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81.
0IntroductionPhenanthrolinederivativescontainingaminegroupshavebothsoftandhardsitesandaregooddonorsformetalions.1,10鄄phenanthrolineanditsderivativeshavebeenextensivelyusedasligandsinbothanalyticalandpreparativecoordinationchemis鄄try[1].Mostoftheseworksh… 相似文献
82.
在全相对论理论框架下,利用多组态Dirac-Fock(MCDF)方法,系统计算了NⅡ离子2p4f—2p3d的辐射跃迁概率,得到的结果与已有实验值符合很好.具体计算中,详细分析了相对论效应、电子关联、弛豫效应、Breit相互作用和量子电动力学(QED)效应对能级精细结构及辐射跃迁概率的影响.结果表明:相对论效应、电子关联和弛豫效应对NⅡ 2p4f-2p3d辐射跃迁概率有很重要的影响,考虑了这些效应后计算值得到明显改善. 相似文献
83.
The paper discusses the basic design of the critical facility, whose main purpose is the physics validation of AHWR. Apart
from moderator level control, the facility will have shutdown systems based on shutoff rods and multiple ranges of neutron
detection systems. In addition, it will have a flux mapping system based on 25 fission chambers, distributed in the core.
We are planning to use this reactor for experiments with a suitable source to simulate an ADS system. Any desired sub-criticality
can be achieved by adjusting the moderator level. Apart from perfecting our experimental techniques, in simple configurations,
we intend to study the one-way coupled core in this facility. Preliminary calculations, employing a Monte Carlo code TRIPOLI,
are presented.
相似文献
84.
应用飞秒时间分辨差异吸收光谱技术对PSⅡ的LHCⅡ三聚体中的能量传递过程进行实验研究,分析得到三组能量传递的时间寿命组分:748 fs、3.28 ps、32.15 ps.其中748 fs的组分为单体内Chl b649分子经Chl b658将能量传递给Chl a665分子的过程;3.28 ps时间常量反映单体内能量从Chl a677向吸收更长波长的Chl a688分子的能量传递过程,以及Chl b643、Chl b658和Chl a668~670分子获得能量的过程;而32.15 ps的时间与三聚体内的单体间的能量传递过程有关. 相似文献
85.
86.
在CH3OH/H2O混合溶剂中,经2,4,6-三(2-吡啶基)-1,3,5-三嗪(tptz)、草酸和新制Ni(OH)2/NiCO3反应合成得到配合物[Ni(H2O)(tptz)(C2O4)]·4H2O.单晶X-射线衍射分析表明:它与已报道的[M(H2O)(tptz)(C2O4)]·4H2O(M=Co(2)、Cu(3)、Zn(4))配合物同晶形,属三斜晶系,P1空间群,晶胞参数a=7.760(2)A,b=12.116(2)A,c=13.031(3)A,α=78.76(4)°,β=83.84(3)°,γ=78.69(3)°,V=1175.3(5)A^3,Z=2,Dc=1.543,F(000)=562,R1=0.0472,wR2=0.1350,GOF=1.088.在配合物的结构基础上与同晶形结构进行比较分析,并研究了它们的IR及TG/DTA测试表征. 相似文献
87.
Two Cd(Ⅱ) complexes, Cd2L2Cl2 (1) and Cd2L2(NCS)2 (2) (HL = N-(3-methoxylsalicylidene)-3-dimethylaminopropylamine) were synthesized and determined by EA, IR, TG and single-crystal X-ray diffraction. The crystallographic data are as follows: monoclinic, space group P21/n, a = 9.2710(9), b = 18.0069(18), c = 18.5562(19) A^°, β= 99.741(4)°, V = 3053.1(5), Z = 4,μ = 1.605, F(000) = 1536, R = 0.0264 and wR = 0.0699 for 1; orthorhombic, space group Pca21, a = 16.196(3), b = 11.506(2), c = 36.126(7) A^°, V = 6732(2), Z = 8,μ = 1.428, F(000) = 3264, R = 0.0376 and wR = 0.0877 for 2. There are two geometrically different octahedral Cd(Ⅱ) atoms, with N4O2 and O4Cl2 donor sets for 1 while N4O2 and N2O4 for 2. In the dinuclear Cd(Ⅱ) centers, the Cd(Ⅱ) atoms are held together by two deprotonted phenolate oxygen atoms from tetradentate L^- ligands. The thermal gravity data show two step decompositions with the residues of CdO for two complexes. 相似文献
88.
A new copper(Ⅱ) complex 3,Cu(C17H13F3O3)2·C5H5N,has been synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic,space group C2/c with a = 17.8511(7),b = 17.4136(7),c = 13.9425(7) ,β = 124.4830(10)°,V = 3572.5(3) 3,Z = 4,C39H29CuF6NO6,Mr = 785.17,F(000) = 1604,T = 292(2) K,Dc = 1.460 g/cm3 and μ = 0.691 mm-1. The structure was refined to R = 0.0477 and wR = 0.1110 for 2935 observed reflections with I > 2σ(I). For the title compound,X-ray analysis reveals that the copper(II) is penta-coordinated by four oxygen atoms from the corresponding 1-(4-(benzyloxy)phenyl)-4,4,4-trifluorobutane-1,3-dione ligands and one nitrogen atom of pyridine,forming a distorted square pyramidal geometry. It is found that the trifluoromethyl group,F(1)/F(1'),F(2)/F(2') and F(3)/F(3')),is disordered over two orientations in an approximate 3:1 ratio. 相似文献
89.
This contribution is focused on an acceleration of branch and bound algorithms for the uncapacitated facility location problem. Our approach is based on the well-known Erlenkotters’ procedures and Körkels’ multi-ascent and multi-adjustment algorithms, which have proved to be the efficient tools for solving the large-sized instances of the uncapacitated facility location problem. These two original approaches were examined and a thorough analysis of their performance revealed how each particular procedure contributes to the computational time of the whole algorithms. These analyses helped us to focus our effort on the most frequent procedures. The unique contribution of this paper is a new dual ascent procedure. This procedure leads to considerable acceleration of the lower bound computation process and reduces the resulting computational time. To demonstrate more efficient performance of amended algorithms we present the results of extensive numerical experiments. 相似文献
90.
以DNA杂交双链为联接, 构建纳米金颗粒Core-satellites结构并激发等离子体耦合增强效应,利用Hg2+可与DNA中胸腺嘧啶T形成T-Hg2+-T特异性结构,研制了用于检测水中Hg2+的局域等离子体共振(LSPR)光纤传感器.待测溶液中的Hg2+能够引起富含T的DNA单链折叠,抑制DNA杂交反应,降低等离子体耦合强度,改变LSPR谐振波长.通过检测谐振波长红移变化,实现对Hg2+浓度的定量检测.本方法检测Hg2+的线性范围为5~150 nmol/L, 检出限为3.4 nmol/L (3σ). Zn2+、Mg2+、Pb2+等重金属离子对Hg2+检测无明显干扰作用.实际水样中Hg2+加样回收率为94.2%~105.4%,相对标准偏差<4.8%. 相似文献