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21.
We have simultaneously used adsorption isotherm volumetry and Fourier transform infrared spectroscopy in order to take the investigations on amorphous ice structure a step further, especially concerning porosity and annealing-induced modifications. We have studied surface reorganization during annealing and found that the number of surface sites decreases before crystallization, their relative ratios being different for amorphous and crystalline ice. We also present results confirming that ice can have a large specific surface area and nevertheless be non-microporous. 相似文献
22.
The general stability of single-layer cylindrical grids is studied in linear and nonlinear formulations. Dependence of the general buckling load on the geometry and stiffness parameters of a grid is established in an analytical form. Such grids are numerically analyzed for stability. It is established that the general buckling load is much less than the local buckling load. Typical general buckling modes are found. It is shown that such grids are weakly sensitive to imperfections 相似文献
23.
The numerical prediction of the fields of inelastic strains (the linear invariant of the tensor of inelastic strains) in thermoset polyester/marble filler composite plates is discussed. A uniformly distributed load is applied to the plates, which lie on a steel base. The strain fields are predicted by means of the boundary element method by using creep test data for the composites and the polyester matrix itself. Identical creep tests were performed for two ages of the materials (1 month and 13 years), which allowed evaluating the aging effect. The study is carried out in two stages. At the first stage, the application of the generalized Maxwell-Gurevich equation to the thermoset matrix/mineral filler composite is demonstrated. The model parameters determined from the experimental creep data is used for the second stage, where the state of inelastic strains in the plates is predicted by applying the boundary element method. The influence of composite formulation (filler content) and physical aging of the polyester matrix on the state of inelastic strains in the plates is shown.__________Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 41, No. 2, pp. 145–156, March–April, 2005. 相似文献
24.
Early stages of rare-earth metal (Yb and Eu) growth on a vicinal, single-domain Si(1 0 0)2 × 1 surface have been studied in the coverage range of 0.1-0.3 monolayer (ML) by low energy electron diffraction, scanning tunneling microscopy, and synchrotron radiation photoemission spectroscopy. We show that Yb induces the 2 × 3 periodicity in the whole range of coverage studied. The 2 × 3 reconstruction coexists with the local 3 × 2/4 × 2 structure at about 0.2 ML of Yb. In contrast, Eu forms the 3 × 2 periodicity at 0.1-0.2 ML, whereas this structure is converted into the 2 × 3 phase at about 0.3 ML. The atomic arrangement and electronic properties of these reconstructions and the adsorbate-mediated modification of surface morphology are investigated. 相似文献
25.
Zhengmao Zhu 《Applied Surface Science》2005,252(2):303-310
The reactivity of the surface of poly(ethylene terephthalate) (PET) film under 172 nm UV irradiation (xenon excimer lamp) towards nitrogen-borne 1-octene, n-nonane and heptafluorodecene vapor was investigated. Materials receiving from 0 to 24 J/cm2 of UV were examined by X-ray photoelectron spectroscopy (XPS), time of flight secondary ion mass spectroscopy (ToF/SIMS), water and mineral oil contact angle measurement and atomic force microscopy (AFM). A uniform nanoscale layer developed on PET surface attributed to the grafting reaction between photolytically-produced polymer radicals and vapor phase molecules. 相似文献
26.
27.
Previous studies of the initial stage of oxidation on clean single crystal of Cu(1 0 0) have been extended to the case of the Cu(1 1 0) surface. The dynamic observation of the nucleation and growth of Cu oxide by means of in situ ultra high vacuum transmission electron microscopy (UHV-TEM) shows a highly enhanced oxidation rate on Cu(1 1 0) surface as compared to Cu(1 0 0). The kinetic data on the nucleation and growth of the three-dimensional oxide islands agree well with our heteroepitaxial model of surface diffusion of oxygen. 相似文献
28.
An experimental method is developed to examine the near tip deformation at the mesoscopic scale level. The differential interference contrast (DIC) method is used by application of the Nomarski prism in polarized microscope for measuring the out of surface deformation. The method is very sensitive to small height changes detected by different interference color. Discussed are results for the crack tip deformation field. 相似文献
29.
Shigeyuki Toki Igors Sics Benjamin S. Hsiao Syozo Murakami Masatoshi Tosaka Sirilux Poompradub Shinzo Kohjiya Yuko Ikeda 《Journal of Polymer Science.Polymer Physics》2004,42(6):956-964
The molecular orientation and strain‐induced crystallization of synthetic rubbers—polyisoprene rubber, polybutadiene rubber, and butyl rubber [poly(isobutylene isoprene)]—during uniaxial deformation were studied with in situ synchrotron wide‐angle X‐ray diffraction. The high intensity of the synchrotron X‐rays and the new data analysis method made it possible to estimate the mass fractions of the strain‐induced crystals and amorphous chain segments in both the oriented and unoriented states. Contrary to the conventional concept, the majority of the molecules (50–75%) remained in an unoriented amorphous state at high strains. Each synthetic rubber showed a different behavior of strain‐induced crystallization and molecular orientation during extension and retraction. Our results confirmed the occurence of strain‐induced networks in the synthetic rubbers due to the inhomogeneity of the crosslink distribution. The strain‐induced networks containing microfibrillar crystals and oriented amorphous tie chains were responsible for the ultimate mechanical properties. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 956–964, 2004 相似文献
30.
Su Nee Tan Daniel Fornasiero Rossen Sedev John Ralston 《Colloids and surfaces. A, Physicochemical and engineering aspects》2004,250(1-3):307-315
The foam behaviour of low molecular weight polypropylene glycols (PPG) was investigated as a function of concentration and molecular weight (190–2000 g mol−1). For each polypropylene glycol, foam stability increases with concentration and passes through a maximum, beyond which foamability is suppressed as the solubility limit of the glycol is exceeded and droplets of glycol form. Light-scattering data as well as static and dynamic surface tension results provide the key information leading to these interpretations. A maximum in foamability was observed for the PPG molecules with increasing molecular weight (caused by a change in molecular conformation at the interface). This suppresses the Marangoni effect and leads to a decrease in foam stability. 相似文献