Influence of experimental parameters on physical properties of porous silicon and oxidized porous silicon layers

This paper reports physical properties of porous silicon and oxidized porous silicon, manufactured by anodisation from heavily p-type doped silicon wafers as a function of experimental parameters. The growth rate and refractive index of the layers were studied at different applied current densities and glycerol concentrations in electrolyte. When the current density varied from 5 to 100 mA/cm², the refractive index was between 1.2 and 2.4 which corresponded to a porosity range from 42 to 85%. After oxidation, the porosity decreased and was between 2 and 45% for a refractive index range from 1.22 to 1.46. The thermal processing also induced an increase in thickness which was dependent on the initial porosity. This increase in thickness was more important for the lowest porosities. Lastly, the roughness of the porous layer/silicon substrate interface was studied at different applied current densities and glycerol concentrations in solution. Roughness decreased when the current density or glycerol concentration increased. Moreover, roughness was also reduced by thermal oxidation.     

Automatic fringe analysis of two-beam interference patterns for measurement of refractive index and birefringence profiles of fibres

Automatic fringe pattern analysis is a powerful and inexpensive digital image-processing technique. Two-beam polarizing interference Pluta microscope [Pluta M. Opt Acta 1971;18:661, Pluta M. J Microsc 1972;96:309] is automated by the computer-aid via CCD camera and digital frame grabber. Software program is prepared to deal with the duplicated (separated and overlapped) Microinterferograms produced by two-beam polarizing microscope. It also gives an accurate and fast automatic measurement of refractive index and birefringence profiles for fibres. In this paper, the refractive index and birefringence profiles of two different types of fibres, basalt and polypropylene (PP) fibres are presented. A new method to determine the birefringence profile of fibres from non-duplicated microinterferogram is suggested. The cold drawing process for PP fibres is studied.     

An enhanced common path interference optic measurement system for refractive indices and thickness

This study proposes a common path interference optical system for the measurement of refractive indices and thickness of uniaxial crystal material. The measurement system comprises an accurate Mach–Zehnder laser interferometer, a single-axis rotary stepping motor, and a computer. The laser interferometer is composed of a single-frequency He–Ne laser, two-beam splitters and two reflectors. The Mach–Zehnder laser interferometer measures the optical length difference by using its linear measurement accuracy. The proposed solution procedure enables both the refractive indices and the thickness of the optical waveplate to be obtained. The proposed design differs from conventional designs in that it does not use a heterodyne modulator with a lock-in technique. It is shown that the refractive indices and thickness of the tested optical elements can be measured rapidly and accurately.     

正切平方势阱中线性与非线性光学折射率变化的研究

利用正切平方势把电子的Schrodinger方程化为了超几何方程，并用超几何函数严格求解了电子的本征值和本征函数利用量子力学中的密度矩阵算符理论导出了正切平方势阱中的线性与三阶非线性光学折射率的解析表达式计算了该系统中的线性与非线性光学折射率变化的大小，讨论了影响折射率变化因素文章以典型的GaAs/AlGaAs势阱为例作了数值计算,数值计算结果表明，势阱的形状和入射光强对光学折射率的变化有着重要的影响.     

Optical detection of Cu ion using a SQ-dye containing polymeric thin-film on Au surface

In this study, we have fabricated Cu²⁺ ion sensor using a squarylium dye (SQ-dye) containing polymeric thin-film. Surface Plasmon Resonance (SPR) was used as a signal amplifier to achieve high sensitivity and large linear dynamic range for detection of Cu²⁺ ion. High selectivity to Cu²⁺ ion was obtained by the effective electro-static interaction between SQ-dye and Cu²⁺ ion in the polymeric film. The optimal analytical condition of high selectivity and sensitivity in the wider linear dynamic range obtained in this study may be a result of the cooperative ‘hard-soft’ metal ion-ligand interaction and effective detection of refractive index changes by the complexation of Cu²⁺ ion and SQ-dye in SPR measurement. Among 10 different alkali metal, alkaline earth metal, and transition metal ions, SQ-dye in poly(vinylchloride)–poly(vinyl acetate)–poly(vinyl alcohol) (PVC–PVAc–PVA) copolymer film showed the highest selectivity to Cu²⁺ ion. Although the interaction between SQ-dye and metal ions has not been well understood, both cooperative ‘hard-soft’ metal ion-ligand interaction and size-selective recognition of Cu²⁺ ion to SQ-dye may contribute to high selectivity. Furthermore, additional sensitivity in the detection of Cu²⁺ ion by SPR was obtained by matching the wavelength of probing radiation of SPR and absorption maximum of SQ-dye at 675 nm, which allow to detect small changes in the refractive index by complex formation on the sensing surface. This result may apply in development of the Cu²⁺ ion selective sensor for medical, biochemical, and environmental applications.     

Automated interferometric technique for express analysis of the refractive indices in isotropic and anisotropic optical materials

This paper deals with the technique for the refractive index measurements based on the interferometry of a rotated parallel plate (IRPP). The device consists of the Michelson interferometer, the sample rotation system and the optoelectronic registration system. A refractive index of parallel plates is determined by their rotation through measuring simultaneously a shift of interference fringes. Although the IRPP technique is known from long ago [Shumate MS. Appl Opt 1966;5:327] several considerable improvements have been done in order to improve the accuracy of the method. The measuring process is completely automated. The method has been tested on the model crystals of the lithium niobate giving the magnitudes for ordinary and extraordinary refractive indices as n₀=2.2865±0.0007 and n_e=2.2034±0.0007. A considerable increase of accuracy is reached in our case by an automation of the measuring procedure, development of a new software as well as implementing the interferometric method for a precise determination of a sample zero position. The automated refractometer is offered for use in research laboratories and industry.     

Refractive index detection in microbore column liquid chromatography

Summary An existing commercial refractive index detector was modified for use with microbore column LC systems. The detector utilizes the Fresnel method. The effect of band dispersion and dilution at the detector side is of extreme importance in connection with the miniaturized LC system. In the modified model the original heat-exchanger tube was removed and a stainless steel capillary was used for heat-exchanging. Gaskets having different cell volumes were also examined with respect to band broadening and sensitivity. The detection limit was 10ng for di-n-pentyl phthalate. The examples include the detection of phthalates, alcohols, n-paraffins, and kerosine.     

Refractive index detection in slurry-packed capillary column LC

An existing commercial refractive index detector was modified for use with slurry-packed capillary column LC systems. The cell gasket of the original detector cell was replaced by a micro cell gasket giving a volume of 0.8 μL. The relationship between detector response and the amount of sample injected was examined. The limit of detection was 2-3 ng for di-n-pentyl phthalate.     

Low-temperature, solution processing of TiO2 thin films and fabrication of multilayer dielectric optical elements

High-quality TiO₂ thin films have been deposited from aqueous titanium-peroxo solutions via spin coating. The effects of precursor solution pH on the crystallization behavior, morphology, density, and refractive index of the films are reported. From X-ray diffraction measurements, the amorphous as-deposited films are found to crystallize in the anatase phase at 250 °C. Surface and cross-section SEM images reveal that films deposited from an acidic precursor are more uniform and denser than those deposited from a basic precursor. X-ray reflectivity measurements show that films with smooth surfaces and high densities (up to 87% of single-crystal anatase) can be produced at temperatures as low as 300 °C. Measured densities are consistent with high refractive indices at 633 nm of 2.24 and 2.11 for films derived from acidic and basic precursors, respectively. The uniformity and dense nature of the films have allowed fabrication of multilayer dielectric optical elements with thermal processing at only 300 °C. The distributed Bragg reflector with four bilayers exhibits a reflectance of 92% and a stop band width of 150 nm. The optical microcavity has a quality factor of 20. The optical properties of all elements agree well with theoretical models, indicating good optical quality. Use of the precursor chemistry for direct photopatterning of TiO₂ films without a polymer resist is also demonstrated.     

Determination of Fatty Acid Methyl Esters in Biodiesel Produced from Yellow Horn Oil by LC

A simple and accurate HPLC method with refractive index detection was developed to determine the main fatty acid methyl esters in biodiesel produced from yellow horn oil. Methyl linoleate, methyl linolenate, methyl arachidate, methyl stearate, methyl palmitate and methyl oleate were separated on a HIQ SIL C18W column using methanol as mobile phase. The method has good repeatability and precision, the intraday and interday RSD for both retention time and peak area was less than 3.2%. The LOD (S/N = 3) and LOQ (S/N = 9) were less than 0.004 and 0.015 mg mL⁻¹, respectively.