Miscible blends of modified poly(aryl ether ketones) with aromatic polyimides

The phase behavior of binary blends of poly(ether ether ketone) (PEEK), sulfonated PEEK, and sulfamidated PEEK with aromatic polyimides is reported. PEEK was determined to be immiscible with a poly(amide imide) (TORLON 4000T). Blends of sulfonated and sulfamidated PEEK with this poly(amide imide), however, are reported here to be miscible in all proportions. Blends of sulfonated PEEK and a poly(ether imide) (ULTEM 1000) are also reported to be miscible. Spectroscopic investigations of the intermolecular interactions suggest that formation of electron donoracceptor complexes between the sulfonated/sulfamidated phenylene rings of the PEEKs and the n-phenylene units of the polyimides are responsible for this miscibility. © 1993 John Wiley & Sons, Inc.     

The first ruthenium-alkyne-dihydride reported is now recognized as an intermediate in the homogeneous hydrogenation of diphenylacetylene: Crystal structure of (μ-H)2Ru3(CO)9(μ3-η2-∥-C2Ph2)

The title complex (complex1) was the first alkyne-substituted triruthenium dihydrido cluster to be reported and was characterized by spectroscopy as a triangular cluster with the alkyne parallel to a Ru-Ru edge. Recently, we have found that1 is a key intermediate in the homogeneous hydrogenation of diphenylacetylene catalyzed by tetrahedral Ru₄ and FeRu₃ clusters. Since the discovery of1, a great number of complexes with alkynes parallel to a cluster edge have been reported; at present this is the more common bonding mode for alkynes on trinuclear clusters. The structural features of1 allow a comparison with those of other ruthenium-containing derivatives and help to draw suggestions of the role of1 in hydrogenation catalysis.     

Titanium nanocarbides: Synthesis and modeling

The present state of research on the production and modeling of nanostructures based on titanium carbide-a typical representative of an extensive class of carbides of d-and f-metals-is reviewed. Methods for the synthesis of various Ti-C nanostructures (molecular clusters, nanocrystallites, nanospheres, nanofibers, nanowires) are examined, and their morphology, atomic structure, and known physicochemical characteristics are described. Theoretical models of the atomic structure and properties of new types of nanostructures in the titanium-carbon system (endo-and exohedral titanofullerenes, “hybrid” structures based on carbon nanotubes, the so-called peapods, nanocables, and a number of others) and the prospects for their application as components of nanoceramics, hydrogen accumulators, materials for spintronics, etc. are discussed. __________ Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 1, pp. 1–23, January–February, 2007.     

L-S category of quaternionic Stiefel manifolds

By calculating certain generalized cohomology theory, lower bounds for the L-S category of quaternionic Stiefel manifolds are given.     

Lévy processes and their subordination in matrix Lie groups

Lévy processes in matrix Lie groups are studied. Subordination (random time change) is used to show that quasi-invariance of the Brownian motion in a Lie group induces absolute continuity of the laws of the corresponding pure jump processes. These results are applied to several examples which are discussed in detail.     

加权Herz—type Triebel—Lizorkin空间的特征及应用

当s∈ R,0,〈q, p〈∈∞,0,〈β≤∞且 max{-n/q,-nδ2/qδ1}〈a时，定义了加权Herz—type　Triebel-Lizorkin空间kq^q,pF^s β（R^n,ω1，ω2）和Kq^a,pF^sβ（R^n，ω1，ω2），并给出这些空间的一些特征及在这些空间上的Hard—Littlewood极大算子不等式．     

Countably compact topological group topologies on free Abelian groups from selective ultrafilters

Tkachenko showed in 1990 the existence of a countably compact group topology on the free Abelian group of size c using CH. Koszmider, Tomita and Watson showed in 2000 the existence of a countably compact group topology on the free Abelian group of size c² using a forcing model in which CH holds.Wallace's question from 1955, asks whether every both-sided cancellative countably compact semigroup is a topological group. A counterexample to Wallace's question has been called a Wallace semigroup. In 1996, Robbie and Svetlichny constructed a Wallace semigroup under CH. In the same year, Tomita constructed a Wallace semigroup from MAcountable.In this note, we show that the examples of Tkachenko, Robbie and Svetlichny, and Koszmider, Tomita and Watson can be obtained using a family of selective ultrafilters. As a corollary, the constructions presented here are compatible with the total failure of Martin's Axiom.     

On cellularization for simplicial presheaves and motivic homotopy

We construct cellular homotopy theories for categories of simplicial presheaves on small Grothendieck sites and discuss applications to the motivic homotopy category of Morel and Voevodsky.     

四（对-羟基苯基）卟啉氧合配合物的室温固相合成，表征及氧合能力

采用固相反应合成了四羟基苯基卟啉与与Fe^2＋,Co^2＋金属离子的配合物,在室温下,将其与分子O2作用,提纯后得到两种固态氧合配合物．通过元素分析、红外光谱（IR）、核磁共振氢谱（^1HNMR）、电导、热分析（TG／DTA）、紫外光谱（UV）等测试手段确定了氧合配合物的组成为[Co·THPP·O2]（NO3）2·2H2O、[Fe·THPP·O2]Cl2·2H2O]，可知1mol配合物吸收了1molO2,采用失重法测定了氧合配合物中的配位氧,确定1mol金属配合物吸收1molO2形成超氧配合物．     

QN-spaces, wQN-spaces and covering properties

The main results of the paper are as follows: covering characterizations of wQN-spaces, covering characterizations of QN-spaces and a theorem saying that Cp(X) has the Arkhangel'ski?ˇ property (α₁) provided that X is a QN-space. The latter statement solves a problem posed by M. Scheepers [M. Scheepers, Cp(X) and Arhangel'ski?ˇ's αi-spaces, Topology Appl. 89 (1998) 265-275] and for Tychonoff spaces was independently proved by M. Sakai [M. Sakai, The sequence selection properties of Cp(X), Preprint, April 25, 2006]. As the most interesting result we consider the equivalence that a normal topological space X is a wQN-space if and only if X has the property S₁(Γshr,Γ). Moreover we show that X is a QN-space if and only if Cp(X) has the property (α₀), and for perfectly normal spaces, if and only if X has the covering property (β₃).