Liquid-liquid extraction followed by solid-phase extraction for the determination of lipophilic pesticides in beeswax by gas chromatography-electron-capture detection and matrix-matched calibration

Analytical methods for the simultaneous analysis of lindane, chlorpyriphos, z-chlorfenvinphos, endosulfan A and B, 4,4'-DDE, 4,4'-TDE, acrinathrine, bromopropylate, tetradifon, coumaphos and fluvalinate in pure beeswax samples are studied. For the analysis of bleached beeswaxes, a liquid-liquid extraction with acetonitrile followed by a clean-up on polymeric cartridges is the best option in terms of recovery and precision. However, some interferences that hinder the identification and quantification of important varroacides are found when non-bleached beeswaxes are analyzed. The analysis of all compounds in the latter samples require a clean-up by coupling an ODS cartridge before the polymeric cartridge. Considerations about the influence of the matrix in the quantitative analysis by a classical external standard calibration are also made and the use of a matrix-matched calibration is advised. Recoveries resulted to be about 100% with coefficients of variation between 10% and 20% (n = 5) for concentrations of 0.5 and 5 mg/kg.     

Commutativity of rings through a Streb's result

In this paper we investigate commutativity of rings with unity satisfying any one of the properties:

Trees and valuation rings

A subring of a division algebra is called a valuation ring of if or holds for all nonzero in . The set of all valuation rings of is a partially ordered set with respect to inclusion, having as its maximal element. As a graph is a rooted tree (called the valuation tree of ), and in contrast to the commutative case, may have finitely many but more than one vertices. This paper is mainly concerned with the question of whether each finite, rooted tree can be realized as a valuation tree of a division algebra , and one main result here is a positive answer to this question where can be chosen as a quaternion division algebra over a commutative field.

     

体相位全息光栅式波分复用器的研究

利用体相位全息光栅的优良特性,研制光栅式密集型波分复用器(DWDM)。准直后的信道波长通过体相位全息光栅两次衍射,在焦面上实现信道波长的分复用。阐述了体相位全息光栅的独特结构特点,给出了体相位全息光栅式密集型光波分复用器件的原理图,计算出各个信道的位置及间隔,用Zemax仿真出设计模型。相比于薄膜滤光片式器件而言,具有许多独特的优良特性,能够实现更密集更多信道数量的分复用。     

Broadband arrayed waveguide gratings on InP

Broadband arrayed waveguide gratings on InP are presented using a novel S-shape design. This design was utilized to accommodate the large free spectral range required for broadband operation. Four and eight channel AWGs with a wavelength channel spacing of 18 nm are discussed. The output peaks of the AWGs have a wide FWHM of 11 nm which provides insensitive operation to polarization, temperature fluctuations, and chromatic dispersion.     

外光注入半导体激光器实现时钟分频

从理论和实验上研究了利用光注入半导体激光器对高重复速率光脉冲产生的周期振荡和时钟分频现象.结果表明，光注入半导体激光器引起的二倍周期振荡是使注入脉冲重复频率分频的直接原因.通过耦合速率方程，数值模拟了半导体激光器在外光注入时输出光的时间序列和功率谱，并且分析了激光腔内各种周期振荡的特征.研究表明，当注入光使半导体激光器出现稳定的二倍周期振荡，且注入光的重复频率为此振荡频率的二倍时，时钟分频即可产生实验中，采用重复频率为6.32GHz的光脉冲注入Fabry-Perot激光器，实现了3.16GHz时钟分频信号 关键词： 周期振荡 时钟分频 光谱侧带 光注入     

无溶剂顶空气相色谱法测定盐酸左氧氟沙星残留溶剂

采用无溶剂-顶空-气相色谱直接测定盐酸左氧氟沙星中残留溶剂乙醇、甲苯、二甲基亚砜(DMSO)等.各残留溶剂的检出限分别在0.007-0.032 μg,6次测定的相对标准偏差RSD在1.84%-1.92%,加标回收在90.9%-110%.方法简便、快速、灵敏,可应用于其他药品中残留溶剂的分析.     

会聚光在柱状模拟生物组织中的实验研究

在中空的柱状有机玻璃中充入Intralipid-10%溶液构成单层圆柱模拟样品.在会聚单色光入射Intralipid-10%溶液的情况下，利用特制的光纤探头、锁相放大器、斩波器和微动平台等组成测试装置，测量了柱状Intralipid-10%溶液内后向散射光、能流率的空间分布情况，并对测量结果进行分析.对参量不同的溶液中的光分布进行了比较，得出了柱状溶液中光分布的初步规律.     

Total analysis of surface structure and properties by UHV transfer system

We have developed an ultrahigh-vacuum (UHV) complex sample preparation and analysis system, which realizes a reliable surface science analyzing various characters on an identical surface. The system contains three sample-preparation-and-characterization chambers and five analysis chambers. They are (1) an electronic-properties-characterization chamber, (2) a magnetic-properties-characterization chamber, (3) an organic-molecule chamber, (4) UHV SEM, (5) a high-energy-resolution angle-resolved photoelectron spectrometer, (6) a high-energy-resolution display-type spherical mirror analyzer, (7) a room-temperature (RT) STM, and (8) an optical-properties characterization chamber. A special sample holder is used with six electrodes on it, which enables accurate temperature measurement of a sample by connecting a thermocouple directly to the sample even if it is transferred. Four other electrodes can be used for construction of various circuits including evaporators. Some examples are shown.     

Pervaporation in chemical analysis

Unlike thermal processes such as distillation, pervaporation relies on the relative rates of solute permeation through a membrane and is a combination of evaporation and gas diffusion. The analytical pervaporation systems consist of a membrane module suitable for liquid sample introduction and a vacuum (or a sweeping gas) on the permeate side. It has been used in a wide range of applications including the analysis of various organic and inorganic compounds, and sample concentration. It has been directly interfaced with gas chromatography, spectrophotometry, capillary electrophoresis, electrochemical detectors, liquid chromatography, and mass spectrometry. A wide range of liquids, slurries, and solids samples has been analyzed using these techniques. This review highlights the basic principles of the pervaporation and the state of its current development as applied to analytical chemistry.