2):167-179
CARS laboratory experiments were done in the 2905–2925 cm−1 range, in the vicinity of the ν1 band of the methane molecule, for pressures ranging from 1 to 50 bar, and temperatures up to 1100 K. These experiments were carried out in order to retrieve the pressure evolution of the CH4 spectrum, as well as to confirm its temperature dependance. After a brief recall on the theory used to compute pressure broadening coefficients and relaxation rates, we consider the ν3 and ν4 infrared bands of methane for benchmark calculations purposes. Next, we present recent experimental CARS spectra and calculated ones. Lastly, we discuss flame experiments as well as comparisons of temperature retrieval using N2 and CH4 as probe molecules. 相似文献
56.
Jonathan Levine Michael R. Savina Thomas Stephan Nicolas Dauphas Andrew M. Davis Kim B. Knight Michael J. Pellin 《International journal of mass spectrometry》2009,288(1-3):36-43
Resonance ionization mass spectrometry offers extremely high sensitivity and elemental selectivity in microanalysis, but the isotopic precision attainable by this technique has been limited. Measured isotope ratios are sensitive to small fluctuations in the pointing, pulse timing, and wavelength of the resonance lasers. We show that, by minimizing these fluctuations using feedback controls and by power-broadening the optical transitions, we are able to measure chromium isotope ratios with statistics-limited precision better than 1%. Small additional improvements in reproducibility come from careful shaping of the electric field in the region where atoms are photoionized and from minimizing pulse-to-pulse variations in the time-of-flight mass spectrometer through which the photoions travel. The increased reproducibility of isotopic measurements on standard materials has enabled us to detect anomalous chromium isotopic abundances in presolar SiC grains extracted from primitive meteorites. 相似文献
57.
Broadening-independent demodulation for wavelength modulation spectroscopy based on even-order harmonics 总被引:1,自引:0,他引:1
The line broadening of gas absorption spectrum is a significant but unknown factor in traditional demodulation of wavelength modulation spectroscopy, which is a kind of tunable diode laser absorption spectroscopy in weak absorption cases. In this paper, another signal demodulation method based on some simple algebraic operations with the amplitudes of the zero-, second-, and fourth-order harmonics was proposed. With this method the effect of spectrum broadening could be selfeliminated. That makes the amplitude of the demodulated signal is irrelevant to the broadening, and enables the direct and fast measurement without complex simulations and curve fittings in traditional method. 相似文献
58.
Jean-Philippe Bartier 《Journal of Functional Analysis》2008,254(3):851-878
Qualitative properties of non-negative solutions to a quasilinear degenerate parabolic equation with an absorption term depending solely on the gradient are shown, providing information on the competition between the nonlinear diffusion and the nonlinear absorption. In particular, the limit as t→∞ of the L1-norm of integrable solutions is identified, together with the rate of expansion of the support for compactly supported initial data. The persistence of dead cores is also shown. The proof of these results strongly relies on gradient estimates which are first established. 相似文献
59.
We modify a uniform model of single bubble sonoluminescence, in which heat diffusion, water vapor diffusion and chemical reactions
are included to describe the bubble dynamics, and the processes of electron-atom bremsstrahlung, electron-ion bremsstrahlung
and recombination radiation, radiative attachment of electrons to atoms and molecules, line emissions of OH radicals and Na
atoms are taken into account to calculate the light emission. With this model, we compute the light pulse width, the photon
number per flash, the continuum and line spectra and the gas species as the products of chemical reactions, and try to compare
with all the experimental data available. We obtain good agreement with the observations of Ar and Xe bubbles in many cases,
but fail to match the experimental data of the photon number per flash. We also find that for He bubble the computed photon
number is always too small to interpret the observations.
Supported by the National Natural Science Foundation of China (Grant Nos. 10674081 and 10434070) 相似文献
60.
Perdeuterated benzofluoranthenes have slightly shorter retention times than their equivalent unlabeled forms in a DB-5 capillary column. Under column overload conditions, perdeuterated benzofluoranthenes in moderate multifold excesses, which might be encountered in their use as internal standards and carriers for quantitative analysis, are seen to exhibit both normal and reverse solvent effects on their close eluting congeners. In some cases the effects may be used to advantage by knowledgeable analysts, but for the ignorant and unwary the effects can lead to serious errors in identification and quantification. 相似文献